Microwave air and microwave finish drying of banana (Maskan)
Journal of Food Engineering 44 (2000) 71ą78 www.elsevier.com/locate/jfoodeng Microwave/air and microwave nish drying of banana Medeni Maskan Department of Food Engineering, Engineering Faculty, University of Gaziantep, 27310 Gaziantep, Turkey Received 16 July 1999; accepted 6 December 1999 Abstract Banana samples (4:3 0:177; 7:4 0:251 and 14 0:492 mm thick) were dried using the following drying regimes; convection (60C at 1.45 m/s); microwave (350, 490 and 700 W power) and convection followed by microwave (at 350 W, 4.3 mm thick sample) nish drying. The drying of banana slices took place in the falling rate drying period with convection drying taking the longest time. Higher drying rates were observed with the higher power level. Microwave nish drying reduced the convection drying time by about 64.3%. A physical model was employed to t the experimental data and gave good t for all experimental runs except mi- crowave nish data. Microwave nish dried banana was lighter in colour and had the highest rehydration value. Ó 2000 Published by Elsevier Science Ltd. All rights reserved. Notation rious damage to the Żavour, colour, nutrients, reduction k drying constant (min 1) in bulk density and rehydration capacity of the dried MR moisture ratio product (Lin, Durance & Scaman, 1998; Drouzas, MW microwave Tsami & Saravacos, 1999). Major disadvantages of hot r2 coecient of determination S.E. standard error air drying of foods are low energy eciency and lengthy t drying time (min) drying time during the falling rate period. Because of the Wd weight of dried sample (g) low thermal conductivity of food materials in this peri- Wt weight of rehydrated sample (g) at any time od, heat transfer to the inner sections of foods during X moisture content (kg H2O/kg dry solids) at any time conventional heating is limited (Adu & Otten, 1996; Xe equilibrium moisture content (kg H2O/kg dry solids) Xo initial moisture content (kg H2O/kg dry solids) Feng & Tang, 1998). The desire to eliminate this prob- lem, prevent signicant quality loss, and achieve fast and eective thermal processing has resulted in the in- 1. Introduction creasing use of microwaves for food drying. Microwave drying is rapid, more uniform and energy ecient Banana is one of the important high sugar containing compared to conventional hot air drying. In this case, tropical fruit crops grown commercially in many coun- the removal of moisture is accelerated and, furthermore, tries. It is very susceptible to deterioration and consid- heat transfer to the solid is slowed down signicantly erable amounts of this fruit is wasted due to the lack of due to the absence of convection. And also because of ecient preservation techniques that are unique to ba- the concentrated energy of a microwave system, only nana. An alternative method seems to be drying to ob- 20ą35% of the Żoor space is required, as compared to tain a stable banana for further use. conventional heating and drying equipment. However, Drying is one of the oldest methods of food preser- microwave drying is known to result in a poor quality vation and it is a dicult food processing operation product if not properly applied (Yongsawatdigul & mainly because of undesirable changes in quality of the Gunasekaran, 1996a; Adu & Otten, 1996; Drouzas & dried product. High temperatures and long drying times, Schubert, 1996). required to remove the water from the sugar containing It has also been suggested that microwave energy fruit material in conventional air drying, may cause se- should be applied in the falling rate period or at a low moisture content for nish drying (Prabhanjan, Ra- maswamy & Raghavan, 1995; Kostaropoulos & Sarav- E-mail address: maskan@gantep.edu.tr (M. Maskan). acos, 1995; Funebo & Ohlsson, 1998). The reason for 0260-8774/00/$ - see front matter Ó 2000 Published by Elsevier Science Ltd. All rights reserved. PII: S 0 2 6 0 - 8 7 7 4 ( 9 9 ) 0 0 167- 3 72 M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 this is essentially economic. Due to high cost, microwave shorter drying times compared with hot air drying can not compete with conventional air drying. However, alone. microwaves may be advantageous in the last stages of The objectives of this study are to: (1) compare drying air drying. Because the least ecient portion of a con- characteristics, colour and rehydration of banana sam- ventional drying system is near the end, when two-thirds ples dried by hot air, microwave and hot air followed by of the time may be spent removing the last one-third of a microwave nish drying; (2) determine