P20 074

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74.

(a) When n = 1, V = V

m

= RT /p, where V

m

is the molar volume of the gas. So

V

m

=

RT

p

=

(8.31 J/mol

·K)(273.15K)

1.01

× 10

5

Pa

= 22.5 L .

(b) We use v

rms

=



3RT /M . The ratio is given by

v

rms,He

v

rms,Ne

=



M

Ne

M

He

=



20 g

4.0 g

= 2.25 .

(c) We use λ

He

= (

2πd

2

N/V )

1

, where the number of particles per unit volume is given by N/V =

N

A

n/V = N

A

p/RT = p/kT . So

λ

He

=

1

2πd

2

(p/kT )

=

kT

2πd

2

p

=

(1.38

× 10

23

J/K)(273.15K)

1.414π(1

× 10

10

m)

2

(1.01

× 10

5

Pa)

= 0.84 µm .

(d) λ

Ne

= λ

He

= 0.84 µm.


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