Materialy do MS

background image

1

MW: 142 CAS# 124-18-5 C10H22 (m ainlib) Decane

20

30

40

50

60

70

80

90

100

110

120

130

140

150

0

50

100

27

29

39

41

43

53

57

71

85

99

113

142

MW: 142 CAS# 1071-81-4 C10H22 (m ainlib) Hexane, 2,2,5,5-tetram ethyl-

10

20

30

40

50

60

70

80

90

100

110

120

130

140

150

0

50

100

27

29

39

41

43

53

57

69

71

85

127

MW: 142 CAS# 13475-81-5 C10H22 (m ainlib) Hexane, 2,2,3,3-tetram ethyl-

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100

105

110

115

120

125

130

135

140

145

150

0

50

100

39

41

43

44

53

55

57

58

67

69

71

84

85

99

background image

Fragment widma masowego

MW: 92 CAS# 108-88-3 C7H8 (m ainlib) Toluene

20

23

26

29

32

35

38

41

0

50

100

27

38

39

40

masowego toluenu wykreślonego przez pięciokrotny galwanometr.

44

47

50

53

56

59

62

65

68

71

74

77

80

83

45

51

52

63

64

65

66

2

ciokrotny galwanometr.

83

86

89

92

95

98

89

91

92

93

background image

3

MW: 112 CAS# 108-90-7 C6H5Cl (m ainlib) Benzene, chloro-

20

25

30

35

40

45

50

55

60

65

70

75

80

85

90

95

100

105

110

115

120

125

130

0

50

100

38

39

49

51

52

56

75

77

78

112

114

Cl

MW: 252 CAS# 50-32-8 C20H12 (m ainlib) Benzo[a]pyrene

30

40

50

60

70

80

90

100

110

120

130

140

150

160

170

180

190

200

210

220

230

240

250

260

0

50

100

113

126

224

252

MW: 252 CAS# 207-08-9 C20H12 (m ainlib) Benzo[k]fluoranthene

70

80

90

100

110

120

130

140

150

160

170

180

190

200

210

220

230

240

250

260

0

50

100

74

87

99

113

126

200

224

252

background image

4

Tablice Beynona. Masy różnych kombinacji atomów C, H, O i N

(najczęściej występujących

izotopów).

m. cz.

m. cz.

m. cz.