the drying the moisture content (Al-Duri & McIntyre, 1992). constants, using a simple diusion model (Eq. (1)) and assess the eect of selected parameters such as drying temperature, sample thickness and microwave power. X Xe MR exp ktą: 1ą 2. Microwave principles and application to drying of foods Xo Xe For microwave drying it can be assumed that Xe 0. Microwaves are electromagnetic waves in the fre- quency range of 300 MHz to 300 GHz (equivalent to a wavelength of 1ą0.01 m), generated by a magnetron- 3. Materials and methods type vacuum tube. Electromagnetic energy at 915 and 2450 MHz can be absorbed by water containing mate- 3.1. Material rials or other ``lossy'' substances, such as carbon and some organics, and converted to heat (Khraisheh, Ripe bananas (Musa species) with an initial moisture Cooper & Magee, 1997a). Because the waves can pene- content of 3.1 kg H2O/kg dry solids were obtained from trate directly into the material, heating is volumetric a local supermarket and stored at 4 0:5C. Prior to (from the inside out) and provides fast and uniform drying, samples were taken out of storage, hand peeled, heating throughout the entire product. The quick energy cut into 4:3 0:177; 7:4 0:251; 14 0:492 mm thick absorption by water molecules causes rapid evaporation and 30 0:901 mm diameter slices (where shows of water (results in higher drying rates of the food), standard deviation of measurements) with a cutting creating an outward Żux of rapidly escaping vapour. In machine. At least 10 measurements of the thickness were addition to improving the rate of drying, this outward made at dierent points with a dial micrometer; only Żux can help to prevent the shrinkage of tissue structure, slices that fell within a 5% range of the average thickness which prevails in most conventional air drying tech- were used. All bananas used for drying were from the niques. Hence better rehydration characteristics may be same batch. expected in microwave dried products (Prabhanjan et al., 1995). In recent years, microwave drying has gained popu- 3.2. Drying equipment larity as an alternative drying method for a wide variety A programmable domestic microwave oven (Arcelik
of food products such as fruits, vegetables, snack foods ARMD 580, TURKEY), with maximum output of and dairy products. Several food products have been 700 W at 2450 MHz. was used. The oven has the facility successfully dried by the microwave-vacuum application to adjust power (wattage) supply and the time of pro- and/or by a combined microwave assisted-convection cessing. The hot air drying experiments were performed process. These authors included Kim and Bhowmik (1995) for plain yogurt, Yongsawatdigul and Gunasek- in a pilot plant tray dryer (UOP 8 tray dryer, Armeld, UK). The dryer (Fig. 1) consisted of a proportional (P) aran (1996a) for cranberries, Lin et al. (1998) for carrot controller controlling the temperature. Air was drawn slices, Drouzas et al. (1999) for model fruit gels, Al-Duri into the duct through a mesh guard by a motor driven and McIntyre (1992) for skimmed milk, whole milk, axial Żow fan impeller whose speed can be controlled in casein powders, butter and fresh pasta, Bouraout, Richard and Durance (1994) for potato slices, Prab- the duct. hanjan et al. (1995) for carrots, Tulasidas, Raghavan and Norris (1996) for grapes, Funebo and Ohlsson 3.3. Drying procedure (1998) for apple and mushroom, and Ren and Chen (1998) for American ginseng roots. The drying regimes were as follows: Another group of researchers proposed a two-stage (1) Hot air drying: The dryer was operated at an air drying process involving an initial forced air convective velocity of 1.45 m/s, parallel to the drying surface of the drying, followed by a microwave nish drying (Prab- sample, 60C dry bulb and 30C wet bulb temperatures. hanjan et al., 1995; Feng & Tang, 1998). Microwave The three sample thicknesses were studied at constant application has been reported to improve product temperature. Moisture loss was recorded at 10 min inter- quality such as better aroma, faster and better rehy- vals during drying for determination of drying curves dration, considerable savings in energy and much by a digital balance (Avery Berkel, CC062D10ABAAGA). M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 73 Fig. 1. Schematic diagram of the hot air drying equipment (not to scale). Bananas were dried until equilibrium (no weight change) colour and rehydration was performed (within one week was reached. after the drying). (2) Microwave drying: Factors investigated in micro- wave drying were microwave power intensity (350, 490 3.4.1. Colour and 700 W) at constant sample thickness of 4.3 mm, and Sample colour was measured before and after drying sample thickness/load (4.3 mm/3.56 g, 7.4 mm/5.60 g by a HunterLab ColorFlex, A60-1010-615 model col- and 14.0 mm/11.85 g) at constant microwave power ormeter (HunterLab., Reston, VA). The colour values output of 490 W. One glass petri dish (7.1 cm diameter were expressed as L (whiteness/darkness), a (redness/ 1:2 cm deep), containing the sample, was placed on the greenness) and b (yellowness/blueness). And also, the centre of a turntable tted inside (bottom) the micro- total colour dierence from the fresh bananas DE, as wave cavity during treatment for even absorption of dened the following, was used to describe the colour microwave energy. The presence of the turntable was change during drying: q necessary to achieve the optimum oven performance and 2 2 2 DE L o L a o a b o b ; 2ą to reduce the levels of reŻected microwaves onto the magnetron (Khraisheh et al., 1997b). The drying was where subscript ``o'' refers to the colour reading of fresh performed according to a preset power and time banana, L ; a and b indicate brightness, redness and schedule. Moisture loss was measured by taking out and yellowness of dried samples respectively. Fresh banana weighing the dish on the digital balance periodically. was used as the reference and a larger DE denotes When the material reached a constant weight, equilib- greater colour change from the reference material. rium moisture content was assumed to be reached. At- tention was paid to ensure that the sample was not 3.4.2. Rehydration charred. The dried samples were manually ground and im- (3) Air followed by a microwave nish drying: A4.3 mm mediately loaded (about 0.5 g each) into small alumi- thick banana sample was dried at 60C and 1.45 m/s air nium sample dishes. 100 ml of distilled water was velocity to 1.25 kg H2O/kg dry solids moisture content, transferred into a glass jar and a tripod was also placed the point where drying slows down. Then, sample was in the jar. The dishes were placed on tripod in the jar taken out and dried in the microwave oven. Some pre- which was then tightly closed and kept at 20C for liminary tests conducted on partially air dried sample equilibration. The dishes were periodically weighed until resulted in burning of sample at high microwave power equilibrium was reached. The rehydration ratio was levels. Hence, a microwave power of 350 W was selected determined by for nish drying purpose. Wt Wdą Weight gain %ą 100: 3ą Wd 3.4. Quality evaluation For quality evaluation, similar drying experiments 3.5. Statistical analysis were conducted separately under the same microwave, hot air and microwave nish drying conditions. Drying Analysis of variance (ANOVA was conducted to de- ANOVA) was terminated when moisture content reached about termine the eect of variable factors on drying param- 0.1 kg H2O/kg dry solids. After the drying tests, samples eters using Statgraphics software (1991). Least-squares were kept in air tight glass jars until measurements of multiple range test was performed to dierentiate the 74 M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 signicant eect of drying methods on drying rate. The parameter of non-linear model (Eq. (1)) was calculated by the NLIN procedure of the SigmaPlot (Scientic Graph System, version 4.00, Jandel). 4. Results and discussion 4.1. Hot air drying The moisture content versus time curves for hot air drying of banana samples as inŻuenced by thickness are shown in Fig. 2. Obviously, as the thickness of the sample increased, the time required to achieve a certain moisture content increased. For example, the drying Fig. 3. Drying rate curves of banana slices dried by hot air (60C and times for reaching about 0.1 kg H2O/kg dry solids 1.45 m/s). moisture content of 4.3, 7.4 and 14 mm thick samples were about 482, 610 and 777 min respectively at 60C air constant rate period in their study. A high initial drying temperature. These results were in agreement with pre- rate, with higher rates at lower thicknesses, was ob- vious literature studies (Yusheng & Poulsen, 1988; served (Fig. 3). All the samples tended to dry slowly at Madamba, Driscoll & Buckle, 1996; Maskan & Ibano- the last stages of drying, presumably due to collapse glu, 1998). The drying rate was calculated at dierent (shrinkage) of the banana structure resulting in low times and plotted against average moisture content as transport rate of water and prolonged drying time shown in Fig. 3. A constant rate period was not ob- (Kostaropoulos & Saravacos, 1995). served in hot air drying of banana samples at 60C. Hence, the entire drying process for the samples oc- curred in the range of falling rate period in this study. 