Structure and reactivity of alkenes and alkynes

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Burrows et al: Chemistry

3

- Summaries & learning outcomes

OXFORD H i g h e r E d u c a t i o n

© Oxford University Press, 2009. All rights reserved.

21

Alkenes and alkynes:
electrophilic addition and
pericyclic reactions

21.1

Structure and reactivity of alkenes and alkynes

C=C and C

≡C bonds react with electrophiles in electrophilic addition

reactions.

21.2

Preparation of alkenes and alkynes

Alkenes are prepared from halogenoalkanes, alcohols, alkynes, and
aldehydes/ketones.

background image

Burrows et al: Chemistry

3

- Summaries & learning outcomes

OXFORD H i g h e r E d u c a t i o n

© Oxford University Press, 2009. All rights reserved.

Alkynes are prepared from 1,2-dibromoalkanes.

Substituted alkynes are prepared by alkylation of alkynyl anions with
halogenoalkanes.

21.3

Electrophilic addition reactions of alkenes

Seven important addition reactions involving alkenes.

21.4

Pericyclic reactions of alkenes

Important pericyclic reactions involving alkenes.

background image

Burrows et al: Chemistry

3

- Summaries & learning outcomes

OXFORD H i g h e r E d u c a t i o n

© Oxford University Press, 2009. All rights reserved.

21.5

Electrophilic addition reactions of alkynes

Two important electrophilic addition reactions of alkynes.

• HC

≡CH and RC≡CH react with strong bases to form alkynylmetal reagents

(for example, HC

≡CNa), which can act as nucleophiles.

Learning outcomes

By the end of this chapter you should be able to do the following.

Describe how alkenes are prepared from halogenoalkanes, alcohols, alkynes,
and aldehydes/ketones.

Describe how alkynes are prepared from 1,2-dibromoalkanes and how
substituted alkynes are prepared by alkylation of alkynyl anions (RC

≡C

) with

halogenoalkanes.

Understand how C=C and C

≡C bonds react in electrophilic addition reactions.

background image

Burrows et al: Chemistry

3

- Summaries & learning outcomes

OXFORD H i g h e r E d u c a t i o n

© Oxford University Press, 2009. All rights reserved.

Write reaction mechanisms to explain how C=C bonds undergo the addition
reactions shown below.

Write reaction mechanisms to explain how C=C bonds undergo the pericyclic
reactions shown below.

Write reaction mechanisms to explain how C

≡C bonds undergo the addition

reactions shown below.


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