06 25 88

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ENTHALPY OF VAPORIZATION

The molar enthalpy (heat) of vaporization ∆

vap

H, which is de-

fined as the enthalpy change in the conversion of one mole of liq-

uid to gas at constant temperature, is tabulated here for about 950

inorganic and organic compounds. Values are given, when avail-

able, both at the normal boiling point t

b

, referred to a pressure of

101.325 kPa (760 mmHg), and at 25°C.

The values in this table were measured either by calorimetric

techniques or by application of the Claperyon equation to the

variation of vapor pressure with temperature. See Reference 1 for

a discussion of the accuracy of different experimental techniques

and methods of estimating enthalpy of vaporization at other tem-

peratures. Several of the references present empirical techniques

for correlating enthalpy of vaporization with molecular structure.

Compounds are listed by systematic name, with compounds not

containing carbon preceding those that do contain carbon. To lo-

cate a compound by molecular formula or CAS Registry Number,

use the indexes to the table “Physical Constants of Organic

Compounds” in Section 3, which point to the entry in that table

from which the name can be determined.

References

1. Majer, V., and Svoboda, V., Enthalpies of Vaporization of Organic

Compounds, Blackwell Scientific Publications, Oxford, 1985.

2. Chase, M. W., Davies, C. A., Downey, J. R., Frurip, D. J., McDonald, R.

A., and Syverud, A. N., JANAF Thermochemical Tables, Third Edition,

J. Phys. Chem. Ref. Data, 14, Suppl. 1, 1985.

3. Landolt-Börnstein, Numerical Data and Functional Relationships

in Science and Technology, Sixth Edition, II/4, Caloric Quantities of

State, Springer-Verlag, Heidelberg, 1961.

4. Daubert, T. E., Danner, R. P., Sibul, H. M., and Stebbins, C. C.,

Physical and Thermodynamic Properties of Pure Compounds: Data

Compilation, extant 1994 (core with 4 supplements), Taylor & Francis,

Bristol, PA.

5. Ruzicka, K., and Majer, V., Simultaneous Treatment of Vapor Pressures

and Related Thermal Data Between the Triple and Normal Boiling

Temperatures for n-Alkanes C5–C20, J. Phys. Chem. Ref. Data, 23, 1,

1994.

6. Verevkin, S. P., Thermochemistry of Amines: Experimental Standard

Molar Enthalpies of Formation of Some Aliphatic and Aromatic

Amines, J. Chem. Thermodynamics, 29, 891, 1997.

7. Cady, G. H., and Hargreaves, G. B., The Vapor Pressure of Some Heavy

Transition Metal Hexafluorides, J. Chem. Soc., 1563, 1578, 1961.

8. Steele, W. V., Chirico, R. D., Knipmeyer, S. E., and Nguyen, A., J. Chem.

Eng. Data 41, 1255, 1996.

9. Nichols, G., et al., J. Chem. Eng. Data 51, 475, 2006.

10. Dias, A. M. A., et al., J. Chem. Eng. Data 50, 1328, 2005.

11. Umnahanant, P., et al., J. Chem. Eng. Data 51, 2246, 2006.

12. Raganov, G. N., Pisarev, P. N., and Emel’yanenko, V. N., J. Chem. Eng.

Data 50, 1114, 2005.

13. Verevkin, S. P., et al., J. Chem. Eng. Data 51, 1896, 2006.

14. Verevkin, S. P., J. Chem. Thermodynamics 38, 1111, 2006.

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Compounds not containing carbon
Aluminum

Al

2519

294

Aluminum borohydride

AlB

3

H

12

44.5

30

Aluminum bromide

AlBr

3

255

23.5

Aluminum iodide

AlI

3

382

32.2

Ammonia

H

3

N

–33.33

23.33

19.86

Antimony(III) bromide

Br

3

Sb

288

59

Antimony(III) chloride

Cl

3

Sb

220.3

45.19

Antimony(III) iodide

I

3

Sb

400

68.6

Argon

Ar

–185.85

6.43

Arsenic(III) bromide

AsBr

3

221

41.8

Arsenic(III) chloride

AsCl

3

130

35.01

Arsenic(III) fluoride

AsF

3

57.13

29.7

Arsenic(V) fluoride

AsF

5

–52.8

20.8

Arsenic(III) iodide

AsI

3

424

59.3

Arsine

AsH

3

–62.5

16.69

Barium

Ba

1897

140

Beryllium chloride

BeCl

2

482

105

Beryllium iodide

BeI

2

590

70.5

Bismuth

Bi

1564

151

Bismuth tribromide

BiBr

3

462

75.4

Bismuth trichloride

BiCl

3

441

72.61

Boron

B

4000

480

Boron tribromide

BBr

3

91.3

30.5

Boron trichloride

BCl

3

12.5

23.77

23.1

Boron trifluoride

BF

3

–99.9

19.33

Boron triiodide

BI

3

209.5

40.5

6-101

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Bromine

Br

2

58.8

29.96

30.91

Bromine fluoride

BrF

20

25.1

Bromine pentafluoride

BrF

5

41.3

30.6

Bromine trifluoride

BrF

3

125.8

47.57

Bromosilane

BrH

3

Si

1.9

24.4

Cadmium

Cd

767

99.87

Cadmium bromide

Br

2

Cd

863

115

Cadmium chloride

CdCl

2

964

124.3

Cadmium fluoride

CdF

2

1750

214

Cadmium iodide

CdI

2

744

115

Chlorine

Cl

2

–34.04

20.41

17.65

Chlorine dioxide

ClO

2

11

30

Chlorine fluoride

ClF

–101.1

24

Chlorine monoxide

Cl

2

O

2.2

25.9

Chlorine trifluoride

ClF

3

11.75

27.53

Chlorosilane

ClH

3

Si

–30.4

21

Chlorotrifluorosilane

ClF

3

Si

–70.0

18.7

Chromium(II) chloride

Cl

2

Cr

1120

197

Chromium(VI) dichloride dioxide

Cl

2

CrO

2

117

35.1

Diborane

B

2

H

6

–92.49

14.28

Dibromosilane

Br

2

H

2

Si

66

31

Dichlorodifluorosilane

Cl

2

F

2

Si

–32

21.2

Dichlorosilane

Cl

2

H

2

Si

8.3

25

24.2

Difluorine dioxide

F

2

O

2

–57

19.1

Difluorosilane

F

2

H

2

Si

–77.8

16.3

Digermane

Ge

2

H

6

29

25.1

Diphosphine

H

4

P

2

63.5

28.8

Disilane

H

6

Si

2

–14.8

21.2

Fluorine

F

2

–188.12

6.62

Fluorine monoxide

F

2

O

–144.3

11.09

Fluorosilane

FH

3

Si

–98.6

18.8

Gallium

Ga

2204

254

Gallium(III) bromide

Br

3

Ga

279

38.9

Gallium(III) chloride

Cl

3

Ga

201

23.9

Gallium(III) iodide

GaI

3

340

56.5

Germane

GeH

4

–88.1

14.06

Germanium

Ge

2833

334

Germanium(IV) bromide

Br

4

Ge

186.35

41.4

Germanium(IV) chloride

Cl

4

Ge

86.55

27.9

Gold

Au

2856

324

Helium

He

–268.93

0.08

Hydrazine

H

4

N

2

113.55

41.8

44.7

Hydrazoic acid

HN

3

35.7

30.5

Hydrogen

H

2

–252.76

0.90

Hydrogen bromide

BrH

–66.38

12.69

Hydrogen chloride

ClH

–85

16.15

9.08

Hydrogen disulfide

H

2

S

2

70.7

33.78

Hydrogen iodide

HI

–35.55

19.76

17.36

Hydrogen peroxide

H

2

O

2

150.2

51.6

Hydrogen selenide

H

2

Se

–41.25

19.7

Hydrogen sulfide

H

2

S

–59.55

18.67

14.08

Hydrogen telluride

H

2

Te

–2

19.2

Indium(I) bromide

BrIn

656

92

Indium(I) iodide

IIn

712

90.8

Iodine

I

2

184.4

41.57

6-102

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Iodine pentafluoride

F

5

I

100.5

41.3

Iridium(VI) fluoride

F

6

Ir

53.6

30.9

Krypton

Kr

–153.34

9.08

Lead

Pb

1749

179.5

Lead(II) bromide

Br

2

Pb

892

133

Lead(II) chloride

Cl

2

Pb

951

127

Lead(II) fluoride

F

2

Pb

1293

160.4

Lead(II) iodide

I

2

Pb

872

104

Lithium fluoride

FLi

1673

147

Lithium hydroxide

HLiO

1626

188

Mercury

Hg

356.62

59.11

Mercury(II) bromide

Br

2

Hg

318

58.89

Mercury(II) chloride

Cl

2

Hg

304

58.9

Mercury(II) iodide

HgI

2

351

59.2

Molybdenum(V) chloride

Cl

5

Mo

268

62.8

Molybdenum(V) fluoride

F

5

Mo

213.6

51.8

Molybdenum(VI) fluoride

F

6

Mo

34.0

29.0

Molybdenum(VI) oxide

MoO

3

1155

138

Molybdenum(VI) oxytetrafluoride

F

4

MoO

186.0

50.6

Neon

Ne

–246.05

1.71

Niobium(V) chloride

Cl

5

Nb

247.4

52.7

Niobium(V) fluoride

F

5

Nb

234

52.3

Nitric acid

HNO

3

83

39.1

Nitric oxide

NO

–151.74

13.83

Nitrogen

N

2

–195.79

5.57

Nitrogen tetroxide

N

2

O

4

21.15

38.12

Nitrogen trifluoride

F

3

N

–128.75

11.56

Nitrosyl chloride

ClNO

–5.5

25.78

Nitrosyl fluoride

FNO

–59.9

19.28

Nitrous oxide

N

2

O

–88.48

16.53

Nitryl chloride

ClNO

2

–15

25.7

Nitryl fluoride

FNO

2

–72.4

18.05

Osmium(V) fluoride

F

5

Os

233

65.6

Osmium(VI) fluoride

F

6

Os

47.5

28.1

Oxygen

O

2

–182.95

6.82

Pentaborane(11)

