chf tch I cr 001a

background image

U q w

= +

dw

P dv

z

= − ⋅

PV

const

γ

=

H U

PV

=

+

γ

= C

C

P

V

/

G H TS

=

dG VdP SdT

=

A U

TS

=

dA

PdV

SdT

= −

U

nC T

v

=

H nC T

p

=

H

H

C dT

T

T

P

T

T

2

1

1

2

=

+

S

q

T

odwr

=

dS

C dT

T

PdV

T

v

=

+

S n C

T

T

R

V

V

v

=

+



ln

ln

2

1

2

1

U

H

n RT

g

=

H

n H

n H

r T

i

i tw prod T

i

i

i tw subst T

i

,

, ,

,

, ,

,

0

0

0

=

H

n H

n H

r T

i

i sp subst T

i

i

i sp prod T

i

,

, ,

,

, ,

,

0

0

0

=

G

T

T

H

T

P





= −

2

U q w

= +

dw

P dv

z

= − ⋅

PV

const

γ

=

H U

PV

=

+

γ

= C

C

P

V

/

G H TS

=

dG VdP SdT

=

A U

TS

=

dA

PdV

SdT

= −

U

nC T

v

=

H nC T

p

=

H

H

C dT

T

T

P

T

T

2

1

1

2

=

+

S

q

T

odwr

=

dS

C dT

T

PdV

T

v

=

+

S n C

T

T

R

V

V

v

=

+



ln

ln

2

1

2

1

U

H

n RT

g

=

H

n H

n H

r T

i

i tw prod T

i

i

i tw subst T

i

,

, ,

,

, ,

,

0

0

0

=

H

n H

n H

r T

i

i sp subst T

i

i

i sp prod T

i

,

, ,

,

, ,

,

0

0

0

=

G

T

T

H

T

P





= −

2

U q w

= +

dw

P dv

z

= − ⋅

PV

const

γ

=

H U

PV

=

+

γ

= C

C

P

V

/

G H TS

=

dG VdP SdT

=

A U

TS

=

dA

PdV

SdT

= −

U

nC T

v

=

H nC T

p

=

H

H

C dT

T

T

P

T

T

2

1

1

2

=

+

S

q

T

odwr

=

dS

C dT

T

PdV

T

v

=

+

S n C

T

T

R

V

V

v

=

+



ln

ln

2

1

2

1

U

H

n RT

g

=

H

n H

n H

r T

i

i tw prod T

i

i

i tw subst T

i

,

, ,

,

, ,

,

0

0

0

=

H

n H

n H

r T

i

i sp subst T

i

i

i sp prod T

i

,

, ,

,

, ,

,

0

0

0

=

G

T

T

H

T

P





= −

2

U q w

= +

dw

P dv

z

= − ⋅

PV

const

γ

=

H U

PV

=

+

γ

= C

C

P

V

/

G H TS

=

dG VdP SdT

=

A U

TS

=

dA

PdV

SdT

= −

U

nC T

v

=

H nC T

p

=

H

H

C dT

T

T

P

T

T

2

1

1

2

=

+

S

q

T

odwr

=

dS

C dT

T

PdV

T

v

=

+

S n C

T

T

R

V

V

v

=

+



ln

ln

2

1

2

1

U

H

n RT

g

=

H

n H

n H

r T

i

i tw prod T

i

i

i tw subst T

i

,

, ,

,

, ,

,

0

0

0

=

H

n H

n H

r T

i

i sp subst T

i

i

i sp prod T

i

,

, ,

,

, ,

,

0

0

0

=

G

T

T

H

T

P





= −

2


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