26691

26691



Wikipedia:

A complex in chemistry usually is used to describe molecules or ensembles formed by the combination of ligands and metal ions. Originally, a complex implied a reversible association of molecules. atoms. or ions through weak Chemical bonds. As applied to coordination chemistry, this meaning has evolved. Some metal complexes are formed virtually irreversibly and many are bound together by bonds that are quite strong. The ions or molecules surrounding the metal are called ligands. Ligands are generally bound to a metal ion by a coordinate covalent bond (donating electrons from a lone electron pair into an empty metal orbital), and are thus said to be coordinated to the ion. The areas of coordination chemistry can be classified according to the naturę of the ligands, broadly speaking (tylko część przykładów):

- Classical (or "Werner Complexes"): Ligands in classical coordination chemistry bind to metals, almost exclusively, via their "lone pairs" of electrons residing on the main group atoms of the ligand. Typical ligands are H20, NH3, CT, CN~

Example: [Co(EDTA)J] {ethylenediaminetetraacetic acid, kwas etylenodiaminotetraoctowy,}, ICo(Nl~L)JCh



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