Carboxyl |
^\>H ^/0H |
Carbonyl |
/OO |
Ether |
\ / / X | ||
Phenolic |
o |
O | |
Ester |
—c—O—C—1 | ||
Alcohol |
—C-OH | ||
Methoxyl |
-0--CH, |
TABLE 5-12 Physical and Fulvic Acids |
Chemical Properties ol Humic and |
Property |
Mumie Acids Fulvic Acids |
Elemental Composition (% by weight)
C |
50-80 |
40-50 |
M |
4 6 |
4 6 |
O |
30 35 |
44 50 |
N |
2-4 |
<1-3 |
S |
1-2 |
0-2 |
Solubility in strong acid (pH 1) |
Not soluble |
Soluble |
Molecular weight rangę |
f sever.al inillion |
180-10.000 |
Functional group distribution |
Percent of oxygen in | |
indicated iunctional group | ||
carbozyl —COOH |
14 45 |
50-65 |
phenol |
10-38 |
9-19 |
alcohol —(j;—OH |
13-15 |
11-16 |
carbonyl —0=0 |
4-23 |
4-11 |
methoxyl —O—CH, |
1-5 |
1-2 |
Source: M. Schnitzer and S. U. Khan, Humic Substances in Ihe Enviion-ment, Dekker, New York, 1972.