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Oblicz pH roztworu zawierającego w 1 dm3 0.020 M Na2SO4 i 0.020 M HCl.

cNa+ = 2 *cNa2SO4 = 2*0.020 M = 0.040 M

cSO42- = 0.020 M

cCl- = 0.020 M

I = ½ (0.040*12 + 0.020*22 + 0.020*12 +0.020*12) =0.080

Dla jonu H+: a*B = 3.0, A = 0.51

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ogniwa: K(+)-red | A(-)-utl

elektro: K(-)-red | A(+)-utl

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→(+)e.joniz.,powin.e-(-)char.metal.

↓(+)char.metal.(-)e.joniz.,powin.e-,elektrouj.

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[H3O+]=10-pH

[HCOOH]

[H3O+]

[HCOO]

pocz.

0.10

0

0

zmiana

−4.2 × 10-3

+4.2 × 10-3

+4.2 × 10−3

równow.

0.10 − 4.2 × 10−3

= 0.0958 = 0.10

4.2 × 10−3

4.2 × 10−3

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