Materials & Streams Report
November 23, 2014
for PDO flowsheet for case assignments
1. OVERALL PROCESS DATA
Annual Operating Time 7,920.00h
Unit Production Ref. Rate 90,409,667.41kg MP/yr
Operating Days per Year 330.00
MP = Total Flow of Stream 'Product'
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2.1 STARTING MATERIAL REQUIREMENTS (per Section)
Amount
Gross
Needed Molar Mass
Mass
Section Starting Material Active Product (MT Yield Yield
Yield
Sin/kg (%) (%)
(%)
MP)
Fermentation Section Glucose 1,3 PDO 0.00 Unknown Unknown Unknown
Clarification Section 1,3 PDO 1,3 PDO 0.00 Unknown Unknown Unknown
Purification Section 1,3 PDO 1,3 PDO 0.00 97.02 97.02 97.02
Sin = Section Starting Material, Aout = Section Active Product
2.2 BULK MATERIALS (Entire Process)
Material MT/yr MT/h MT/kg MP
Air 246,059 31.068 0.003
Cane Juice 1,441,440 182.000 0.016
H2SO4 ( 4% w/w) 21,275 2.686 0.000
Inorganics 577 0.073 0.000
NaOH (4% w/w) 10,976 1.386 0.000
NH3 Sltn (28%) 3,870 0.489 0.000
Organics 2,595 0.328 0.000
Water 76,810 9.698 0.001
TOTAL 1,803,601 227.727 0.020
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2.3 BULK MATERIALS (per Section)
SECTIONS IN: Main Branch
Fermentation Section
Material MT/yr MT/h MT/kg MP
Air 246,059 31.068 0.003
Cane Juice 1,441,440 182.000 0.016
Inorganics 577 0.073 0.000
NH3 Sltn (28%) 3,870 0.489 0.000
Organics 2,595 0.328 0.000
Water 42,567 5.375 0.000
TOTAL 1,737,107 219.332 0.019
Clarification Section
Material MT/yr MT/h MT/kg MP
Water 29,281 3.697 0.000
TOTAL 29,281 3.697 0.000
Purification Section
Material MT/yr MT/h MT/kg MP
H2SO4 ( 4% w/w) 21,275 2.686 0.000
NaOH (4% w/w) 10,976 1.386 0.000
Water 4,963 0.627 0.000
TOTAL 37,213 4.699 0.000
Bulk Materials Per Section (%)
100.00
90.00
80.00
70.00
Process Sections
60.00
Fermentation Section
50.00
Clarification Section
Purification Section
40.00
30.00
20.00
10.00
0.00
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2.4 BULK MATERIALS (per Material)
Air
Air % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-4 100.00 246,059 31.068 0.003
TOTAL 100.00 246,059 31.068 0.003
Cane Juice
Cane Juice % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-1 100.00 1,441,440 182.000 0.016
TOTAL 100.00 1,441,440 182.000 0.016
H2SO4 ( 4% w/w)
H2SO4 ( 4% w/w) % Total MT/yr MT/h MT/kg MP
Purification Section (Main Branch)
P-11 100.00 21,275 2.686 0.000
TOTAL 100.00 21,275 2.686 0.000
Inorganics
Inorganics % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-3 100.00 577 0.073 0.000
TOTAL 100.00 577 0.073 0.000
NaOH (4% w/w)
NaOH (4% w/w) % Total MT/yr MT/h MT/kg MP
Purification Section (Main Branch)
P-11 100.00 10,976 1.386 0.000
TOTAL 100.00 10,976 1.386 0.000