12

H

4

N

2

32,0375

C

2

H

6

0

46,0419

C

12,0000

CH

4

O

32,0262

47

13

33

HNO

2

47,0007

CH

13,0078

HO

2

32,9976

CH

3

O

2

47,0133

14

H

3

NO

33,0215

CH

5

NO

47,0371

N

14,0031

34

48

CH

2

14,0157

H

2

O

2

34,0054

O

3

47,9847

15

38

H

2

NO

2

48,0085

HN

15,0109

C

3

H

2

38,0157

H

4

N

2

O

48,0324

CH

3

15,0235

39

CH

4

O

2

48,0211

16

C

2

HN

39,0109

49

O

15,9949

C

3

H

3

39,0235

H

3

NO

2

49,0164

H

2

N

16,0187

40

52

CH

4

16,0313

C

2

H

2

N

40,0187

C

4

H

4

52,0313

17

C

3

H

4

40,0313

53

HO

17,0027

41

C

3

H

3

N

53,0266

H

3

N

17,0266

CHN

2

41,0140

C

4

H

5

53,0391

18

C

2

H

3

N

41,0266

54

H

2

O

18,0106

C

3

H

5

41,0391

C

2

H

2

N

2

54,0218

24

42

C

3

H

2

O

54,0106

C

2

24,0000

N

3

42,0093

C

3

H

4

N

54,0344

26

CNO

41,9980

C

4

H

6

54,0470

CN

26,0031

CH

2

N

2

42,0218

55

C

2

H

2

26,0157

C

2

H

2

O

42,0106

C

2

H

3

N

2

55,0297

27

C

2

H

4

N

42,0344

C

3

H

3

O

55,0184

CHN

27,0109

C

3

H

6

42,0470

C

3

H

5

N

55,0422

C

2

H

3

27,0235

43

C

4

H

7

55,0548

28

HN

3

43,0170

56

N

2

28,0062

CHNO

43,0058

C

2

O

2

55,9898

CO

27,9949

CH

3

N

2

43,0297

C

2

H

2

NO

56,0136

CH

2

N

28,0187

C

2

H

3

O

43,0184

C

2

H

4

N

2

56,0375

C

2

H

4

28,0313

C

2

H

5

N

43,0422

C

3

H

4

O

56,0262

29

C

3

H

7

43,0548

C

3

H

6

N

56,0501

HN

2

29,0140

44

C

4

H

8

56,0626

CHO

29,0027

N

2

O

44,0011

57

CH

3

N

29,0266

CO

2

43,9898

C

2

H

3

NO

57,0215

C

2

H

5

29,0391

CH

2

NO

44,0136

C

2

H

5

N

2

57,0453

30

CH

4

N

2

44,0375

C

3

H

5

O

57,0340

NO

29,9980

C

2

H

4

O

44,0262

C

3

H

7

N

57,0579

H

2

N

2

30,0218

C

2

H

6

N

44,0501

C

4

H

9

57,0705

CH

2

O

30,0106

C

3

H

8

44,0626

58

CH

4

N

30,0344

45

CH

2

N

2

O

58,0167

C

2

H

6

30,0470

CH

3

NO

45,0215

CH

4

N

3

58,0406

31

CH

5

N

2

45,0453

C

2

H

2

O

2

58,0054

HNO

31,0058

C

2

H

5

0

45,0340

C

2

H

4

NO

58,0293

H

3

N

2

31,0297

C

2

H

7

N

45,0579

C

3

H

6

N

2

58,0532

CH

3

O

31,0184

46

C

3

H

6

O

58,0419

CH

5

N

31,0422

NO

2

45,9929

C

3

H

8

N

58,0657

32

CH

2

O

2

46,0054

C

4

H

10

58,0783

O

2

31,9898

CH

4

NO

46,0293

59

H

2

NO

32,0136

CH

6

N

2

46,0532

CHNO

2

59,0007

background image

5

m. cz.

m. cz.

m. cz.

