heat capacity – ciepło właściwe

is reported – jest przedstawione (jest obserwowane)

as obtained – uzyskane (otrzymane)

differential scanning calorimetry (d.s.c.) – różnicowej kalorymetrii skaningowej

adiabatic calorimetry – adiabatycznej kalorymetrii

solid - stały

is linked – jest związany z.. (łaczy się z…)

group vibrational spectrum – widma grupowych drgań

the skeletal vibrations – drgania szkieletowe

the latter –drugi (ostatnie)

equation – równanie

compared to –w porównaniu

contributions of – wkłady

constituent groups – grupy składników (grupy charakterystyczne)

glass transition temperature – temperature zeszklenia

occurs – występuje

endotherm – endoderma

variable – zmienna

heats of fusion – temperature topnienia

crystalline – krystaliczny

estimated to – szacuje się

rigid-amorphous fractions - sztywno-amorficzne frakcje

enthalpy, H – entalpia

free enthalpy,G – entalpia swobodna

entropy, S – entropia

temperatures and heats of transition – temperatury I ciepła przejścia

structure-property-processing – struktura przetwarzania połaczeń

molecular motion – ruch molekularny

irreversible effects – nieodwracalne skutki

glass transition –zeszklenie

partial crystallinity –częściowo krytaliczny

broadened transitions – poszerzone przejścia

ageing –starzenie się

non-equilibrium – nierównowagowy

requires –wymaga

quantitative knowledge – ilościowa wiedza

to serve –służyć

reference – odniesienia

provide – zapewnić

different fiber – różne włókna

film – film

bulk applications – luźnyxh aplikacji

agriculture –rolnictwo

homologous series –homologiczna seria

aliphatic polyesters – poliestry alifatyczne

repeating –

predominantly –

amount-

comonomer-

have been combined –

measurements –

baselines –

first established-

fit –

allow –

providing an estimate –

region of the glass transition –

melt –

fully amorphous sample –

yields –

crystallinity –

assuming –

sufficiently –

constant pressure –

constant volume –

compressibility –

expansivity –

customary to refer to –

available –

estimate –

equilibrium melting temperature –

independent of-

convenience –

separated –

derived –

assessed –

fitting –

a series of single frequencies –

box distributions –

over narrow frequency-ranges –

terms –

summation representing –

respectively –

chain –

infrared-

suitable

low-molar-mass analogs –

identified areas of the group vibrations –

one-dimensional –

uniformly –

subtracting –

remains –

frequencies of the corresponding distribution –

respectively –

denotes –

quadratic frequency distribution –

lowest frequencies –

an additional –

commonly values –

exceeds –

still of –

laser excitation –

comparison –

repeating-

gradual absorption –

performed –

general –

assumed-

reduced to-

applied in

adequate –

significant –

Empirically –

obtained from –

supplied –

measurements –

mainly –

obtain –

cooled at constant rate-

melt

melting transition

crystallinities

quenched

inherently amorphous

random copolymer nature

sapphire (Al2O3)

onset

transition behavior

heat-flux

gained by

melting range.

identify changes

empty reference

asymmetry of

pan

including

controlled cooling

accuracy of

preliminary

conditions.

Comparison

versus temperature

quenched

indicate

undergoes

reorganization,

combined

smoothed

the halfheight

peak temperature. These

evaluation of the vibrational

repeating unit

approximate

frequencies

relevant

fitted

equal

subtracted

unique minimum at

dimensional

graphically

Quantitative thermal analysis

dependent

applies

deviations

apparent molar heat capacity

melting range

evaluation

interchangeably

gradual increase

plotted

major contribution

originates

excited

best-fit of

justifies

leading

approaching

increases

sufficiently

affected

significantly

increases

uncertain

cooperative conformational

external contributions

internal rotation

corresponding

premelting

curve

absence of rigid amorphous material

chosen sample

decreases

reheating

metastable only

lamellar thickness

extendedchain

Atomic force microscopy

thicknesses

stereochemical composition

chain

scheme

discrepancy

measured

subtracting the excess

assume

repeating

consists of

beads

backbone

hindering

uncertainties

quasi-

esolve

well-crystallized