Geochemia węgla
Krążenie węgla w przyrodzie
Prelekcja na dwóch materiałach źródłowych wzbogaconych
informacjami podręcznikowymi oraz materiałami własnymi AT
1/
IPCC: http://www.ipcc.ch/; United Nations Environmental Program (UNEP:
http://www.grida.no/climate/vital/06.htm)
2/
Anthropogenic Influences on the Global Carbon Cycle and its Implications for the Future
Pushkaraj Sardesai and Sarah Eggleston
Earth System Science and Policy
1) Janzen, H.H. “Carbon cycling in earth systems – a soil science perspective.” Agriculture, Ecosystems &
Environment 104 (2004) 399-417.
2) Jorge L. Sarmiento & Steven C. Wofsy Co-Chairs A U.S Carbon Cycle Science Plan. A report of the Carbon and
Climate working Group. 1999
3) http://www.cypenv.org/Files/sequest.htm
4) http://cdiac.esd.ornl.gov/trends/emis/em_cont.htm
Izotopy węgla
Węgiel ma trzy naturalne izotopy:
12C trwały 98,89 %
13C trwały 1,11 %
14C nietrwały, promieniotwórczy
rst.gsfc.nasa.gov/ Sect16/Sect16_4.html
Natural Carbon Cycle
Terminy ogólne
OCEAN UPTAKE Dissolving of CO
2
gas into the oceans and inflow of
carbon carried from land by rivers.
OCEAN RELEASE Return of carbon in the oceans directly back to the
atmosphere as CO
2
gas.
SEDIMENTATION Slow burial of plant and animal matter on land and
on the ocean floor, which eventually becomes limestone, coal, gas,
and oil.
RESPIRATION Slow combustion of carbon compounds, producing
energy within organisms and releasing CO
2
.
PHOTOSYNTHESIS Conversion of CO
2
into energy-rich carbon
compounds by plants.
2 H
2
O + CO
2
+ hv = CH
2
O + H
2
O + O
2
(C
2
H – węglowodany)
Ca(HCO
3
)
2
CaCO
3
+ H
2
O + CO
2
Natural Carbon Cycle
www.koshland-science-
museum.org/exhibitgcc/images/carbon02.jsp.
*
*
*
*
K.L. Griffin, Columbia U. 2002
Bilans węgla w
atmosferze
Grassland
s
Boreal
Forest
Tundra
Desert
Chaparral
Temperate
Forest
Alpine
Tropical
Forest
Savann
a
Biomes
http://www.blueplanetbiomes.org/world_biomes.htm
Carbon
Storage
Potential of
Biomes
Efektywność wiązania
Znaczenie w skali globalnej
PRODUKCJA PIERWOTNA
Effect of CO
2
& Greenhouse gases
Indicators of the Human Influence
Indicators of the Human Influence
on the Atmosphere during the Industrial Era
on the Atmosphere during the Industrial Era
Source: IPCC TAR 2001
http://www.climateark.org/vital/05.htm
www.pewclimate.org/
images/figure4.gif
Human Impacts On The Carbon Cycle
http://cdiac.esd.ornl.gov/trends/landuse/houghton/houghton.gif
http://cdiac.esd.ornl.gov/trends/meth/methane.gif
Emissions of carbon dioxide due to changes in land use mainly come from the
cutting down of forests and instead using the land for agriculture or built-up areas,
urbanization, roads etc.
http://www.grida.no/climate/vital/10.htm
Global distribution of large stationary sources of CO2
SRCCS Figure TS-2a
Carbon dioxide emissions comes from energy production, industrial
processes and transport.
http://www.grida.no/climate/vital/09.htm
Change in Forest Area, ‘90 -‘95
C.S. Potter, BioScience, 49:769 (1999)
Area (% y
-1
)
-3
-2
-1
0
1
2
3
Philippines
Paraguay
Thailand
Malaysia
Burma
Bolivia
Venezuela
Angola
Tanzania
Indonesia
Mexico
Zambia
Zaire
Colombia
Brazil
India
Australia
Canada
Former USSR
Italy
Poland
United States
Norway
United Kingdom
Portugal
France
Greece
Ireland
• Brazil: -0.25 Pg/y
• Zaire:
-0.10 Pg/y
• Indonesia:
-0.10 Pg/y
• USA:
0.11 Pg/y
• F USSR: 0.07 Pg/y
• France: 0.04 Pg/y
• Global net: -1.15
Pg/y
Possible way to mitigate Point Source Carbon dioxide
Pollution
With help of atmospheric modeling and satellite images,
determine the effective radius from a point source within
which the concentration of CO
2
are high.
With help of satellite images identify the type and
concentration of biomass in the area.
Determine the uptake of carbon dioxide by this biomass.
(carbon sequestered).
Determine the potential for carbon sequestration with help of
local man managed ecosystems.
e.g. Trees planted in this radius will sequester carbon more
effectively and rapidly then elsewhere, and reduce overall
national emissions.
www.clarkson.edu/.../ Fig8_small.jpe
www.clarkson.edu/.../ Fig8_small.jpe
www.clarkson.edu/.../ Fig8_small.jpe
Fossil Fuel CO
2
emission and carbon
sequestration