scan0033 4

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Table I.5 Commercial sohating extractants J

Carbon-oxygen extractants

/

Amides

R'CONRś

*

R1 = R2 = unknown

A101 (12)

R1 = CH3; R2 = CH3(CH2)3CH(CH3)-

N503 (12)

Ethers

CHs(CH2)30CH2CH20CH2CH20(CH2)3CH3

dibutylcarbitol (13) Butex

Ketones

(CH3)2CHCH2COCH3

isobutylmethylketone (13)

MIBK

Phosphous-oxygen extractants

R'R2R3PO

Phosphorus esters

R1 = R2 = R3 = CH3(CH2)2CH20-

tri-n-butylphosphate (13) TBP

R1 = R2 = CH3(CH2)2CH20- ;

dibutylbutylphosphonate (7,11)

R3 = CH3(CH2)2CH2CH2-

DBPP

R! = R2 = CH30- ; R3 = CH}-

dimethylmethylphosphonate (7)

Phosphine oxides

R‘ = R2 = R3 = CH3(CH2)6CH2-

tri-n-octylphosphine oxide TOPO (13) Cyanex 921 (2)

Mixcd alkyl groups n-octyl and n-hexyl R2 = CH3C(CH3)2CH2CH(CH3)CH2-

Cyanex 923 (2)

R3 = CH,(CH2)6CH2-

Cyanex 925 (2)


MICHAEL COX



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