Required math

Required math: calculus

Required physics: Schrödinger equation

Reference: Griffiths, David
J. (2005), Introduction to Quantum
Mechanics, 2nd Edition; Pearson Education – Chapter 2, Post 20.

While analyzing the free particle, we saw that we could construct a normalizable combination of stationary states by writing

We can find the function  by specifying the initial wave function:

This relation can be inverted by using Plancherel’s theorem, which states

Here we run through a plausibility argument which is a sort of physicist’s proof of Plancherel’s theorem. We start with Dirichlet’s theorem which says that any (physically realistic, anyway) function can be written as a Fourier series. We can show that this is equivalent to a series in complex exponentials. That is

We’ve used the facts that cosine is even and sine is odd. This is equivalent to a Fourier series:

where the coefficients are related by

Inverting the relations we get, for 

We can get the coefficients in terms of  by integration:

The integral is zero if  and  if , so the right hand side comes out to just  and we get

Now we can make the substitutions

If  is the increment in  from one  to the next, then . We can then write the original series as

The formula for  now becomes

Now we can take the limit as . In this case,  (that is, it becomes a differential) and the sum becomes an integral, so we get

In the second formula, the limits on the integral become infinite, and we get the other half of Plancherel’s theorem:

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