antiaroma
tic
nonaromatic
aromatic
antiaromatic
NH
antiaromati
c
aromatic
antiaromat
ic
aromatic
aromatic
Predict the products.
1)
This cation is 2° and 3°. Other cation is 2° and 2°.
Thermodynamic product is most substituted alkene.
H
Br
+
+
Br-
Br
4)
H
3
CO
O
O
H
3
CO
H
H
HCl
Cl
+
Cl
+
CO
2
CH
3
CO
2
CH
3
heat
CO
2
CH
3
CO
2
CH
3
+
CO
2
CH
3
CO
2
CH
3
+
O
O
heat
O
O
H
H
+
O
O
H
H
+
CO
2
CH
3
heat
CO
2
CH
3
+
CO
2
CH
3
CO
2
CH
3
heat
CO
2
CH
3
CO
2
CH
3
28)
O
ClCOCH
2
CH2CH
2
CH
3
/AlCl
3
Zn(Hg)
HCl
b
)
ClCOC(CH3)3
AlCl
3
O
NH
2
NH
2
/KOH
CH3Cl
AlCl
3
CO
2
H
KMnO
4
NO
2
H
2
Pd-C
HNO
3
/
H
2
SO
4
NH
2
Br
Br
+
CO
2
H
Br
CH
3
Cl/
AlCl
3
Br
2
FeBr
3
KMnO
4
32.Predit the prodcut.
d)
OH
NO
2
Sn
HCl
OH
NH
2
e
)
OH
O
R
NH
2
NH
2
-OH
OH
R
35.Predict the products.
a)
NO
2
HO
HNO
3
H2SO
4
NO
2
HO
NO
2
HO
O
2
N
NO
2
b)
OH
SO
3
H2SO
4
HO
HO
SO
3
H
SO
3
H
c)
O
CH
3
CH
2
Cl
O
Cl
AlCl
3
O
O
Cl
54c) Fill in the blanks.
Cl
2
FeCl
3
Cl
Cl
O
CH
3
CH
2
CH
2
COCl
AlCl
3
Zn(Hg)
HCl
Cl
1
2
3
f)
CH
3
Cl
AlCl
3
SO
3
H
2
SO
4
SO
3
H
CO
2
H
SO
3
H
KMnO
4
1
2
3
j)
CH
3
Cl
AlCl
3
CH
3
SO
3
H
2
SO
4
CH
3
SO
3
H
Cl
2
(excess)
FeCl
3
CH
3
Cl
Cl
SO
3
H
CO
2
H
Cl
Cl
SO
3
H
KMnO
4
1
2
3
4
k
)
(CH
3
)
2
CHCl
AlCl
3
NO
2
HNO
3
H
2
SO
4
Cl
2
FeCl
3
NO
2
Cl
NO
2
Cl
Br
Br
2
hv
KOCH
3
NO
2
Cl
1
2
3
4
5
55d)
CH
3
Cl
AlCl
3
HNO
3
H
2
SO
4
O
2
N
CO
2
H
O
2
N
Sn/HCl
CO
2
H
H
2
N
KMnO
4
1
2
3
4
f)
O
CH
3
CH
2
COCl
AlCl
3
Br
2
FeBr
3
O
Br
NH
2
NH
2
-OH
Br
Br
NO
2
HNO
3
H
2
SO
4
H
2
Pd-C
Br
NH
2
1
2
3
4
5
AlCl
3
O
CH
3
CH
2
CH
2
COCl
O
O
2
N
HNO
3
H
2
SO
4
NH
2
NH
2
-OH
O
2
N
H
2
Pd-C
H
2
N
j)
1
2
3
4
O
AlCl3
CH3CH2CH2COCl
Cl
2
FeCl
3
O
Cl
O
Cl
Br
Br
2
hv
O
Cl
HO
-OH
POC
O
Cl
O
k)
1
2
3
4
5
CH
3
CH
2
Cl
AlCl
3
Br
Br
2
hv
KOR
Br
2
Br
Br
2 NaNH
2
58a
)
1
2
3
4
5
CH
NaH
b)
C
CH
3
CH
2
Br
1
2
h)
Cl
2
FeCl
3
Cl
Cl
NO
2
HNO
3
H
2
SO
4
Br
2
hv
Cl
NO
2
Br
Cl
NO
2
KOR
mClPBA
Cl
NO
2
O
H
2
O
Cl
NO
2
HO
1
2
3
4
5
6
Document Outline
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