NH3 Sltn (28%)
NH3 Sltn (28%) % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-3 100.00 3,870 0.489 0.000
TOTAL 100.00 3,870 0.489 0.000
Organics
Organics % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-3 100.00 2,595 0.328 0.000
TOTAL 100.00 2,595 0.328 0.000
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Water
Water % Total MT/yr MT/h MT/kg MP
Fermentation Section (Main Branch)
P-8 6.08 4,672 0.590 0.000
P-1 49.34 37,895 4.785 0.000
Clarification Section (Main Branch)
P-6 16.56 12,721 1.606 0.000
P-10 21.56 16,560 2.091 0.000
Purification Section (Main Branch)
P-11 6.46 4,963 0.627 0.000
TOTAL 100.00 76,810 9.698 0.001
2.5 BULK MATERIALS: SECTION TOTALS (MT/kg MP)
Fermentation Clarification Purification
Raw Material
Section Section Section
Air 0.003 0.000 0.000
Cane Juice 0.016 0.000 0.000
H2SO4 ( 4% w/w) 0.000 0.000 0.000
Inorganics 0.000 0.000 0.000
NaOH (4% w/w) 0.000 0.000 0.000
NH3 Sltn (28%) 0.000 0.000 0.000
Organics 0.000 0.000 0.000
Water 0.000 0.000 0.000
TOTAL 0.019 0.000 0.000
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Bulk Materials (Entire Process)
0.02
0.01
0.01
0.01
0.01 Raw Materials
0.01
Air
0.01
Cane Juice
0.01 H2SO4 ( 4/w)
Inorganics
0.01
NaOH (4/w)
0.01
NH3 Sltn (28)
0.01
Organics
0.01
Water
0.00
0.00
0.00
0.00
0.00
2.6 BULK MATERIALS: SECTION TOTALS (MT/h)
Fermentation Clarification Purification
Raw Material
Section Section Section
Air 31.068 0.000 0.000
Cane Juice 182.000 0.000 0.000
H2SO4 ( 4% w/w) 0.000 0.000 2.686
Inorganics 0.073 0.000 0.000
NaOH (4% w/w) 0.000 0.000 1.386
NH3 Sltn (28%) 0.489 0.000 0.000
Organics 0.328 0.000 0.000
Water 5.375 3.697 0.627
TOTAL 219.332 3.697 4.699
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Material Consumption (MT/kg MP)
Bulk Materials (Entire Process)
180.00
160.00
Raw Materials
140.00
Air
120.00
Cane Juice
H2SO4 ( 4/w)
100.00
Inorganics
NaOH (4/w)
80.00
NH3 Sltn (28)
Organics
60.00
Water
40.00
20.00
0.00
2.7 BULK MATERIALS: SECTION TOTALS (MT/yr)
Fermentation Clarification Purification
Raw Material
Section Section Section
Air 246,059 0 0
Cane Juice 1,441,440 0 0
H2SO4 ( 4% w/w) 0 0 21,275
Inorganics 577 0 0
NaOH (4% w/w) 0 0 10,976
NH3 Sltn (28%) 3,870 0 0
Organics 2,595 0 0
Water 42,567 29,281 4,963
TOTAL 1,737,107 29,281 37,213
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Material Consumption (MT/h)
Bulk Materials (Entire Process)
1500000.00
1400000.00
1300000.00
1200000.00
Raw Materials
1100000.00
Air
1000000.00
Cane Juice
900000.00
H2SO4 ( 4/w)
800000.00
Inorganics
700000.00
NaOH (4/w)
600000.00
NH3 Sltn (28)
500000.00
Organics
400000.00 Water
300000.00
200000.00
100000.00
0.00
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Material Consumption (MT/yr)