4.2. Microwave drying However, it might be possible to have a short constant rate period using lower temperatures such as 40ą50C. The eect of changing the power output in the mi- It has been reported that almost all of the drying of crowave oven on the moisture content curve of 4.3 mm biological products takes place in the falling rate period thick banana sample is shown in Fig. 4. At all power (Madamba et al., 1996). However, Mowlah, Takano, levels, drying curves were steeper and tended to end at Kamoi and Obara (1983) have found both constant and about the same time. The observed initial acceleration of falling rate periods in dehydration of bananas at 60Cin drying may be caused by an opening of the physical an air circulated oven. Air in the oven is saturated, by structure allowing rapid evaporation and transport of the time, and forms a thick lm around the food that water (Kostaropoulos & Saravacos, 1995). The ANOVA ANOVA prevents eective separation of the evaporated moisture showed no eect of the intensity of power on moisture from the food. This may be the reason for existence of a Fig. 4. Drying curves of banana slice (4:3 0:177 mm) dried by mi- Fig. 2. Air drying curves for banana slices (air at 60C and 1.45 m/s). crowave method with dierent microwave power levels. M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 75 loss (P > 0:05). Similar results were obtained by Walde, karan, 1996b). Due to that, the 14 and 7.4 mm thick Balaswamy, Sivaswamy, Chakkaravarthi and Rao samples spread on the bottom of the dishes as a thin (1995) for microwave drying of gum karaya and layer, a large drying surface area formed hence, drying Yongsawatdigul and Gunasekaran (1996b) for micro- accelerated (data were not shown). Only the thin sample wave-vacuum drying of cranberries. However, several (4.3 mm) maintained its shape without spreading and it investigators have reported the eect of power output on took much time to dry this sample compared to the drying time of food materials (Al-Duri & McIntyre, others. The drying times were found to be about 18, 13 1992; Prabhanjan et al., 1995; Drouzas & Schubert, and 10 min at 490 W for 4.3, 7.4 and 14 mm thick 1996). Fig. 5 shows the eect of drying conditions on the samples to reach a moisture content of about 0.1 kg drying rate. Although high moisture foods can be ex- H2O/kg dry solids. pected to have a period of constant rate drying, this was not observed in the present study under any of the test 4.3. Microwave nish drying conditions. The total drying times required to reach a nal moisture content of about 0.1 kg H2O/kg dry solids Banana sample (4.3 mm thick) was hot-air dried at were 13, 18 and 27 min at 700, 490 and 350 W, respec- 60C initially, then microwave energy was applied (to tively. These results show that the drying time of the the point where conventional drying is very slow) for 4.3 mm thick sample was shortened from 482 min by hot nish drying. The drying rate versus average moisture air drying to the 13ą27 min range when dried by mi- content curve was presented in Fig. 6. It can be seen that crowave energy. ANOVA results showed a signicant ANOVA microwave nish application increased the drying rate dierence (P < 0:05) between drying rates of hot air and signicantly (over 0.8 kg water/kg dry solids/min). The microwave drying techniques. Average drying rate over same sample has an initial drying rate value of about the drying periods was 0.0088 kg water/kg dry solids/ 0.035 kg water/kg dry solids/min (Fig. 3) when air dried, min for air dried, and between 0.0880 and 0.2027 kg 0.4 kg water/kg dry solids/min when microwave dried at water/kg dry solids/min for microwave dried 4.3 mm 350 W microwave power output (Fig. 5). This applica- thick banana sample in the 350ą700 W power range, tion also reduced the drying time from 482 to 172 min respectively. The results indicated that mass transfer (64.3% reduction in drying time) when dried by air and within the sample is rapid during microwave heating nish dried respectively. because heat is generated within the sample, creating a large vapour pressure dierential between the centre and 4.4. Modelling drying curves the surface of products (Lin et al., 1998). Eorts were made to study the eect of the sample In this work, Eq. (1) was employed as a physical thickness (4.3, 7.4, 14 mm) on drying at constant power model for description of the drying processes, rather output (490 W). In contrast to hot air