B

5

H

11

65

31.8

Perchloryl fluoride

ClFO

3

–46.75

19.33

Phosphine

H

3

P

–87.75

14.6

Phosphorothioc trifluoride

F

3

PS

–52.25

19.6

Phosphorus

P

280.5

12.4

14.2

Phosphorus(III) bromide

Br

3

P

173.2

38.8

Phosphorus(III) chloride

Cl

3

P

76

30.5

32.1

Phosphorus(III) chloride difluoride

ClF

2

P

–47.3

17.6

Phosphorus(III) dichloride fluoride

Cl

2

FP

13.85

24.9

Phosphorus(III) fluoride

F

3

P

–101.8

16.5

Phosphorus(V) fluoride

F

5

P

–84.6

17.2

Phosphorus(III) iodide

I

3

P

227

43.9

Phosphoryl bromide

Br

3

OP

191.7

38

Phosphoryl chloride

Cl

3

OP

105.5

34.35

38.6

Rhenium(VII) dioxytrifluoride

F

3

O

2

Re

185.4

65.7

Rhenium(V) fluoride

F

5

Re

221.3

58.1

Rhenium(VI) fluoride

F

6

Re

33.8

28.7

Rhenium(VI) oxytetrafluoride

F

4

ORe

171.7

61.0

Selenium

Se

685

95.48

Selenium tetrafluoride

F

4

Se

101.6

47.2

Enthalpy of Vaporization

6-103

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Silane

H

4

Si

–111.9

12.1

Silver(I) bromide

AgBr

1502

198

Silver(I) chloride

AgCl

1547

199

Silver(I) iodide

AgI

1506

143.9

Sodium hydroxide

HNaO

1388

175

Stannane

H

4

Sn

–51.8

19.05

Stibine

H

3

Sb

–17

21.3

Sulfur

S

444.61

45

Sulfur dioxide

O

2

S

–10.05

24.94

22.92

Sulfur hexafluoride

F

6

S

8.99

Sulfur tetrafluoride

F

4

S

–40.45

26.44

Sulfur trioxide

O

3

S

44.5

40.69

43.14

Sulfuryl chloride

Cl

2

O

2

S

69.4

31.4

30.1

Tantalum(V) bromide

Br

5

Ta

348.8

62.3

Tantalum(V) chloride

Cl

5

Ta

239

54.8

Tantalum(V) fluoride

F

5

Ta

229.5

56.9

Tellurium

Te

988

114.1

Tellurium tetrachloride

Cl

4

Te

387

77

Tetraborane(10)

B

4

H

10

18

27.1

Tetrabromosilane

Br

4

Si

154

37.9

Tetrachlorosilane

Cl

4

Si

57.65

28.7

29.7

Tetrafluorodiborane

B

2

F

4

–34.0

28

Tetrafluorohydrazine

F

4

N

2

–74

13.27

Tetraiodosilane

I

4

Si

287.35

50.2

Thallium(I) bromide

BrTl

819

99.56

Thallium(I) chloride

ClTl

720

102.2

Thallium(I) iodide

ITl

824

104.7

Thallium(I) sulfide

STl

2

1367

154

Thionitrosyl fluoride (NSF)