3. STREAM DETAILS
Stream Name Cane Juice S-101 Waste-101 S-107
Source INPUT P-1 P-1 P-16
Destination P-1 P-16 OUTPUT OUTPUT
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.22 25.20 100.00
Pressure (bar) 1.01 1.01 1.01 1.01
Density (g/L) 1,021.16 1,018.69 1,066.20 0.59
Total Enthalpy (kW-h) 4,821.34 4,638.85 224.82 95,727.14
Specific Enthalpy (kcal/kg) 22.79 23.14 20.36 683.17
Heat Capacity (kcal/kg-°C) 0.91 0.92 0.81 0.45
Component Flowrates (MT/h)
Ash 0.546 0.087 0.459 0.000
Cellulose 1.820 0.291 1.529 0.000
Glucose 27.300 26.158 1.142 0.000
Water 152.334 145.962 6.372 120.565
TOTAL (MT/h) 182.000 172.498 9.502 120.565
TOTAL (m3/h) 178.229 169.333 8.912 204,919.467
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Stream Name S-106 S-102 Air-In S-103
Source P-16 P-2 INPUT P-4
Destination P-2 P-3 P-4 P-3
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 100.00 35.00 25.00 40.00
Pressure (bar) 1.01 1.01 1.01 4.01
Density (g/L) 1,040.05 1,074.20 1.18 4.45
Total Enthalpy (kW-h) 4,406.69 1,542.34 218.44 349.58
Specific Enthalpy (kcal/kg) 73.01 25.55 6.05 9.68
Heat Capacity (kcal/kg-°C) 0.73 0.73 0.24 0.24
Component Flowrates (MT/h)
Ash 0.087 0.087 0.000 0.000
Cellulose 0.291 0.291 0.000 0.000
Glucose 26.158 26.158 0.000 0.000
Nitrogen 0.000 0.000 23.829 23.829
Oxygen 0.000 0.000 7.239 7.239
Water 25.397 25.397 0.000 0.000
TOTAL (MT/h) 51.933 51.933 31.068 31.068
TOTAL (m3/h) 49.933 48.346 26,345.761 6,986.324
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Organics &
Stream Name Aq NH3 (28%) Vent-1 S-104
Inorganics
Source INPUT INPUT P-3 P-3
Destination P-3 P-3 OUTPUT P-5
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 35.00 35.00
Pressure (bar) 1.01 1.01 1.00 1.00
Density (g/L) 1,152.90 900.00 1.27 1,005.08
Total Enthalpy (kW-h) 4.69 14.67 1,310.54 1,539.34
Specific Enthalpy (kcal/kg) 10.08 25.83 27.88 30.48
Heat Capacity (kcal/kg-°C) 0.40 1.03 0.23 0.87
Component Flowrates (MT/h)
1,3 PDO 0.000 0.000 0.000 12.563
1-2-4 butanetri 0.059 0.000 0.000 0.059
Acetic-Acid 0.126 0.000 0.000 0.126
Ammonia 0.000 0.137 0.000 0.001
Ash 0.000 0.000 0.000 0.087
Biomass 0.000 0.000 0.000 0.813
Calcium Chlorid 0.001 0.000 0.000 0.001
Carb. Dioxide 0.000 0.000 14.768 0.000
Cell Debris 0.000 0.000 0.000 0.167
Cellulose 0.000 0.000 0.000 0.291
Citric Acid 0.015 0.000 0.000 0.015
Glucose 0.000 0.000 0.000 0.026
Glycerol 0.084 0.000 0.000 0.084
KH2PO4 0.020 0.000 0.000 0.020
MgSO4 0.009 0.000 0.000 0.009
NaCl 0.000 0.000 0.000 0.000
Nitrogen 0.000 0.000 23.829 0.000
Oxygen 0.000 0.000 1.848 0.000
Phosphoric Acid 0.019 0.000 0.000 0.019
Pyruvic Acid 0.059 0.000 0.000 0.059
Sulfuric Acid 0.008 0.000 0.000 0.008
