------------------------------------ Kolokwium 2. kinetyka 12.05.08
imi

LQD]ZLVNR>ZW 12 wt 13

UU@

1

2

3

4

5

6

7

Σ

Σ

=DGSNW

%DGDQR VSHNWURVNRSRZR L]RPHU\]DFM FKORUNX FLVGZXHW\OHQRGZXDPLQRGZXFKORUNX NREDOWX,,, Z

PHWDQROXELHJQFZ

R

&QLHRGZUDFDOQLH2WU]\PDQRQDVWSXMFHGDQHGRW\F]FHHNVW\QNFML(SU]\

PDNVLPXPSLNXDEVRUSF\MQHJRRGSRZLDGDMFHJRGáXJRFLIDOLλ QPMDNRIXQNFMLF]DVX

WPLQ

⋅

(

=DNáDGDMF*HQDSRF]WNXLNRFXGRZLDGF]HQLDREMWRüPLHV]DQLQ\UHDNF\MQHM9 GP

D

SURPLHQLRZDQLHMHVWSRFKáDQLDQHW\ONRSU]H]VXEVWUDWZ\]QDF]\üU]GUHDNFMLLMHMF]DVSyáWUZDQLD

=DGSNW

'RUHDNWRUDRREMWRFLGP

]DZLHUDMFHJRVXEVWUDW$GRGDQR%NWyUHMHVWUyZQLH*SURGXNWHP

UHDNFMLWDN*HVW*HQLHSRF]WNRZH$Z\QRVLPRO⋅GP

D%MHVWUyZQHPRO⋅GP

6]\ENRüUHDNFML

$

B

 →



%&MHVWZSURVWSURSRUFMRQDOQD]DUyZQRGRVW*HQLDF

$

MDNLF

%

6WDáDV]\ENRFLUHDNFMLZ

WHPSHUDWXU]H

R

&Z\QRVL

PRO

GP

V

2EOLF]\üF]DVSRXSá\ZLHNWyUHJRV]\ENRüUHDNFMLRVLJQLH

ZDUWRüPDNV\PDOQ

=DGSNW ) k

1

6WDáDUyZQRZDJLSHZQHMRGZUDFDOQHM reakcji pierwszego U]GX$⇔%Z\QRVL6WDáDV]\ENRFL

N

WZRU]HQLDSURGXNWyZN

Â

V

-DNLSURFHQWSURGXNWyZZVWRVXQNXGRLFKLORFLZVWDQLH

UyZQRZDJLSRZVWDQLHSRXSá\ZLHSyáJRG]LQ\RGFKZLOL]DSRF]WNRZDQLDUHDNFML"
Zad.4.( 4 pkt).

:\]QDF]RQR VWDáH V]\ENRFL UHDNFML ]DFKRG]FHM Z ID]LH FLHNáHM $ % ⇒ & ' Z Uy*Q\FK

WHPSHUDWXUDFK
t/

o

C

25

40

50

60

75

k/s

-1

1,4⋅10

-5

7,62⋅10

-5

2,16⋅10

-4

5,75⋅10

-4

2,25⋅10

-3

2EOLF]\üHQHUJLDNW\ZDFMLRUD]F]\QQLNSU]HGZ\NáDGQLF]\
Zad.5. (3 pkt )

5HDNFMD%U

&+

→+%U&+

%UPR*H]DFKRG]LüZJQDVWSXMF\FKHWDSyZHOHPHQWDUQ\FK

N

N

N

R

%U

⇔%U

•

%U

•

R

%U

•

&+

⇔&+

•

+%U

R

&+

•

%U

⇒%U

•

&+

%U

N

N

:\SURZDG(UyZQDQLHNLQHW\F]QHWZRU]HQLDEURPNXPHW\OX

=DGSNW

%DGDQRMHGQRF]VWHF]NRZUHDNFM$→%SU]HELHJDMFZ

R

&VDPRU]XWQLH*G\]DVWRVRZDQR

NDWDOL]DWRUZWHMVDPHMWHPSHUDWXU]HVWDáDV]\ENRFLUHDNFML]ZLNV]\áDVLNURWQLH=DNáDGDMF*H

HQWURSLDDNW\ZDFML]PQLHMV]\áDVLW\ONRR-PRO⋅.REOLF]RLOH]PQLHMV]\áDVLHQHUJLDDNW\ZDFMLZ

Z\QLNX]DVWRVRZDQLDNDWDOL]DWRUD
Zad.7 (2 pkt )

2PyZ SR]QDQH PHFKDQL]P\ Z UHDNFMDFK XWOHQLDQLD FLDáD VWDáHJR QS NRUR]MD FKHPLF]QD L SRGDM

FKDUDNWHU\]XMFHMHW\S\NU]\Z\FKNLQHW\F]Q\FK

:DUWRFLVWDá\FK5 -⋅PRO

⋅

.

K ⋅

-⋅VN

%

⋅

-⋅.

1 ⋅

PRO

) &⋅PRO

$ZUyZQDQLX'+

R

&+

2 GP

⋅

PRO