Describe the phases of hair growth
1
Learning Objectives
Identify synthetic and natural polymers
Explain the methods used to identify fibres and dyes
3
4
Define “Polymer”
2
1
Describe how hair analysis helps
to identify species and individuals
5
2
A long chain molecule made
up of many repeating units
What is a polymer?
Monomer
3
May be made up of two different monomers
What is a polymer?
Co-polymer
Ethylene
Polyethylene
4
Polymers
Polyethylene or polythene
Polymerise
5
Polymers
Polypropylene
Polystyrene
Formation in a similar way to
the polymerisation of ethylene
Propylene monomer
Styrene monomer
6
Polymers
Polyethylene, polypropylene and polystyrene
Not good for making fibres
7
Co-polymer
Nylon
Nylon-6,6
8
Nylon
Diaminohexane
Adipic acid
9
Fibre examination
Wool, nylon, cotton, etc.
Microscopic to determine type
Spectroscopic analysis of fibre
Physical features
3
2
1
Shape
10
Fibre examination
Delustrant
Chemicals added to reduce shine
5
Colour
4
Spectroscopic analysis of the dye
More chemical components analyzed
Better individualization of fibre
Natural fibres vs synthetic fibres
11
Polymers
Natural fibres
Synthetic fibres
From chemical industry
From plants and animals
Made by Extrusion
12
Synthetic polymer fibres
Fibre shape and size
depends on the hole
13
Microscopic examination
allows for identification of
Manufacturer
Trilobal fibre
Synthetic polymer fibres
Batch of material
IR spectrum
14
Identification
Analysis of
chemical
constituents
IR Microscope
Microscope
IR spectrometer
IR microscope
15
Jeffrey
MacDonald
U.S. Army, Fort Bragg, N.C.
16
Jeffrey MacDonald
Convicted of murdering
his wife and daughters
Beaten and stabbed
to death at home
Jeffrey MacDonald
Murders done by a group of drug addicts
17
Defense
No evidence of anyone else in the house
Broke into the house
MacDonald found guilty
Additional evidence used at the appeal
18
Defense
Fibre from the crime scene
No match to victims’ clothes
Evidence of an intruder
19
IR comparison
From Mrs.
MacDonald
Claimed to be
from attackers