2749771867

2.    Fundamentals of Crystallography, Giacovazzo, C; Monaco HL, Viterbo D, Scordari F, Gilli G. Zanotti G, and Catti M (1992) Oxford University Press;

3.    Modem Charge Density Analysis, Gatti C, Macchi P (2012) Springer:

4.    P Popelier, Atoms in Molecules (1999) Pearson Education;

5.    Dittrich B et al. Acta Crysatllogr. B69 (2013), 91-104:

6.    W Steurer, S Deloudi, Crystallography of Quasiciystals Concepts, Methods and Structures (2009) Springer Series in Materials Science, Vol. 126.

7.    P. Coppens, X-ray charge density and Chemical Bonding.

Wykład 3:    Organotin Chemistry - prof. UŁ dr hab. Wojciech J. Kinart,

Duration- one semester (28 hours)

Lecturer: dr hab. Wojciech J. Kinart professor of the University of Łódź

Syllabus;

1)    Introduction and overview. History, occurence, production, applications and overview of structures of tin compounds. Bibliography.

2)    Akylstannanes-structures and properties, mechanisms of cleavage, tin/lithium transmetallation.

3)    Allylstannanes- transmetallations, reactions with electrophiles, reactions with radicals, ene reactions, coupling reactions. Allenyl- and propargylstannanes- preparation and reactions of transmetallation. Formation of cyclopentadienyltin compounds and their properties and reactions.

4)    Organotin carboxylates- preparation, structures and properties. Compounds with Sn-S bonds. Organotin sulftdes- preparation, structures and reactions. Organotin thiolates.

5)    Stannacycl oal kenes-monostannacycl oal kenes, stannacycl opentadi enes, oligostannacycloalkanes- structures and properties.

6)    Organotin alkoxides, phenoxides and peroxides- preparation, properties and reactions.

7)    Distannanes-principal ways of forming Sn-Sn bond in distannanes and oligostannanes-structures, properties and reactions.

8)    Reactions involving palladium-catalysed coupling (Stille Reaction). Removal of tin residues.

9)    Alkenyl and alkynylstannanes- reactions.

10)    Organotin hydroperoxides- preparation, properties and reactions.

11)    Aminostannanes, amidostannanes and sulfonamidostannanes- preparation, properties and reactions.

12)    Organotin radicals- generation, methods of detection and reactions.

13)    Materials chemistry of tin compounds- tin compounds for vapor deposition, tin based hybrid materials, PVC stabilizers, flame retardants, smoke suppresants, organotin polymers and related materials. Tin in catalysis.

14) Medical applications of tin compounds-developments in organotin cancer chemotherapy, the cardiovascular activity of organotin compounds.

Literaturę. Tin Chemistry. Fundamentals, frontiers, and applications. Editors. Alwyn G.

Davies, Marcel Gielen, Keith H. Pannell, and Edward Tiekink. John Wiley & Sons, Ltd 2008.

Alwyn G. Davies, Organotin chemistry 2-nd Ed. Wiley-YCFI, Weinheim, 2004.

Wykład 4:    Chemia cynoorganiczna - prof. UŁ dr hab. Wojciech J. Kinart,

Czas trwania wykładu-jeden semestr (28 godzin)

Wykładowca; dr hab. profesor ndzw. UŁ Wojciech J. Kinart Plan wykładu:

1)    Wstęp, historia, występowanie, produkcja, zastosowania i przegląd struktur związków cynoorganicznych. Literatura.

2)    Alkilostannany- struktura i własności, mechanizm rozrywania wiązań, reakcje transmetaloawania typu cyna/lit.