FNS

4.8

22.2

Thionyl chloride

Cl

2

OS

75.6

31.7

31

Thionyl fluoride

F

2

OS

–43.8

21.8

Thorium(IV) chloride

Cl

4

Th

921

146.4

Thorium(IV) fluoride

F

4

Th

1680

258

Tin(II) bromide

Br

2

Sn

639

102

Tin(IV) bromide

Br

4

Sn

205

43.5

Tin(II) chloride

Cl

2

Sn

623

86.8

Tin(IV) chloride

Cl

4

Sn

114.15

34.9

Tin(II) iodide

I

2

Sn

714

105

Tin(IV) iodide

I

4

Sn

364.35

56.9

Titanium(IV) bromide

Br

4

Ti

233.5

44.37

Titanium(II) chloride

Cl

2

Ti

1500

232

Titanium(III) chloride

Cl

3

Ti

960

124

Titanium(IV) chloride

Cl

4

Ti

136.45

36.2

Titanium(IV) iodide

I

4

Ti

377

58.4

Tribromosilane

Br

3

HSi

109

34.8

Trichlorosilane

Cl

3

HSi

33

25.7

Trifluorosilane

F

3

HSi

–95

16.2

Trigermane

Ge

3

H

8

110.5

32.2

Trisilane

H

8

Si

3

52.9

28.5

Tungsten(VI) chloride

Cl

6

W

337

52.7

Tungsten(VI) fluoride

F

6

W

17.1

26.5

Tungsten(VI) oxytetrachloride

Cl

4

OW

230

67.8

Tungsten(VI) oxytetrafluoride

F

4

OW

185.9

59.5

Vanadium(IV) chloride

Cl

4

V

151

41.4

42.5

Vanadium(V) fluoride

F

5

V

48.3

44.52

6-104

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Vanadyl trichloride

Cl

3

OV

127

36.78

Water

H

2

O

99.97

40.65

43.98

Xenon

Xe

–108.09

12.57

Zinc bromide

Br

2

Zn

670

118

Zinc chloride

Cl

2

Zn

732

126

Zinc fluoride

F

2

Zn

1500

190.1

Compounds containing carbon
Acetaldehyde

C

2

H

4

O

20.1

25.76

25.47

Acetic acid

C

2

H

4

O

2

117.9

23.70

23.36

Acetic anhydride

C

4

H

6

O

3

139.5

38.2

Acetone

C

3

H

6

O

56.05

29.10

30.99

Acetonitrile

C

2

H

3

N

81.65

29.75

32.94

Acetophenone

C

8

H

8

O

202

43.98

55.40

Acrolein

C

3

H

4

O

52.6

28.3

Acrylonitrile

C

3

H

3

N

77.3

32.6

Allyl acetate

C

5

H

8

O

2

103.5

36.3

Allyl alcohol

C

3

H

6

O

97.4

40.0

2-Amino-2-methyl-1-propanol

C

4

H

11

NO

165.5

50.6

Aniline

C

6

H

7

N

184.17

42.44

55.83

Anisole

C

7

H

8

O

153.7

38.97

46.90

Azobutane

C

8

H

18

N

2

49.31

Azopropane

C

6

H

14

N

2

114

39.88

Benzaldehyde

C

7

H

6

O

178.8

42.5

Benzene

C

6

H

6

80.09

30.72

33.83

Benzenethiol

C

6

H

6

S

169.1

39.93

47.56

Benzonitrile

C

7

H

5

N

191.1

45.9

Benzyl acetate

C

9

H

10

O

2

213

49.4

Benzyl alcohol

C

7

H

8

O

205.31

50.48

Benzylamine

C

7

H

9

N

185

60.16

N-Benzylaniline

C

13

H

13

N

306.5

79.6

Benzyl benzoate

C

14

H

12

O

2

323.5

53.6

Bis(2-chloroethyl) ether

C

4

H

8

Cl

2

O

178.5

45.2

Bis(ethoxymethyl) ether

C

6

H

14

O

3

140.6

36.17

44.69

Bromobenzene

C

6

H

5

Br

156.06

44.54

1-Bromobutane

C

4

H

9

Br

101.6

32.51

36.64

2-Bromobutane

C

4

H

9

Br

91.3

30.77

34.41

Bromochloromethane

CH

2

BrCl

68.0

30.0

2-Bromo-2-chloro-1,1,1-trifluoroethane

C

2

HBrClF

3

50.2

28.08

29.61

Bromoethane

C

2

H

5

Br

38.5

27.04

28.03

Bromoethene

C

2

H

3

Br

15.8

23.4

1-Bromoheptane

C

7

H

15

Br

178.9

50.60

1-Bromohexane

C

6

H

13

Br

155.3

45.89

Bromomethane

CH

3

Br

3.5

23.91

22.81

1-Bromo-2-methylpropane

C

4

H

9

Br

91.1

31.33

34.82

2-Bromo-2-methylpropane

C

4

H

9

Br

73.3

29.23

31.81

1-Bromonaphthalene

C

10

H

7

Br

281

39.3

1-Bromooctane

C

8

H

17

Br

200.8

55.77

1-Bromopentane

C

5

H

11

Br

129.8

35.01

41.28

1-Bromopropane

C

3

H

7

Br

71.1

29.84

32.01

2-Bromopropane

C

3

H

7

Br

59.5

28.33

30.17

3-Bromopropene

C

3

H

5

Br

70.1

30.24

32.73

1,2-Butadiene

C

4

H

6

10.9

24.02

23.21

1,3-Butadiene

C

4

H

6

–4.41

22.47

20.86

Butanal

C

4

H

8

O

74.8

31.5

Enthalpy of Vaporization

6-105

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Butane

C

4

H

10

–0.5

22.44

21.02

1,2-Butanediol

C

4

H

10

O

2

190.5

52.84

71.55

1,3-Butanediol

C

4

H

10

O

2

207.5

54.31

74.46

1,4-Butanediol

C

4

H

10

O

2

235

77.1

1,4-Butanedithiol

C

4

H

10

S

2

195.5

55.10

Butanenitrile

C

4

H

7

N

117.6

33.68

39.33

1-Butanethiol

C

4

H

10

S

98.5

32.23

36.63

2-Butanethiol

C

4

H

10

S

85.0

30.59

33.99

Butanoic acid

C

4

H

8

O

2

163.75

40.45

Butanoic anhydride

C

8

H

14

O

3

200

50.0

1-Butanol

C

4

H

10

O

117.73

43.29

52.35

2-Butanol

C

4

H

10

O

99.51

40.75

49.72

2-Butanone

C

4

H

8

O

79.59

31.30

34.79

1-Butene

C

4

H

8

–6.26

22.07

20.22

cis-2-Butene

C

4

H

8

3.71

23.34

22.16

trans-2-Butene

C

4

H

8

0.88

22.72

21.40

2-Butoxyethanol

C

6

H

14

O

2

168.4

56.59

Butyl acetate

C

6

H

12

O

2

126.1

36.28

43.86

tert-Butyl acetate

C

6

H

12

O

2

95.1

33.07

38.03

Butylamine

C

4

H

11

N

77.00

31.81

35.72

sec-Butylamine

C

4

H

11

N

62.73

29.92

32.85

tert-Butylamine

C

4

H

11

N

44.04

28.27

29.64

Butylbenzene

C

10

H

14

183.31

38.87

50.8

sec-Butylbenzene

C

10

H

14

173.3

48.1

tert-Butylbenzene

C

10

H

14

169.1

47.6

Butylcyclohexane

C

10

H

20

180

49.36

Butylcyclopentane

C

9

H

18

156.6

36.16

45.89

Butylethylamine

C

6

H

15

N

107.5

33.97

40.15

Butyl ethyl ether

C

6

H

14

O

92.3

31.63

36.32

Butyl ethyl sulfide

C

6

H

14

S

144.3

37.01

44.51

Butyl formate

C

5

H

10

O

2

106.1

36.58

41.11

tert-Butyl isobutyl ether

C

8

H

18

O

112.0

33.11

40.5

Butyl methyl ether

C

5

H

12

O

70.16

29.55

32.37

sec-Butyl methyl ether

C

5

H

12

O

59.1

28.09

30.23

Butyl methyl sulfide

C

5

H

12

S

123.4

34.47

40.46

tert-Butyl methyl sulfide

C

5

H

12

S

98.9

31.47

35.84

Butyl propyl ether

C

7

H

16

O

118.1

33.72

40.22

Butyl vinyl ether

C

6

H

12

O

94

31.58

36.17

1-Butyne

C

4

H

6

8.08

24.52

23.35

2-Butyne-1,4-diol

C

4

H

6

O

2

238

81.5

γ-Butyrolactone

C

4

H

6

O

2

204

52.2

Camphor, (+)

