5654708750

Duriannci | riciciciiLC^

Welcome Marta Sadowska-Hinc | Sign Out

« Add kmp Ai»rt Research Topie "catalytic hydrodechlorination

> references (51) > Synergistic effects in hydrode

Reference Dęta i I

4 Get

Substances

Get

Reactions

89

Get    Get    Get    Cp* Send to

Cited ■ Citing    Fuli Text    SciPlanner

'y Return

3. Synergistic effects in hydrodechlorination of organie compounds catalyzed by metals

By: Bonarowska, M.; Srebowata, A.; Karpiński, Z.

Link Save Print Export

^ Previous | Next ^

A review. The search for the most suitable hydrodechlorination catalysts should consider both the C-CI bond strength in a mol. subjected to reaction and the metal-chlorine bond, which should be neither too strong nor too weak. An improvement of Pd- and Pt-based catalysts can be achieved by alloying with metals which bind chlorine even less strongly, e.g. with gold. Addn. of platinum to palladium would also be beneficial because of metal-chloride bond energy considerations. Analogous effects occur in the hydrodechlorination of dichlorodifluoromethane and 1,2-dichloroethane, the mols. characterized by stronger carbon-chlorine bonds.

Indexing

Physical Organie Chemistiy (Section 22-0) <i/

Concepts

Dechlorination    Dechlorination catalysts

reductive; synergistic effects in hydrodechlorination of org. compds. catalyzed by metals

Substances <0

56-23-5 Tetrachloromethane, reactions 75-71-8 Dichlorodifluoromethane 107-06-2 1,2-Dichloroethane, reactions

Cl — CH 2 — CH _: — Cl

Quick Links

0 Tags, 0 Comments

—

—

Source

Anndles Universitatis Mariae

Curie-Skiodowska, Sectio AA:

Chemia

Volume 65

Pages 1-8

Journal; General Review 2010

CODEN: AUMCD7 ISSN: 0137-6853

Company/Organization

Institute of Physical Chemistry of PAS

Warsaw, Pol. 01-224

Accession Number

2011:732637 CAN 155:406637 CAPLUS

Cooperative phenomena

synergism; synergistic effects in hydrodechlorination of org. compds. catalyzed by metals

synergistic effects in hydrodechlorination of org. compds. catalyzed by metals Reactant; Reactant or reagent

Organie compounds

synergistic effects in hydrodechlorination of org. compds. catalyzed by metals Reactant; Reactant or reagent

Supplementary Terms

review; synergistic; effect; hydrodechlorination; org; compd; catalyzed; metal

Publisher

Wydawnictwo Uniwersytetu Marii Curie-Sklodowskiej

_

—

Language

English

Citations

Kaptejjn, F; Catalysis, An Integrated Approach to Homogeneous, Heterogeneous and Industrial Catalysis 1993, 83

Thompson, C; J Phys Chem B 2000, 104, 3067

Srebow-ata, A; PhD thesis, Institute of Physical Chemistry of PAS 2006

Bonarowska, M; J Catal 2002, 209, 528