C

11

H

13

O

4

209,0814

C

16

H

18

210,1409

C

13

H

8

O

3

212,0473

C

11

H

15

NO

3

209,1052

211

C

13

H

10

NO

2

212,0712

C

11

H

17

N

2

O

2

209,1291

C

9

H

11

N

2

O

4

211,0719

C

13

H

12

N

2

O

212,0950

C

11

H

19

N

3

O

209,1529

C

9

H

13

N

3

O

3

211,0958

C

13

H

14

N

3

212,1189

C

11

H

21

N

4

209,1768

C

9

H

15

,N

4

O

2

211,1196

C

13

H

24

O

2

212,1777

C

12

H

9

N

4

209,0829

C

10

H

13

NO

4

211,0845

C

13

H

26

NO

212,2015

C

12

H

17

O

3

209,1178

C

10

H

15

N

2

O

3

211,1083

C

13

H

28

N

2

212,2254

C

12

H

19

NO

2

209,1416

C

10

H

17

N

3

O

2

211,1322

C

14

H

12

O

2

212,0837

C

12

H

21

N

2

O

209,1655

C

10

H

19

N

4

O

211,1560

C

14

H

14

NO

212,1076

C

12

H

23

N

3

209,1894

C

11

H

7

N

4

O

211,0621

C

14

H

16

N

2

212,1315

C

13

H

9

N

2

O

209,0715

C

11

H

15

O

4

211,0970

C

14

H

28

O

212,2141

C

13

H

11

N

3

209,0954

C

11

H

17

NO

3

211,1209

C

14

H

30

N

212,2380

C

13

H

21

O

2

209,1542

C

11

H

19

N

2

O

2

211,1447

C

15

H

16

O

212,1202

C

13

H

23

NO

209,1781

C

11

H

21

N

3

O

211,1686

C

15

H

18

N

212,1440

C

13

H

25

N

2

209,2019

C

11

H

23

N

4

211,1925

C

15

H

32

212,2505

C

14

H

9

O

2

209,0603

C

12

H

9

N

3

O

211,0746

C

16

H

20

212,1566

C

14

H

11

NO

209,0841

C

12

H

11

N

4

211,0985

213

C

14

H

13

N

2

209,1080

C

12

H

19

O

3

211,1334

C

9

H

13

N

2

O

4

213,0876

C

14

H

25

O

209,1906

C

12

H

21

NO

2

211,1573

C

9

H

15

N

3

O

3

213,1114

C

14

H

27

N

209,2145

C

12

H

23

N

2

O

211,1811

C

9

H

17

N

4

O

2

213,1353

C

15

H

13

0

209,0967

C

12

H

25

N

3

211,2050

C

10

H

15

NO

4

213,1001

C

15

H

15

N

209,1205

C

13

H

9

NO

2

211,0634

C

10

H

17

N

2

O

3

213,1240

C

15

H

29

209,2270

C

13

H

11

N

2

O

211,0872

C

10

H

19

N

3

O

2

213,1478

C

16

H

17

209,1331

C

13

H

13

N

3

211,1111

C

10

H

21

N

4

O

213,1717

210

C

13

H

23

O

2

211,1699

C

11

H

7

N

3

O

2

213,0539

C

9

H

10

N

2

O

4

210,0641

C

13

H

25

NO

211,1937

C

11

H

9

N

4

O

213,0777

C

9

H

12

N

3

O

3

210,0879

C

13

H

27

N

2

211,2176

C

11

H

17

O

4

213,1127

C

9

H

14

N

4

O

2

210,1118

C

14

H

11

O

2

211,0759

C

11

H

19

NO

3

213,1365

C

10

H

12

NO

4

210,0766

C

14

H

13

NO

211,0998

C

11

H

21

N

2

O

2

213,1604

C

10

H

14

N

2

O

3

210,1005

C

14

H

15

N

2

211,1236

C

11

H

23

N

3

O

213,1842

C

10

H

16

N

3

O

2

210,1244

C

14

H

27

O

211,2063

C

11

H

25

N

4

213,2081

C

10

H

18

N

4

O

210,1482

C

14

H

29

N

211,2301

C

12

H

9

N

2

O

2

213,0664

C

11

H

14

O

4

210,0892

C

15

H

15

O

211,1123

C

12

H

11

N

3

O

213,0903

C

11

H

16

NO

3

210,1131

C

15

H

17

N

211,1362

C

12

H

13

N

4

213,1142

C

11

H

18

N

2

O

2

210,1369

C

15

H

31

211,2427

C

12

H

21

O

3

213,1491

C

11

H

20

N

3

O

210,1608

C

16

H

19

211,1488

C

12

H

23

NO

2

213,1730

C

11

H

22

N

4

210,1846

212

C

12

H

25

N

2

O

213,1968

C

12

H

8

N

3

O

210,0668

C

9

H

12

N

2

O

4

212,0797

C

12

H

27

N

3

213,2207

C

12

H

10

N

4

210,0907

C

9

H

14

N

3

O

3

212,1036

C

13

H

9

O

3

213,0552

C

12

H

18

O

3

210,1256

C

9

H

16

N

4

O

2

212,1275

C

13

H

11

NO

2

213,0790

C

12

H

20

NO

2

210,1495

C

10

H

14

NO

4

212,0923

C

13

H

13

N

2

O

213,1029

C

12

H

22

N

2

O

210,1733

C

10

H

16

N

2

O

3

212,1162

C

13

H

15

N

3

213,1267

C

12

H

24

N

3

210,1972

C

10

H

18

N

3

O

2

212,1400

C

13

H

25

O

2

213,1855

C

13

H

8

NO

2

210,0555

C

10

H

20

N

4

O

212,1639

C

13

H

27

NO

213,2094

C

13

H

10

N

2

O

210,0794

C

11

H

8

N

4

O

212,0699

C

13

H

29

N

2

213,2332

C

13

H

12

N

3

210,1032

C

11

H

16

O

4

212,1049

C

14

H

13

O

2

213,0916

C

13

H

22

O

2

210,1620

C

11

H

18

NO

3

212,1287

C

14

H

15

NO

213,1154

C

13

H

24

NO

210,1859

C

11

H

20

N

2

O

2

212,1526

C

14

H

17

N

2

213,1393

C

13

H

26

N

2

210,2098

C

11

H

22

N

3

O

212,1764

C

14

H

29

O

213,2219

C

14

H

10

O

2

210,0681

C

11

H

24

N

4

212,2003

C

15

H

17

O

213,1280

C

14

H

12

NO

210,0919

C

12

H

8

N

2

O

2

212,0586

C

15

H

19

N

213,1519

C

14

H

14

N

2

210,1158

C

12

H

10

N

3

O

212,0825

C

16

H

21

213,1644

C

14

H

26

O

210,1985

C

12

H

12

N

4

212,1063

214

C

14

H

28

N

210,2223

C

12

H

20

O

3

212,1413

C

9

H

14

N

2

O

4

214,0954

C

15

H

14

O

210,1045

C

12

H

22

NO

2

212,1651

C

9

H

16

N

3

O

3

214,1193

C

15

H

16

N

210,1284

C

12

H

24

N

2

O

212,1890

C

9

H

18

N

4

O

2

214,1431

C

15

H

30

210,2349

C

12

H

26

N

3

212,2129

C

10

H

16

NO

4

214,1080

background image

6



18.0 2.9
26.0 1.0
36.0 1.3
37.0 6.9
38.0 11.7
49.0 5.8
50.0 39.0
51.0 5.4
61.0 1.7
73.0 6.8
74.0 26.4
75.0 44.7

76.0 29.9
77.0 5.3
78.0 4.9
79.0 1.2
81.0 1.2
117.0 3.8
118.0 6.5
119.0 3.5
128.0 1.0
129.0 1.5
130.0 1.1
131.0 1.3

155.0 42.8
156.0 3.7
157.0 41.5
158.0 2.6
234.0 51.4
235.0 3.7
236.0 100.0
237.0 6.8
238.0 49.6
239.0 3.3

background image

7

27.0 5.1
39.0 3.6
41.0 3.1
43.0 2.6
50.0 4.2
51.0 15.6
52.0 1.4
55.0 2.1
65.0 1.2

74.0 1.4
75.0 1.1
76.0 2.0
77.0 48.4
78.0 5.6
91.0 2.1
105.0 100.0
106.0 8.6
119.0 1.5

120.0 10.4
121.0 1.0
130.0 1.1
133.0 1.6
147.0 1.4
148.0 16.0
149.0 1.7


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