drying, the thicker than a mathematical model (Prabhanjan et al., 1995; sample dried more rapidly than the thin one. It is be- Madamba et al., 1996; Drouzas et al., 1999). Drying cause of sudden and volumetric heating, generating high data were used to test the applicability of this model. pressure inside the bananas, resulted in boiling and The parameter k together with S.E. and r2 were evalu- bubbling of the samples (Yongsawatdigul & Gunase- ated using nonlinear regression. The results are Fig. 5. Drying rate curves of banana slice (4:3 0:177 mm) under Fig. 6. Drying rate of banana slice (4:3 0:177 mm) dried by hot air various microwave power levels. (60C and 1.45 m/s) followed by microwave at 350 W power output. 76 M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 tabulated in Table 1. The model gave good t for all the red colour (low a value) than microwave drying. The experimental runs with r2 values greater than 0.91. It did discoloration during drying may be related to nonen- not adequately t the whole data of microwave nish zymatic browning (Feng & Tang, 1998). No dierences drying experiment. Hence, the tting was done on hot were observed between b values of air and microwave air and microwave nish drying parts separately. In the dried samples. Microwave drying also caused colour case of hot air drying, the drying constant (k) estimated darkening. The dierences between colour values from Eq. (1) was found to increase signicantly as the (L ; a ; b ) of microwave dried samples were not sig- thickness was reduced from 14 to 4.3 mm. However, the nicant (P > 0:05). The change in colour values was not opposite case was observed when banana was dried by dependent on the microwave power intensity. This is not microwave at constant power level (490 W). The reason in agreement with the observation of Funebo and for this was the spreading of the sample as explained Ohlsson (1998). The colour of the microwave nish previously. This may be an advantage in terms of dried sample was much lighter (higher L value) than the shortening drying time, if the nal shape/size is not air and/or microwave dried product. At the same time important for the product. A signicant increase of this drying process decreased the redness (a value) and constant k was observed when the microwave power was increased yellowness (b value). increased from 350 to 700 W. The highest value of k was The total colour change (DE) values, which takes into observed in the case of microwave application which account changes in redness and yellowness, were also indicated that it oered a minimum resistance. compared. Microwave nish drying caused little, and air drying the highest colour change among the drying methods. Drying temperature and time are important parameters for colour change during drying. The lower 4.5. Colour colour degradation of microwave nish dried banana Table 2 shows the results of colour measurements of may, therefore, be due to the substantial reduction in drying time. It is clear that microwave nish drying fresh and dried bananas. Preferred colours are those maintained the colour quality of the fresh bananas com- closest to the original colour of fresh sample. Air drying pared to the hot air and microwave drying methods alone. resulted in a darker slice colour (lower L value) and less Table 1 Nonlinear regression analysis results of Eq. (1) Parameter Drying method Air MW Air-MW nish Thickness (mm) MW powera (W) Thicknessb (mm) Air part MW part 4.3 7.4 14 700 490 350 4.3 7.4 14 K 0.0086 0.0059 0.003 0.268 0.188 0.141 0.188 0.387 0.469 0.0059 1.319 S.E. ( ) 1 10 4 9 10 5 5 10 5 5 10 3 4 10 3 4 10 3 1 10 2 2 10 2 1 10 2 9 10 5 3 10 2 r2 0.992 0.991 0.987 0.995 0.994 0.994 0.916 0.978 0.998 0.988 0.999 a Sample thickness is constant (4:3 0:177 mm). b MW power is constant (490 W). Table 2 Colour parameters of fresh and dried banana slices (4:3 0:177 mm) Parameter Fresh banana Drying method Air MW (W) Air-MW nish 700 490 350 L* 71.01 40.815 53.25 55.13 52.88 62.08 a 3.96 6.32 9.95 9.46 11.70 5.97 b 21.75 14.35 13.37 13.85 16.46 18.00 DE 0.00 31.17 20.53 18.56 20.41 9.89 M. Maskan / Journal of Food Engineering 44 (2000) 71ą78 77 It had little eect on the colour and rehydration ca- pacity of nished products as compared to the hot air and microwave drying methods. 4. Constant drying rate period was not observed under any of the test conditions. References Adu, B., & Otten, L. (1996). Eect of increasing hygroscopicity on the microwave heating of solid foods. Journal of Food Engineering, 27, 35ą44. Al-Duri, B., & McIntyre, S. (1992). 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