C

10

H

16

O

207.4

59.5

Carbon disulfide

CS

2

46

26.74

27.51

Carbon monoxide

CO

–191.5

6.04

2-Chloroaniline

C

6

H

6

ClN

208.8

44.4

Chlorobenzene

C

6

H

5

Cl

131.72

35.19

40.97

1-Chlorobutane

C

4

H

9

Cl

78.4

30.39

33.51

2-Chlorobutane

C

4

H

9

Cl

68.2

29.17

31.53

Chlorodifluoromethane

CHClF

2

–40.7

20.2

Chloroethane

C

2

H

5

Cl

12.3

24.65

2-Chloroethanol

C

2

H

5

ClO

128.6

41.4

Chloroethene

C

2

H

3

Cl

–13.8

20.8

1-Chloroheptane

C

7

H

15

Cl

160.4

47.66

1-Chlorohexane

C

6

H

13

Cl

135.1

35.67

42.83

Chloromethane

CH

3

Cl

–24.09

21.40

18.92

6-106

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

1-Chloro-3-methylbutane

C

5

H

11

Cl

98.9

32.02

36.24

1-Chloro-2-methylpropane

C

4

H

9

Cl

68.5

29.22

31.67

2-Chloro-2-methylpropane

C

4

H

9

Cl

50.9

27.55

28.98

1-Chloronaphthalene

C

10

H

7

Cl

259

52.1

1-Chlorooctane

C

8

H

17

Cl

183.5

52.42

Chloropentafluorobenzene

C

6

ClF

5

117.96

34.76

41.07

Chloropentafluoroethane

C

2

ClF

5

–39.1

19.41

1-Chloropentane

C

5

H

11

Cl

108.4

33.15

38.24

2-Chloropentane

C

5

H

11

Cl

97.0

31.79

36.03

1-Chloropropane

C

3

H

7

Cl

46.5

27.18

28.35

2-Chloropropane

C

3

H

7

Cl

35.7

26.30

26.90

3-Chloropropene

C

3

H

5

Cl

45.1

29.0

2-Chlorotoluene

C

7

H

7

Cl

159.0

37.5

4-Chlorotoluene

C

7

H

7

Cl

162.4

38.7

Chlorotrifluoromethane

CClF

3

–81.37

15.8

Cholesterol

C

27

H

46

O

360 dec

148.0

o-Cresol

C

7

H

8

O

191.04

45.19

m-Cresol

C

7

H

8

O

202.27

47.40

61.71

p-Cresol

C

7

H

8

O

201.98

47.45

Cyanogen

C

2

N

2

–21.1

23.33

19.75

Cyclobutane

C

4

H

8

12.6

24.19

23.51

Cyclobutanecarbonitrile

C

5

H

7

N

149.6

36.88

44.34

Cyclohexane

C

6

H

12

80.73

29.97

33.01

Cyclohexanecarbonitrile

C

7

H

11

N

184

51.92

Cyclohexanethiol

C

6

H

12

S

158.8

37.06

44.57

Cyclohexanol

C

6

H

12

O

160.84

62.01

Cyclohexanone

C

6

H

10

O

155.43

45.06

Cyclohexene

C

6

H

10

82.98

30.46

33.47

1-Cyclohexenecarbonitrile

C

7

H

9

N

53.55

Cyclohexylamine

C

6

H

13

N

134

36.14

43.67

Cyclohexylbenzene

C

12

H

16

240.1

60.8

Cyclohexylcyclohexane

C

12

H

22

238

57.98

Cyclopentane

C

5

H

10

49.3

27.30

28.52

Cyclopentanecarbonitrile

C

6

H

9

N

170

43.43

Cyclopentanethiol

C

5

H

10

S

132.1

35.32

41.42

Cyclopentanol

C

5

H

10

O

140.42

57.05

Cyclopentanone

C

5

H

8

O

130.57

36.35

42.72

1-Cyclopentenecarbonitrile

C

6

H

7

N

44.98

Cyclopropane

C

3

H

6

–32.81

20.05

16.93

Cyclopropanecarbonitrile

C

4

H

5

N

135.1

35.55

41.94

Cyclopropylbenzene

C

9

H

10

173.6

50.22

Cyclopropyl methyl ketone

C

5

H

8

O

111.3

34.07

39.41

cis-Decahydronaphthalene

C

10

H

18

195.8

41.0

trans-Decahydronaphthalene

C

10

H

18

187.3

40.2

Decane

C

10

H

22

174.15

39.58

51.42

1,10-Decanediol

C

10

H

22

O

2

120.0

Decanenitrile

C

10

H

19

N

243

66.84

1-Decanethiol

C

10

H

22

S

240.6

65.48

1-Decanol

C

10

H

22

O

231.1

81.50

1-Decene

C

10

H

20

170.5

50.43

Decylbenzene

C

16

H

26

293

78.2

1,4-Dibromobutane

C

4

H

8

Br

2

197

53.09

1,2-Dibromo-1-chloro-1,2,2-trifluoroethane C

2

Br

2

ClF

3

93

31.17

35.04

1,2-Dibromoethane

C

2

H

4

Br

2

131.6

34.77

41.73

Dibromomethane

CH

2

Br

2

97

32.92

36.97

Enthalpy of Vaporization

6-107

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

1,2-Dibromopropane

C

3

H

6

Br

2

141.9

35.61

41.67

1,3-Dibromopropane

C

3

H

6

Br

2

167.3

47.45

1,2-Dibromotetrafluoroethane

C

2

Br

2

F

4

47.35

27.03

28.39

Dibutylamine

C

8

H

19

N

159.6

38.44

49.45

Dibutyl ether

C

8

H

18

O

140.28

36.49

44.97

Di-sec-butyl ether

C

8

H

18

O

121.1

34.06

40.84

Di-tert-butyl ether

C

8

H

18

O

107.23

32.15

37.61

Dibutyl phthalate

C

16

H

22

O

4

340

79.2

Dibutyl sulfide

C

8

H

18

S

185

52.96

Di-tert-butyl sulfide

C

8

H

18

S

149.1

33.26

43.76

o-Dichlorobenzene

C

6

H

4

Cl

2

180

39.66

50.21

m-Dichlorobenzene

C

6

H

4

Cl

2

173

38.62

48.58

p-Dichlorobenzene

C

6

H

4

Cl

2

174

38.79

49.0

1,2-Dichlorobutane

C

4

H

8

Cl

2

124.1

33.90

39.58

1,4-Dichlorobutane

C

4

H

8

Cl

2

161

46.36

Dichlorodifluoromethane

CCl

2

F

2

–29.8

20.1

1,1-Dichloroethane

C

2

H

4

Cl

2

57.3

28.85

30.62

1,2-Dichloroethane

C

2

H

4

Cl

2

83.5

31.98

35.16

1,1-Dichloroethene

C

2

H

2

Cl

2

31.6

26.14

26.48

cis-1,2-Dichloroethene

C

2

H

2

Cl

2

60.1

30.2

trans-1,2-Dichloroethene

C

2

H

2

Cl

2

48.7

28.9

1,1-Dichloro-1-fluoroethane

C

2

H

3

Cl

2

F

32.0

26.06

26.48

Dichlorofluoromethane

CHCl

2

F

8.9

25.2

1,2-Dichloro-1,1,2,3,3,3-hexafluoropropane C

3

Cl

2

F

6

34.1

26.28

26.93

1,2-Dichlorohexane

C

6

H

12

Cl

2

173

48.16

Dichloromethane

CH

2

Cl

2

40

28.06

28.82

1,2-Dichloropentane

C

5

H

10

Cl

2

148.3

36.45

43.89

1,5-Dichloropentane

C

5

H

10

Cl

2

179

50.71

1,3-Dichloropropane

C

3

H

6

Cl

2

120.9

35.18

40.75

1,2-Dichloro-1,1,2,2-tetrafluoroethane

C

2

Cl

2

F

4

3.5

23.3

Dicyclopropyl ketone

C

7

H

10

O

161

53.70

Diethanolamine

C

4

H

11

NO

2

268.8

65.2

1,1-Diethoxyethane

C

6

H

14

O

2

102.25

36.28

43.20

1,2-Diethoxyethane

C

6

H

14

O

2

121.2

36.28

43.20

Diethoxymethane

C

5

H

12

O

2

88

31.33

35.65

Diethylamine

C

4

H

11

N

55.5

29.06

31.31

Diethyl carbonate

C

5

H

10

O

3

126

43.60

Diethyl disulfide

C

4

H

10

S

2

154.0

37.58

45.18

Diethylene glycol

C

4

H

10

O

3

245.8

52.3

Diethylene glycol diethyl ether

C

8

H

18

O

3

188

58.40

Diethylene glycol dimethyl ether

C

6

H

14

O

3

162

36.17

44.69

Diethylene glycol monoethyl ether

C

6

H

14

O

3

196

47.5

Diethylene glycol monomethyl ether

C

5

H

12

O

3

193

46.6

Diethyl ether

C

4

H

10

O

34.5

26.52

27.10

Diethyl malonate

C

7

H

12

O

4

200

54.8

Diethyl oxalate

C

6

H

10

O

4

185.7

42.0

3,3-Diethylpentane

C

9

H

20

146.3

34.61

42.0

Diethyl sulfide

C

4

H

10

S

92.1

31.77

35.80

o-Difluorobenzene

C

6

H

4

F

2

94

32.21

36.18

m-Difluorobenzene

C

6

H

4

F

2

82.6

31.10

34.59

p-Difluorobenzene

C

6

H

4

F

2

89

31.77

35.54

1,1-Difluoroethane

C

2

H

4

F

2

–24.05

21.56

19.08

2,3-Dihydrothiophene

C

4

H

6

S

112.1

33.24

37.74

2,5-Dihydrothiophene

C

4

H

6

S

122.4

34.83

39.95

Diiodomethane

CH

2

I

2

182

42.5

6-108

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Diisobutyl sulfide

C

8

H

18

S

171

48.71

Diisopentyl ether

C

10

H

22

O

172.5

35.1

Diisopropylamine

C

6

H

15

N

83.9

30.40

34.61

Diisopropyl ether

C

6

H

14

O

68.4

29.10

32.12

Diisopropyl sulfide

C

6

H

14

S

120.0

33.80

39.60

Diketene

C

4

H

4

O

2

126.1

36.80

42.89

1,2-Dimethoxyethane

C

4

H

10

O

2

84.5

32.42

36.39