Water 0.000 0.352 0.000 29.110
TOTAL (MT/h) 0.401 0.489 40.445 43.458
TOTAL (m3/h) 0.347 0.543 31,870.768 43.239
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Stream Name S-105 S-201 S-202 S-204
Source P-5 P-6 P-6 P-8
Destination P-6 P-9 P-7 P-9
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 35.00 35.29 35.30 69.33
Pressure (bar) 1.00 1.00 1.00 0.46
Density (g/L) 1,005.08 1,004.13 1,011.94 980.73
Total Enthalpy (kW-h) 1,539.34 1,386.75 165.51 1,090.87
Specific Enthalpy (kcal/kg) 30.48 30.66 31.37 67.24
Heat Capacity (kcal/kg-°C) 0.87 0.87 0.89 0.97
Component Flowrates (MT/h)
1,3 PDO 12.563 11.449 1.113 0.891
1-2-4 butanetri 0.059 0.053 0.005 0.004
Acetic-Acid 0.126 0.115 0.011 0.009
Ammonia 0.001 0.001 0.000 0.000
Ash 0.087 0.078 0.009 0.007
Biomass 0.813 0.065 0.749 0.024
Calcium Chlorid 0.001 0.001 0.000 0.000
Cell Debris 0.167 0.152 0.015 0.012
Cellulose 0.291 0.254 0.037 0.027
Citric Acid 0.015 0.014 0.001 0.001
Glucose 0.026 0.024 0.002 0.002
Glycerol 0.084 0.077 0.007 0.006
KH2PO4 0.020 0.019 0.002 0.001
MgSO4 0.009 0.008 0.001 0.001
NaCl 0.000 0.000 0.000 0.000
Phosphoric Acid 0.019 0.018 0.002 0.001
Pyruvic Acid 0.059 0.053 0.005 0.004
Sulfuric Acid 0.008 0.007 0.001 0.001
Water 29.110 26.530 2.580 12.968
TOTAL (MT/h) 43.458 38.918 4.540 13.960
TOTAL (m3/h) 43.239 38.758 4.487 14.234
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Stream Name S-205 S-206 Waste-202 NaOH (4%)
Source P-9 P-10 P-10 INPUT
Destination P-10 P-11 OUTPUT P-11
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 45.00 45.37 45.40 25.00
Pressure (bar) 0.46 0.46 0.46 1.01
Density (g/L) 997.00 996.72 999.03 1,100.00
Total Enthalpy (kW-h) 2,477.62 2,370.99 125.33 38.27
Specific Enthalpy (kcal/kg) 40.32 40.62 40.70 23.76
Heat Capacity (kcal/kg-°C) 0.90 0.90 0.90 0.95
Component Flowrates (MT/h)
1,3 PDO 12.341 11.744 0.596 0.000
1-2-4 butanetri 0.058 0.055 0.003 0.000
Acetic-Acid 0.124 0.118 0.006 0.000
Ammonia 0.001 0.001 0.000 0.000
Ash 0.085 0.080 0.005 0.000
Biomass 0.089 0.000 0.089 0.000
Calcium Chlorid 0.001 0.001 0.000 0.000
Cell Debris 0.164 0.156 0.008 0.000
Cellulose 0.281 0.258 0.023 0.000
Citric Acid 0.015 0.014 0.001 0.000
Glucose 0.026 0.024 0.001 0.000
Glycerol 0.083 0.079 0.004 0.000
KH2PO4 0.020 0.019 0.001 0.000
MgSO4 0.009 0.008 0.000 0.000
NaCl 0.000 0.000 0.000 0.000
Phosphoric Acid 0.019 0.018 0.001 0.000
Pyruvic Acid 0.058 0.055 0.003 0.000
Sodium Hydroxid 0.000 0.000 0.000 0.139
Sulfuric Acid 0.008 0.007 0.000 0.000
Water 39.499 37.590 1.909 1.247
TOTAL (MT/h) 52.878 50.228 2.650 1.386
TOTAL (m3/h) 53.037 50.394 2.652 1.260
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Stream Name H2SO4 (4%) Water S-301 Waste-301
