4.1. Model ralidation
For vaIidation of the model, one single celi, model Ballard Mark V, was simulated, which was fed with gases H2 and O2, using the membranę Nafion 117. The parameters used for this simulation are presented in Table I. Also, the next sections present results for two stack models that confirm the model results.
Table I - Parameters of the Ballard Mark V fuel celi
Param. |
Value |
Param. |
Value |
T |
343 K |
-0.948 | |
A |
50.6 cm2 |
0.00286+0.0002.lnA+(4.3.1(r’).lno,2 | |
i |
178 |xm |
7.6.10! | |
Ph2 |
1 atm |
-1.93.1C4 | |
Po2 |
1 atm |
V |
23 |
B |
0.016 V |
Jmax |
1500 mA/cm1 |
Rc |
0.0003 n |
Jn |
1.2 mA/cm2 |
It should be madę a proviso with relationship to the parameters of the cells and of the model. The main proposal of this model is to supply the characteristics of the system operation in a morę precisely possible way, allowing the development and improvement of electrical energy generation systems using this new and highly promising technology. However, there is a series of parameters involved in this model, empiric some of them and others of difficult determination. For the simulations that proceed, the parameters were mainly obtained in the literaturę and the results fully agree with those presented in the literaturę. With development of the technology, morę precise parameters and of easier determination will be obtained, due to the great and growing worldwide interest in the subject. For the current situation, a model that can be used as a błock in the construction of simulators of generation systems using PEMFC, with reasonable results and good dynamie response, comes as a quite interesting and up-to-date option, that can benefit planners and researchers of the subject.
The celi polarization curve represents the FC output voltage as a function of the current density in steady State. The result obtained with the simulation is presented in Fig. 3, which also shows the practical test results presented in f 1], The simulation results show good likeness with the experimental ones. For current density values above 0.1 A/cm2 and below 1.3 A/cm2 the absolute error was less than 3%. This figurę is completely acceptable taking into account the difficulty to find the right values for the different model parameters.
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