N,N-Dimethylacetamide

C

4

H

9

NO

165

50.24

Dimethylamine

C

2

H

7

N

6.88

26.40

25.05

2,4-Dimethylaniline

C

8

H

11

N

214

61.3

2,5-Dimethylaniline

C

8

H

11

N

214

61.7

N,N-Dimethylaniline

C

8

H

11

N

194.15

52.83

2,2-Dimethylbutane

C

6

H

14

49.73

26.31

27.68

2,3-Dimethylbutane

C

6

H

14

57.93

27.38

29.12

2,3-Dimethyl-2-butanethiol

C

6

H

14

S

126.1

39.3

3,3-Dimethyl-2-butanone

C

6

H

12

O

106.1

33.39

37.91

2,3-Dimethyl-1-butene

C

6

H

12

55.6

29.18

3,3-Dimethyl-1-butene

C

6

H

12

41.2

26.61

2,3-Dimethyl-2-butene

C

6

H

12

73.3

29.64

32.51

1,1-Dimethylcyclohexane

C

8

H

16

119.6

32.51

37.92

cis-1,2-Dimethylcyclohexane

C

8

H

16

129.8

33.47

39.70

trans-1,2-Dimethylcyclohexane

C

8

H

16

123.5

32.96

38.36

cis-1,3-Dimethylcyclohexane

C

8

H

16

120.1

32.91

38.26

trans-1,3-Dimethylcyclohexane

C

8

H

16

124.5

33.39

39.16

cis-1,4-Dimethylcyclohexane

C

8

H

16

124.4

33.28

39.02

trans-1,4-Dimethylcyclohexane

C

8

H

16

119.4

32.56

37.90

cis-1,3-Dimethylcyclopentane

C

7

H

14

90.8

30.40

34.20

Dimethyl decanedioate

C

12

H

22

O

4

86.4

Dimethyl disulfide

C

2

H

6

S

2

109.74

33.78

37.86

Dimethyl ether

C

2

H

6

O

–24.8

21.51

18.51

N,N-Dimethylformamide

C

3

H

7

NO

153

46.89

Dimethyl glutarate

C

7

H

12

O

4

214

65.7

Dimethyl heptanedioate

C

9

H

16

O

4

73.5

2,6-Dimethyl-4-heptanol

C

9

H

20

O

174.5

65.17

2,6-Dimethyl-4-heptanone

C

9

H

18

O

169.4

50.92

2,2-Dimethylhexane

C

8

H

18

106.86

32.07

37.28

2,3-Dimethylhexane

C

8

H

18

115.62

33.17

38.78

2,4-Dimethylhexane

C

8

H

18

109.5

32.51

37.76

2,5-Dimethylhexane

C

8

H

18

109.12

32.54

37.85

3,3-Dimethylhexane

C

8

H

18

111.97

32.31

37.53

3,4-Dimethylhexane

C

8

H

18

117.73

33.24

38.97

Dimethyl 1,6-hexanedioate

C

8

H

14

O

4

69.0

2,5-Dimethyl-2,5-hexanediol

C

8

H

18

O

2

214

85.2

cis-2,2-Dimethyl-3-hexene

C

8

H

16

105.5

36.86

trans-2,2-Dimethyl-3-hexene

C

8

H

16

100.8

37.03

2,5-Dimethyl-3-hexyne-2,5-diol

C

8

H

14

O

2

205

82.8

1,1-Dimethylhydrazine

C

2

H

8

N

2

63.9

32.55

35.0

Dimethyl malonate

C

5

H

8

O

4

181.4

57.5

Dimethyl nonanedioate

C

11

H

20

O

4

82.3

2,4-Dimethyloctane

C

10

H

22

156

36.47

47.13

Dimethyl octanedioate

C

10

H

18

O

4

268

78.1

Dimethyl oxalate

C

4

H

6

O

4

163.5

54.7

3,3-Dimethyloxetane

C

5

H

10

O

80.6

30.85

33.94

2,2-Dimethylpentane

C

7

H

16

79.2

29.23

32.42

2,3-Dimethylpentane

C

7

H

16

89.78

30.46

34.26

Enthalpy of Vaporization

6-109

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

2,4-Dimethylpentane

C

7

H

16

80.49

29.55

32.88

3,3-Dimethylpentane

C

7

H

16

86.06

29.62

33.03

2,2-Dimethyl-3-pentanone

C

7

H

14

O

125.6

36.09

42.34

2,4-Dimethyl-3-pentanone

C

7

H

14

O

125.4

34.64

41.51

2,4-Dimethyl-1-pentene

C

7

H

14

81.6

33.03

4,4-Dimethyl-1-pentene

C

7

H

14

72.5

31.13

2,4-Dimethyl-2-pentene

C

7

H

14

83.4

34.19

cis-4,4-Dimethyl-2-pentene

C

7

H

14

80.4

32.56

trans-4,4-Dimethyl-2-pentene

C

7

H

14

76.7

32.81

2,2-Dimethylpropanenitrile

C

5

H

9

N

106.1

32.40

37.35

2,2-Dimethyl-1-propanethiol

C

5

H

12

S

103.7

36.4

2,3-Dimethylpyridine

C

7

H

9

N

161.12

39.08

47.82

2,4-Dimethylpyridine

C

7

H

9

N

158.38

38.53

47.49

2,5-Dimethylpyridine

C

7

H

9

N

156.98

38.68

47.04

2,6-Dimethylpyridine

C

7

H

9

N

144.01

37.46

45.34

3,4-Dimethylpyridine

C

7

H

9

N

179.10

39.99

50.50

3,5-Dimethylpyridine

C

7

H

9

N

171.84

39.46

49.33

Dimethyl succinate

C

6

H

10

O

4

196.4

61.0

Dimethyl sulfide

C

2

H

6

S

37.33

27.0

27.65

Dimethyl sulfoxide

C

2

H

6

OS

189

43.1

1,3-Dioxane

C

4

H

8

O

2

106.1

34.37

39.09

1,4-Dioxane

C

4

H

8

O

2

101.5

34.16

38.60

Diphenyl ether

C

12

H

10

O

258.0

48.2

1,2-Dipropoxyethane

C

8

H

18

O

2

163.2

50.62

Dipropylamine

C

6

H

15

N

109.3

33.47

40.04

Dipropyl ether

C

6

H

14

O

90.08

31.31

35.69

Dipropyl sulfide

C

6

H

14

S

142.9

36.60

44.21

1-Docosanol

C

22

H

46

O

135.9

Dodecane

C

12

H

26

216.32

44.09

61.52

1,12-Dodecanediol

C

12

H

26

O

2

135

Dodecanenitrile

C

12

H

23

N

277

76.12

1-Dodecanol

C

12

H

26

O

260

90.8

1-Dodecene

C

12

H

24

213.8

60.78

Dodecylbenzene

C

18

H

30

328

86.6

Eicosane

C

20

H

42

343

58.49

101.81

1-Eicosanol

C

20

H

42

O

356

125.9

1,2-Epoxybutane

C

4

H

8

O

63.4

30.3

Ethane

C

2

H

6

–88.6

14.69

5.16

1,2-Ethanediamine

C

2

H

8

N

2

117

37.98

44.98

1,2-Ethanediol

C

2

H

6

O

2

197.3

50.5

63.9

1,2-Ethanediol, diacetate

C

6

H

10

O

4

190

61.44

1,2-Ethanedithiol

C

2

H

6

S

2

146.1

37.93

44.68

Ethanethiol

C

2

H

6

S

35.0

26.79

27.30

Ethanol

C

2

H

6

O

78.29

38.56

42.32

Ethanolamine

C

2

H

7

NO

171

49.83

Ethoxybenzene

C

8

H

10

O

169.81

51.04

2-Ethoxyethanol

C

4

H

10

O

2

135

39.22

48.21

2-Ethoxyethyl acetate

C

6

H

12

O

3

156.4

40.76

52.61

1-Ethoxy-2-methoxyethane

C

5

H

12

O

2

103.5

34.33

39.83

N-Ethylacetamide

C

4

H

9

NO

205

64.89

Ethyl acetate

C

4

H

8

O

2

77.11

31.94

35.60

Ethyl acrylate

C

5

H

8

O

2

99.4

34.7

N-Ethylaniline

C

8

H

11

N

203.0

58.3

Ethylbenzene

C

8

H

10

136.16

35.57

42.24

Ethyl butanoate

C

6

H

12

O

2

121.3

35.47

42.68

6-110

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

2-Ethyl-1-butanol

C

6

H

14

O

147

43.2

2-Ethyl-1-butene

C

6

H

12

64.7

31.13

Ethyl chloroacetate

C

4

H

7

ClO

2

144.3

40.43

49.47

Ethylcyclobutane

C

6

H

12

70.8

28.67

31.24

Ethylcyclohexane

C

8

H

16

131.9

34.04

40.56

Ethylcyclopentane

C

7

H

14

103.5

31.96

36.40

Ethyl dichloroacetate

C

4

H

6

Cl

2

O

2

155

50.60

Ethyl 2,2-dimethylpropanoate

C

7

H

14

O

2

118.4

34.51

41.25

Ethylene

C

2

H

4

–103.77

13.53

N-Ethylformamide

C

3

H

7

NO

198

58.44

Ethyl formate

C

3

H

6

O

2

54.4

29.91

31.96

3-Ethylhexane

C

8

H

18

118.6

33.59

39.64

Ethyl hexanoate

C

8

H

16

O

2

167

51.72

2-Ethylhexanoic acid

C

8

H

16

O

2

228

75.60

2-Ethyl-1-hexanol

C

8

H

18

O

184.6

54.2

68.51

2-Ethylhexyl acetate

C

10

H

20

O

2

199

43.5

2-Ethylhexylamine

C

8

H

19

N

169.2

40.0

Ethylisopropylamine

C

5

H

13

N

69.6

29.94

33.13

Ethyl isopropyl ether

C

5

H

12

O

54.1

28.21

30.08

Ethyl isopropyl sulfide

C

5

H

12

S

107.5

32.74

37.78

Ethyl 3-methylbutanoate

C

7

H

14

O

2

135.0

37.0

2-Ethyl-3-methyl-1-butene

C

7

H

14

89

34.35

1-Ethyl-1-methylcyclopentane

C

8

H

16

121.6

33.20

38.85

3-Ethyl-2-methylpentane

C

8

H

18

115.66

32.93

38.52

3-Ethyl-3-methylpentane

C

8

H

18

118.27

32.78

37.99

3-Ethyl-2-methyl-1-pentene

C

8

H

16

109.5

37.27

Ethyl 2-methylpropanoate

C

6

H

12

O

2

110.1

33.67

39.83

Ethyl methyl sulfide