Source INPUT INPUT P-11 P-11
Destination P-11 P-11 P-12 OUTPUT
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 25.00 25.00 45.37 25.00
Pressure (bar) 1.01 1.01 0.46 0.46
Density (g/L) 1,066.10 994.70 996.58 1,037.91
Total Enthalpy (kW-h) 72.76 18.17 2,370.84 129.35
Specific Enthalpy (kcal/kg) 23.31 24.96 40.63 23.60
Heat Capacity (kcal/kg-°C) 0.93 1.00 0.90 0.94
Component Flowrates (MT/h)
1,3 PDO 0.000 0.000 11.744 0.000
1-2-4 butanetri 0.000 0.000 0.055 0.000
Acetic-Acid 0.000 0.000 0.118 0.000
Ammonia 0.000 0.000 0.000 0.001
Ash 0.000 0.000 0.064 0.016
Calcium Chlorid 0.000 0.000 0.001 0.000
Cell Debris 0.000 0.000 0.156 0.000
Cellulose 0.000 0.000 0.258 0.000
Citric Acid 0.000 0.000 0.014 0.000
Glucose 0.000 0.000 0.024 0.000
Glycerol 0.000 0.000 0.079 0.000
KH2PO4 0.000 0.000 0.019 0.000
MgSO4 0.000 0.000 0.008 0.000
NaCl 0.000 0.000 0.000 0.000
Phosphoric Acid 0.000 0.000 0.018 0.000
Pyruvic Acid 0.000 0.000 0.055 0.000
Sodium Hydroxid 0.000 0.000 0.000 0.139
Sulfuric Acid 0.269 0.000 0.007 0.269
Water 2.418 0.627 37.590 4.291
TOTAL (MT/h) 2.686 0.627 50.211 4.716
TOTAL (m3/h) 2.520 0.630 50.384 4.544
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Stream Name Water Vapor S-302 S-304 S-303
Source P-12 P-12 P-12 P-13
Destination OUTPUT P-13 P-14 P-7
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 60.00 79.13 60.00 79.13
Pressure (bar) 0.20 0.46 0.20 0.46
Density (g/L) 0.13 974.97 1,006.09 974.97
Total Enthalpy (kW-h) 6,149.10 2,338.94 808.33 1,250.42
Specific Enthalpy (kcal/kg) 665.08 78.99 41.45 78.99
Heat Capacity (kcal/kg-°C) 0.45 1.00 0.69 1.00
Component Flowrates (MT/h)
1,3 PDO 0.000 0.000 11.744 0.000
1-2-4 butanetri 0.000 0.000 0.055 0.000
Acetic-Acid 0.000 0.000 0.118 0.000
Ammonia 0.000 0.000 0.000 0.000
Ash 0.000 0.000 0.064 0.000
Calcium Chlorid 0.000 0.000 0.001 0.000
Cell Debris 0.000 0.000 0.156 0.000
Cellulose 0.000 0.000 0.258 0.000
Citric Acid 0.000 0.000 0.014 0.000
Glucose 0.000 0.000 0.024 0.000
Glycerol 0.000 0.000 0.079 0.000
KH2PO4 0.000 0.000 0.019 0.000
MgSO4 0.000 0.000 0.008 0.000
NaCl 0.000 0.000 0.000 0.000
Phosphoric Acid 0.000 0.000 0.018 0.000
Pyruvic Acid 0.000 0.000 0.055 0.000
Sulfuric Acid 0.000 0.000 0.007 0.000
Water 7.955 25.478 4.156 13.621
TOTAL (MT/h) 7.955 25.478 16.778 13.621
TOTAL (m3/h) 61,435.742 26.132 16.676 13.971
- Page 15 -
Stream Name Condensate S-203 Waste-201 S-305
Source P-13 P-7 P-8 P-14
Destination OUTPUT P-8 OUTPUT P-15
Stream Properties
Activity (U/ml) 0.00 0.00 0.00 0.00
Temperature (°C) 79.13 69.10 69.30 145.28
Pressure (bar) 0.46 0.46 0.46 1.01
Density (g/L) 974.97 983.42 992.09 943.89
Total Enthalpy (kW-h) 1,088.52 1,415.93 329.86 1,861.67
Specific Enthalpy (kcal/kg) 78.99 67.08 67.55 102.38