C

3

H

8

S

66.7

29.53

31.85

3-Ethylpentane

C

7

H

16

93.5

31.12

35.22

Ethyl pentanoate

C

7

H

14

O

2

146.1

36.96

47.01

3-Ethyl-3-pentanol

C

7

H

16

O

142

57.34

Ethyl pentyl ether

C

7

H

16

O

117.6

34.41

41.01

Ethyl propanoate

C

5

H

10

O

2

99.1

33.88

39.21

Ethyl propyl ether

C

5

H

12

O

63.21

28.94

31.43

Ethyl propyl sulfide

C

5

H

12

S

118.6

34.24

39.97

Ethyl trichloroacetate

C

4

H

5

Cl

3

O

2

167.5

50.97

Ethyl vinyl ether

C

4

H

8

O

35.5

26.2

Fluorobenzene

C

6

H

5

F

84.73

31.19

34.58

1-Fluorooctane

C

8

H

17

F

142.3

40.43

49.65

2-Fluorotoluene

C

7

H

7

F

115

35.4

4-Fluorotoluene

C

7

H

7

F

116.6

34.08

39.42

Formamide

CH

3

NO

220

60.15

Formic acid

CH

2

O

2

101

22.69

20.10

Furan

C

4

H

4

O

31.5

27.10

27.45

Furfural

C

5

H

4

O

2

161.7

43.2

Furfuryl alcohol

C

5

H

6

O

2

171

53.6

Glycerol

C

3

H

8

O

3

290

61.0

Glycerol triacetate

C

9

H

14

O

6

259

85.74

Heptadecane

C

17

H

36

302.0

53.58

86.47

1-Heptadecanol

C

17

H

36

O

324

112.5

6-Heptadecanol

C

17

H

36

O

108.6

7-Heptadecanol

C

17

H

36

O

108.2

9-Heptadecanol

C

17

H

36

O

108.5

Heptane

C

7

H

16

98.4

31.77

36.57

1,7-Heptanediol

C

7

H

16

O

2

262

97.9

Enthalpy of Vaporization

6-111

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

1-Heptanol

C

7

H

16

O

176.45

66.81

3-Heptanol

C

7

H

16

O

157

42.5

2-Heptanone

C

7

H

14

O

151.05

47.24

1-Heptene

C

7

H

14

93.64

35.49

cis-2-Heptene

C

7

H

14

98.4

36.26

trans-2-Heptene

C

7

H

14

98

36.27

cis-3-Heptene

C

7

H

14

95.8

35.81

trans-3-Heptene

C

7

H

14

95.7

35.84

Heptylamine

C

7

H

17

N

156

49.96

Heptylbenzene

C

13

H

20

240

64.2

1-Hexacosanol

C

26

H

54

O

153.7

Hexadecane

C

16

H

34

286.86

51.84

81.35

1,16-Hexadecanediol

C

16

H

34

O

2

163

1-Hexadecanol

C

16

H

34

O

312

107.7

1-Hexadecene

C

16

H

32

284.9

80.25

Hexadecylbenzene

C

22

H

38

385

104.8

Hexafluoroacetylacetone

C

5

H

2

F

6

O

2

54.15

27.05

30.58

Hexafluorobenzene

C

6

F

6

80.32

31.66

35.71

Hexafluoroethane

C

2

F

6

–78.1

16.15

Hexane

C

6

H

14

68.73

28.85

31.56

1,6-Hexanediol

C

6

H

14

O

2

208

90.2

Hexanenitrile

C

6

H

11

N

163.65

47.91

1-Hexanol

C

6

H

14

O

157.6

44.50

61.61

2-Hexanol

C

6

H

14

O

140

41.01

58.46

2-Hexanone

C

6

H

12

O

127.6

36.35

43.14

3-Hexanone

C

6

H

12

O

123.5

35.36

42.47

1-Hexene

C

6

H

12

63.48

30.61

cis-2-Hexene

C

6

H

12

68.8

32.19

trans-2-Hexene

C

6

H

12

67.9

31.60

cis-3-Hexene

C

6

H

12

66.4

31.23

trans-3-Hexene

C

6

H

12

67.1

31.55

Hexylamine

C

6

H

15

N

132.8

36.54

45.10

Hexylbenzene

C

12

H

18

226.1

60.4

Hexyl methyl ether

C

7

H

16

O

126.1

34.93

42.07

Indan

C

9

H

10

177.97

39.63

48.79

Iodobenzene

C

6

H

5

I

188.4

39.5

1-Iodobutane

C

4

H

9

I

130.5

34.66

40.63

2-Iodobutane

C

4

H

9

I

120.1

33.27

38.46

Iodoethane

C

2

H

5

I

72.3

29.44

31.93

1-Iodohexane

C

6

H

13

I

181.3

49.75

Iodomethane

CH

3

I

42.43

27.34

27.97

1-Iodo-2-methylpropane

C

4

H

9

I

121.1

33.54

38.83

2-Iodo-2-methylpropane

C

4

H

9

I

100.1

31.43

35.41

1-Iodopentane

C

5

H

11

I

157.0

45.27

1-Iodopropane

C

3

H

7

I

102.5

32.08

36.25

2-Iodopropane

C

3

H

7

I

89.5

30.68

34.06

Isobutane

C

4

H

10

–11.73

21.30

19.23

Isobutyl acetate

C

6

H

12

O

2

116.5

35.9

Isobutylamine

C

4

H

11

N

67.75

30.61

33.85

Isobutylbenzene

C

10

H

14

172.79

48.0

Isobutyl formate

C

5

H

10

O

2

98.2

33.6

Isobutyl isobutanoate

C

8

H

16

O

2

148.6

38.2

Isobutyl methyl ether

C

5

H

12

O

58.6

28.02

30.13

Isopentane

C

5

H

12

27.88

24.69

24.85

Isopentyl acetate

C

7

H

14

O

2

142.5

37.5

6-112

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Isopentyl isopentanoate

C

10

H

20

O

2

190.4

45.9

Isopropyl acetate

C

5

H

10

O

2

88.7

32.93

37.20

Isopropylamine

C

3

H

9

N

31.76

27.83

28.36

Isopropylbenzene

C

9

H

12

152.41

45.13

Isopropylcyclohexane

C

9

H

18

154.8

44.02

Isopropylcyclopentane

C

8

H

16

126.5

33.56

39.44

Isopropylmethylamine

C

4

H

11

N

50.4

28.71

30.69

1-Isopropyl-4-methylbenzene

C

10

H

14

177.1

38.2

Isopropyl methyl ether

C

4

H

10

O

30.77

26.05

26.41

Isopropyl methyl sulfide

C

4

H

10

S

84.8

30.71

34.15

Isopropylpropylamine

C

6

H

15

N

96.9

32.14

37.23

Isopropyl propyl sulfide

C

6

H

14

S

132.1

35.11

41.78

Isoquinoline

C

9

H

7

N

243.22

49.0

60.26

Mesityl oxide

C

6

H

10

O

130

36.1

Methane

CH

4

–161.48

8.19

Methanol

CH

4

O

64.6

35.21

37.43

2-Methoxyethanol

C

3

H

8

O

2

124.1

37.54

45.17

2-Methoxyethyl acetate

C

5

H

10

O

3

143

43.9

Methyl acetate

C

3

H

6

O

2

56.87

30.32

32.29

Methyl acrylate

C

4

H

6

O

2

80.7

33.1

2-Methylacrylonitrile

C

4

H

5

N

90.3

31.8

Methylamine

CH

5

N

–6.32

25.60

23.37

2-Methylaniline

C

7

H

9

N

200.3

44.6

3-Methylaniline

C

7

H

9

N

203.3

44.9

4-Methylaniline

C

7

H

9

N

200.4

44.3

Methyl benzoate

C

8

H

8

O

2

199

55.57

1-Methylbicyclo[3,1,0]hexane

C

7

H

12

93.1

31.07

34.77

3-Methylbutanenitrile

C

5

H

9

N

127.5

35.10

41.64

2-Methyl-1-butanethiol

C

5

H

12

S

119.1

33.79

39.45

2-Methyl-2-butanethiol

C

5

H

12

S

99.1

31.37

35.67

3-Methyl-2-butanethiol

C

5

H

12

S

109.8

37.5

Methyl butanoate

C

5

H

10

O

2

102.8

33.79

39.28

2-Methylbutanoic acid

C

5

H

10

O

2

177

46.91

2-Methyl-1-butanol

C

5

H

12

O

127.5

55.16

3-Methyl-1-butanol

C

5

H

12

O

131.1

44.07

55.61

2-Methyl-2-butanol

C

5

H

12

O

102.4

39.04

50.10

3-Methyl-2-butanol

C

5

H

12

O

112.9

53.0

3-Methyl-2-butanone

C

5

H

10

O

94.33

32.35

36.78

2-Methyl-1-butene

C

5

H

10

31.2

25.50

25.92

3-Methyl-1-butene

C

5

H

10

20.1

23.77

2-Methyl-2-butene

C

5

H

10

38.56

26.31

27.06

(1-Methylbutyl)benzene

C

11

H

16

199

53.0

Methyl tert-butyl ether

C

5

H

12

O

55.0

27.94

29.82

Methyl chloroacetate

C

3

H

5

ClO

2

129.5

39.23

46.73

Methyl cyanoacetate

C

4

H

5

NO

2

200.5

48.2

Methyl cyclobutanecarboxylate

C

6

H

10

O

2

135.5

37.13

44.72

Methylcyclohexane

C

7

H

14

100.93

31.27

35.36

1-Methylcyclohexanol

C

7

H

14

O

155

79.0

cis-2-Methylcyclohexanol

C

7

H

14

O

165

48.5

trans-2-Methylcyclohexanol

C

7

H

14

O

167.5

53.0

Methylcyclopentane

C

6

H

12

71.8

29.08

31.64

Methyl cyclopropanecarboxylate

C

5

H

8

O

2

114.9

35.25

41.27

2-Methyldecane

C

11

H

24

189.3

40.25

54.28

4-Methyldecane

C

11

H

24

187

40.70

53.76

Methyl dichloroacetate

C

3

H

4

Cl

2

O

2

142.9

39.28

47.72

Enthalpy of Vaporization

6-113

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Methyl 2,2-dimethylpropanoate