Heat Capacity (kcal/kg-°C) 1.00 0.97 0.97 0.70
Component Flowrates (MT/h)
1,3 PDO 0.000 1.113 0.222 11.509
1-2-4 butanetri 0.000 0.005 0.001 0.000
Acetic-Acid 0.000 0.011 0.002 0.000
Ammonia 0.000 0.000 0.000 0.000
Ash 0.000 0.009 0.002 0.000
Biomass 0.000 0.749 0.724 0.000
Calcium Chlorid 0.000 0.000 0.000 0.000
Cell Debris 0.000 0.015 0.003 0.000
Cellulose 0.000 0.037 0.010 0.000
Citric Acid 0.000 0.001 0.000 0.000
Glucose 0.000 0.002 0.000 0.000
Glycerol 0.000 0.007 0.001 0.000
KH2PO4 0.000 0.002 0.000 0.000
MgSO4 0.000 0.001 0.000 0.000
NaCl 0.000 0.000 0.000 0.000
Phosphoric Acid 0.000 0.002 0.000 0.000
Pyruvic Acid 0.000 0.005 0.001 0.000
Sulfuric Acid 0.000 0.001 0.000 0.000
Water 11.857 16.201 3.232 4.136
TOTAL (MT/h) 11.857 18.161 4.201 15.645
TOTAL (m3/h) 12.162 18.468 4.235 16.575
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Stream Name Waste-302 Waste-303 Product
Source P-14 P-15 P-15
Destination OUTPUT OUTPUT OUTPUT
Stream Properties
Activity (U/ml) 0.00 0.00 0.00
Temperature (°C) 200.53 100.75 213.13
Pressure (bar) 1.01 1.01 1.01
Density (g/L) 1,008.32 967.31 890.03
Total Enthalpy (kW-h) 131.92 489.04 1,696.61
Specific Enthalpy (kcal/kg) 100.25 99.48 127.88
Heat Capacity (kcal/kg-°C) 0.50 0.99 0.60
Component Flowrates (MT/h)
1,3 PDO 0.235 0.115 11.394
1-2-4 butanetri 0.055 0.000 0.000
Acetic-Acid 0.118 0.000 0.000
Ammonia 0.000 0.000 0.000
Ash 0.064 0.000 0.000
Calcium Chlorid 0.001 0.000 0.000
Cell Debris 0.156 0.000 0.000
Cellulose 0.258 0.000 0.000
Citric Acid 0.014 0.000 0.000
Glucose 0.024 0.000 0.000
Glycerol 0.078 0.000 0.000
KH2PO4 0.019 0.000 0.000
MgSO4 0.008 0.000 0.000
NaCl 0.000 0.000 0.000
Phosphoric Acid 0.018 0.000 0.000
Pyruvic Acid 0.055 0.000 0.000
Sulfuric Acid 0.007 0.000 0.000
Water 0.021 4.115 0.021
TOTAL (MT/h) 1.132 4.230 11.415
TOTAL (m3/h) 1.123 4.373 12.826
- Page 17 -
4. OVERALL COMPONENT BALANCE (MT/yr)
COMPONENT IN OUT IN-OUT
1,3 PDO 0 99,503 - 99,503
1-2-4 butanetri 464 464 - 0
Acetic-Acid 1,000 1,000 - 0
Ammonia 1,084 18 1,066
Ash 4,324 4,425 - 100
Biomass 0 6,442 - 6,442
Calcium Chlorid 12 12 - 0
Carb. Dioxide 0 116,960 - 116,960
Cell Debris 0 1,320 - 1,320
Cellulose 14,414 14,415 - 0
Citric Acid 117 117 - 0
Glucose 216,216 9,251 206,965
Glycerol 668 668 - 0
KH2PO4 161 161 - 0
MgSO4 69 69 - 0
NaCl 1 1 - 0
Nitrogen 188,724 188,724 0
Oxygen 57,334 14,637 42,698
Phosphoric Acid 154 154 - 0
Pyruvic Acid 464 464 - 0
Sodium Hydroxid 1,098 1,964 - 867
Sulfuric Acid 2,191 1,743 447
Water 1,315,107 1,341,216 - 26,109
TOTAL 1,803,601 1,803,728 126
Overall Error: 0.007%
- Page 18 -
5. EQUIPMENT CONTENTS
This section will be skipped (overall process is continuous)
- Page 19 -