C

6

H

12

O

2

101.1

33.42

38.76

Methyl dodecanoate

C

13

H

26

O

2

267

77.17

N-Methylformamide

C

2

H

5

NO

199.51

56.19

Methyl formate

C

2

H

4

O

2

31.7

27.92

28.35

2-Methylheptane

C

8

H

18

117.66

33.26

39.67

3-Methylheptane

C

8

H

18

118.9

33.66

39.83

4-Methylheptane

C

8

H

18

117.72

33.35

39.69

Methyl heptanoate

C

8

H

16

O

2

174

51.62

2-Methyl-2-heptanol

C

8

H

18

O

156

62.87

2-Methylhexane

C

7

H

16

90.04

30.62

34.87

3-Methylhexane

C

7

H

16

92

30.9

Methyl hexanoate

C

7

H

14

O

2

149.5

38.55

48.04

2-Methyl-2-hexanol

C

7

H

16

O

143

58.57

5-Methyl-3-hexanol

C

7

H

16

O

147

59.82

cis-3-Methyl-3-hexene

C

7

H

14

95.4

36.31

trans-3-Methyl-3-hexene

C

7

H

14

93.5

35.70

Methylhydrazine

CH

6

N

2

87.5

36.12

40.37

Methyl isobutanoate

C

5

H

10

O

2

92.5

32.61

37.32

Methyl methacrylate

C

5

H

8

O

2

100.5

36.0

1-Methylnaphthalene

C

11

H

10

244.7

45.5

2-Methylnonane

C

10

H

22

167.1

38.23

49.63

3-Methylnonane

C

10

H

22

167.9

38.26

49.71

5-Methylnonane

C

10

H

22

165.1

38.14

49.34

Methyl octanoate

C

9

H

18

O

2

192.9

56.41

Methyloxirane

C

3

H

6

O

35

27.35

27.89

2-Methylpentane

C

6

H

14

60.26

27.79

29.89

3-Methylpentane

C

6

H

14

63.27

28.06

30.28

2-Methyl-2,4-pentanediol

C

6

H

14

O

2

197.1

57.3

Methyl pentanoate

C

6

H

12

O

2

127.4

35.36

43.10

2-Methyl-1-pentanol

C

6

H

14

O

149

50.2

4-Methyl-1-pentanol

C

6

H

14

O

151.9

44.46

60.47

2-Methyl-2-pentanol

C

6

H

14

O

121.1

39.59

54.77

4-Methyl-2-pentanol

C

6

H

14

O

131.6

44.2

3-Methyl-2-pentanone

C

6

H

12

O

117.5

34.16

40.53

4-Methyl-2-pentanone

C

6

H

12

O

116.5

34.49

40.61

2-Methyl-3-pentanone

C

6

H

12

O

113.5

33.84

39.79

2-Methyl-1-pentene

C

6

H

12

62.1

30.48

3-Methyl-1-pentene

C

6

H

12

54.2

28.62

4-Methyl-1-pentene

C

6

H

12

53.9

28.71

2-Methyl-2-pentene

C

6

H

12

67.3

31.60

3-Methyl-cis-2-pentene

C

6

H

12

67.7

32.09

3-Methyl-trans-2-pentene

C

6

H

12

70.4

31.35

4-Methyl-cis-2-pentene

C

6

H

12

56.3

29.48

4-Methyl-trans-2-pentene

C

6

H

12

58.6

29.97

Methyl pentyl ether

C

6

H

14

O

99

32.02

36.85

Methyl pentyl sulfide

C

6

H

14

S

145.1

37.41

45.24

2-Methylpropanenitrile

C

4

H

7

N

103.9

32.39

37.13

2-Methyl-1-propanethiol

C

4

H

10

S

88.5

31.01

34.63

2-Methyl-2-propanethiol

C

4

H

10

S

64.2

28.45

30.78

Methyl propanoate

C

4

H

8

O

2

79.8

32.24

35.85

2-Methylpropanoic acid

C

4

H

8

O

2

154.45

35.30

2-Methyl-1-propanol

C

4

H

10

O

107.89

41.82

50.82

2-Methyl-2-propanol

C

4

H

10

O

82.4

39.07

46.69

Methyl propyl ether

C

4

H

10

O

39.1

26.75

27.60

Methyl propyl sulfide

C

4

H

10

S

95.6

32.08

36.24

6-114

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

2-Methylpyridine

C

6

H

7

N

129.38

36.17

42.48

3-Methylpyridine

C

6

H

7

N

144.14

37.35

44.44

4-Methylpyridine

C

6

H

7

N

145.36

37.51

44.56

2-Methylquinoline

C

10

H

9

N

246.5

66.1

4-Methylquinoline

C

10

H

9

N

262

67.6

6-Methylquinoline

C

10

H

9

N

258.6

67.7

8-Methylquinoline

C

10

H

9

N

247.5

65.7

Methyl salicylate

C

8

H

8

O

3

222.9

46.7

4-Methylthiazole

C

4

H

5

NS

133.3

37.58

43.85

2-Methylthiophene

C

5

H

6

S

112.6

33.90

38.87

3-Methylthiophene

C

5

H

6

S

115.5

34.24

39.43

Methyl trichloroacetate

C

3

H

3

Cl

3

O

2

153.8

48.33

Molybdenum carbonyl

C

6

MoO

6

701

72.51

Morpholine

C

4

H

9

NO

128

37.1

Naphthalene

C

10

H

8

217.9

43.2

Neopentane

C

5

H

12

9.48

22.74

21.84

Nitrobenzene

C

6

H

5

NO

2

210.8

55.01

Nitroethane

C

2

H

5

NO

2

114.0

38.0

Nitromethane

CH

3

NO

2

101.19

33.99

38.27

1-Nitropropane

C

3

H

7

NO

2

131.1

38.5

2-Nitropropane

C

3

H

7

NO

2

120.2

36.8

Nonadecane

C

19

H

40

329.9

56.93

96.4

Nonane

C

9

H

20

150.82

37.18

46.55

1,9-Nonanediol

C

9

H

20

O

2

112.5

1-Nonanol

C

9

H

20

O

213.37

76.86

2-Nonanone

C

9

H

18

O

195.3

56.44

5-Nonanone

C

9

H

18

O

188.45

53.30

Nonylbenzene

C

15

H

24

280.5

74.1

Octadecane

C

18

H

38

316.3

55.23

91.44

1-Octadecanol

C

18

H

38

O

335

116.8

cis-9-Octadecenoic acid

C

18

H

34

O

2

360

67.4

Octane

C

8

H

18

125.67

34.41

41.49

1,8-Octanediol

C

8

H

18

O

2

104.9

Octanenitrile

C

8

H

15

N

205.25

56.80

Octanoic acid

C

8

H

16

O

2

239

58.5

1-Octanol

C

8

H

18

O

195.16

70.98

2-Octanol

C

8

H

18

O

179.3

44.4

1-Octene

C

8

H

16

121.29

34.07

40.34

Octylbenzene

C

14

H

22

264

69.1

1-Octyne

C

8

H

14

126.3

35.83

42.30

2-Octyne

C

8

H

14

137.6

37.26

44.49

3-Octyne

C

8

H

14

133.1

36.94

43.92

4-Octyne

C

8

H

14

131.6

36.0

42.73

Oxetane

C

3

H

6

O

47.6

28.67

29.85

2-Oxetanone

C

3

H

4

O

2

162

47.03

Oxirane

C

2

H

4

O

10.6

25.54

24.75

Pentachloroethane

C

2

HCl

5

162.0

36.9

Pentadecane

C

15

H

32

270.6

50.08

76.77

1,15-Pentadecanediol

C

15

H

32

O

2

139

1-Pentadecanol

C

15

H

32

O

300

103.5

Pentadecylbenzene

C

21

H

36

373

100.3

Pentafluorobenzene

C

6

HF

5

85.74

32.15

36.27

2,3,4,5,6-Pentafluorotoluene

C

7

H

3

F

5

117.5

34.75

41.12

2,2,4,6,6-Pentamethylheptane

C

12

H

26

177.8

48.97

Pentane

C

5

H

12

36.06

25.79

26.43

Enthalpy of Vaporization

6-115

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

1,5-Pentanediol

C

5

H

12

O

2

239

60.7

83.0

2,4-Pentanedione

C

5

H

8

O

2

138

34.30

41.77

Pentanenitrile

C

5

H

9

N

141.3

36.09

43.60

1-Pentanethiol

C

5

H

12

S

126.6

34.88

41.24

Pentanoic acid

C

5

H

10

O

2

186.1

44.1

1-Pentanol

C

5

H

12

O

137.98

44.36

57.02

2-Pentanol

C

5

H

12

O

119.3

41.40

54.21

3-Pentanol

C

5

H

12

O

116.25

54.0

2-Pentanone

C

5

H

10

O

102.26

33.44

38.40

3-Pentanone

C

5

H

10

O

101.7

33.45

38.52

1-Pentene

C

5

H

10

29.96

25.20

25.47

cis-2-Pentene

C

5

H

10

36.93

26.86

trans-2-Pentene

C

5

H

10

36.34

26.76

trans-3-Pentenenitrile

C

5

H

7

N

144

37.09

44.77

Pentyl acetate

C

7

H

14

O

2

149.2

38.42

48.56

Pentylamine

C

5

H

13

N

104.3

34.01

40.08

Pentylbenzene

C

11

H

16

205.4

55.1

Pentylcyclohexane

C

11

H

22

203.7

53.88

Perfluorobutane

C

4

F

10

-1.9

22.9

Perfluorocyclobutane

C

4

F

8

-5.91

23.2

Perfluorodecalin

C

10

F

18

142.02

41.54

Perfluorohexane

C

6

F

14

57.14

32.47

Perfluorononane

C

9

F

20

117.61

45.27

Perfluorooctane

C

8

F

18

105.9

33.38

41.13

Perfluorotoluene

C

7

F

8

103.55

40.52

Phenanthrene

C

14

H

10

340

75.50

Phenol

C

6

H

6

O

181.87

45.69

57.82

Piperidine

C

5

H

11

N

106.22

39.29

Propanal

C

3

H

6

O

48

28.31

29.62

Propane

C

3

H

8

-42.1

19.04

14.79

1,3-Propanediamine

C

3

H

10

N

2

139.8

40.85

50.16

1,2-Propanediol

C

3

H

8

O

2

187.6

52.4

1,3-Propanediol

C

3

H

8

O

2

214.4

57.9

69.8

1,3-Propanedithiol

C

3

H

8

S

2

172.9

49.66

Propanenitrile

C

3

H

5

N

97.14

31.81

36.03

1-Propanethiol

C

3

H

8

S

67.8

29.54

31.89

2-Propanethiol

C

3

H

8

S

52.6

27.91

29.45

Propanoic acid

C

3

H

6

O

2

141.15

32.14

Propanoic anhydride

C

6

H

10

O

3

170

41.7

1-Propanol

C

3

H

8

O

97.2

41.44

47.45

2-Propanol

C

3

H

8

O

82.3

39.85

45.39

Propene

C

3

H

6

-47.69

18.42

14.24

2-Propoxyethanol

C

5

H

12

O

2

149.8

41.40

52.12

Propyl acetate

C

5

H

10

O

2

101.3

33.92

39.72

Propylamine

C

3

H

9

N

47.22

29.55

31.27

Propylbenzene

C

9

H

12

159.24

46.22

Propylcyclohexane

C

9

H

18

156

45.08

Propylcyclopentane

C

8

H

16

131

34.70

41.08

Propyl formate

C

4

H

8

O

2

80.9

33.61

37.53

Propyl propanoate

C

6

H

12

O

2

122.5

35.54

43.45

Pyridazine

C

4

H

4

N

2

208

53.47

Pyridine

C

5

H

5

N

115.23

35.09

40.21

Pyrimidine

C

4

H

4

N

2

123.8

43.09

49.79

Pyrrole

C

4

H

5

N

129.79

38.75

45.09

Pyrrolidine

C

4

H

9

N

86.56

33.01

37.52

6-116

Enthalpy of Vaporization

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

Quinoline

C

9

H

7

N

237.16

49.7

59.30

Salicylaldehyde

C

7

H

6

O

2

197

38.2

Spiro[2.2]pentane

C

5

H

8

39

26.76

27.49

Styrene

C

8

H

8

145

38.7

Succinonitrile

C

4

H

4

N

2

266

48.5

1,1,2,2-Tetrabromoethane

C

2

H

2

Br

4

243.5

48.7

1,1,2,2-Tetrachloroethane

C

2

H

2

Cl

4

145.2

37.64

45.71

Tetrachloroethene

C

2

Cl

4

121.3

34.68

39.68

Tetrachloromethane

CCl

4

76.8

29.82

32.43

Tetradecane

C

14

H

30

253.58

48.16

71.73

1,14-Tetradecanediol

C

14

H

30

O

2

149.7

Tetradecanenitrile

C

14

H

27

N

85.29

1-Tetradecanol

C

14

H

30

O

287

98.9

Tetradecylbenzene

C

20

H

34

359

95.8

Tetrahydrofuran

C

4

H

8

O

65

29.81

31.99

Tetrahydrofurfuryl alcohol

C

5

H

10

O

2

178

45.2

1,2,3,4-Tetrahydronaphthalene

C

10

H

12

207.6

43.9

Tetrahydropyran

C

5

H

10

O

88

31.17

34.58

Tetrahydrothiophene

C

4

H

8

S

121.1

34.66

39.43

2,2,3,3-Tetramethylbutane

C

8

H

18

106.45

42.90

2,2,4,4-Tetramethylpentane

C

9

H

20

122.29

32.51

38.49

Tetranitromethane

CN

4

O

8

126.1

40.74

49.93

Thiacyclohexane

C

5

H

10

S

141.8

35.96

42.58

Thietane

C

3

H

6

S

95.0

32.32

35.97

Thiophene

C

4

H

4

S

84.0

31.48

34.70

Toluene

C

7

H

8

110.63

33.18

38.01

Triacetamide

C

6

H

9

NO

3

60.41

Tribromomethane

CHBr

3

149.1

39.66

46.05

Tributylamine

C

12

H

27

N

216.5

46.9

Tributyl borate

C

12

H

27

BO

3

234

56.1

1,1,1-Trichloroethane

C

2

H

3

Cl

3

74.09

29.86

32.50

1,1,2-Trichloroethane

C

2

H

3

Cl

3

113.8

34.82

40.24

Trichloroethene

C

2

HCl

3

87.21

31.40

34.54

Trichlorofluoromethane

CCl

3

F

23.7

25.1

Trichloromethane

CHCl

3

61.17

29.24

31.28

1,2,3-Trichloropropane

C

3

H

5

Cl

3

157

37.1

1,1,1-Trichloro-2,2,2-trifluoroethane

C

2

Cl

3

F

3

45.5

26.85

28.08

1,1,2-Trichloro-1,2,2-trifluoroethane

C

2

Cl

3

F

3

47.7

27.04

28.40

Tridecane

C

13

H

28

235.47

46.20

66.68

1,13-Tridecanediol

C

13

H

28

O

2

133

1-Tridecanol

C

13

H

28

O

274

94.7

Tridecylbenzene

C

19

H

32

346

91.8

Triethylamine

C

6

H

15

N

89

31.01

34.84

Triethylene glycol

C

6

H

14

O

4

285

71.4

Trifluoroacetic acid

C

2

HF

3

O

2

73

33.3

1,1,1-Trifluoroethane

C

2

H

3

F

3

-47.25

18.99

(Trifluoromethyl)benzene

C

7

H

5

F

3

102.1

32.63

37.60

Trimethylamine

C

3

H

9

N

2.87

22.94

21.66

1,2,3-Trimethylbenzene

C

9

H

12

176.12

49.05

1,2,4-Trimethylbenzene

C

9

H

12

169.38

47.93

1,3,5-Trimethylbenzene

C

9

H

12

164.74

47.50

2,2,3-Trimethylbutane

C

7

H

16

80.86

28.90

32.05

2,3,3-Trimethyl-1-butene

C

7

H

14

77.9

32.09

2,2,5-Trimethylhexane

C

9

H

20

124.09

33.65

40.16

2,3,5-Trimethylhexane

C

9

H

20

131.4

34.43

41.41

Enthalpy of Vaporization

6-117

background image

Name

Mol. Form.

t

b

°C

Δ

vap

H(t

b

)

kJ/mol

Δ

vap

H(25°C)

kJ/mol

3,5,5-Trimethyl-1-hexanol

C

9

H

20

O

194

67.86

2,4,7-Trimethyloctane

C

11

H

24

168.1

38.22

49.91

2,2,3-Trimethylpentane

C

8

H

18

110

31.94

36.91

2,2,4-Trimethylpentane

C

8

H

18

99.22

30.79

35.14

2,3,3-Trimethylpentane

C

8

H

18

114.8

32.12

37.27

2,3,4-Trimethylpentane

C

8

H

18

113.5

32.36

37.75

2,2,4-Trimethyl-3-pentanone

C

8

H

16

O

135.1

35.64

43.30

2,4,4-Trimethyl-1-pentene

C

8

H

16

101.4

35.59

2,4,4-Trimethyl-2-pentene

C

8

H

16

104.9

37.23

2,3,6-Trimethylpyridine

C

8

H

11

N

171.6

39.95

50.61

2,4,6-Trimethylpyridine

C

8

H

11

N

170.6

39.87

50.33

Tris(perfluorobutyl)amine

C

12

F

27

N

178

46.4

Undecane

C

11

H

24

195.9

41.91

56.58

1,11-Undecanediol

C

11

H

24

O

2

132

Undecanenitrile

C

11

H

21

N

253

71.14

1-Undecanol

C

11

H

24

O

245

85.8

Undecylbenzene

C

17

H

28

316

82.4

Vinyl acetate

C

4

H

6

O

2

72.8

34.6

o-Xylene

C

8

H

10

144.5

36.24

43.43

m-Xylene

C

8

H

10

139.07

35.66

42.65

p-Xylene

C

8

H

10

138.23

35.67

42.40

2,4-Xylenol

C

8

H

10

O

210.98

64.96

2,5-Xylenol

C

8

H

10

O

211.1

46.9

2,6-Xylenol

C

8

H

10

O

201.07

75.31

3,4-Xylenol

C

8

H

10

O

227

85.03

3,5-Xylenol

C

8

H

10

O

221.74

82.01

6-118

Enthalpy of Vaporization


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