Ester |
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mieszanina 0,1 mola NaOH i 0,1 mola estru |
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T= 23 stopnie Celcjusza |
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208,05000000 |
178,39704960 |
0,857472 |
0,857472 |
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cz |
100 |
M |
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251,37000000 |
32,10760752 |
0,1543264 |
0,1543264 |
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t [min] |
S [ mS] |
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Przewodnictwo molowe 0,05 molowego roztworu NaOH lambda prim wyraża równanie |
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0 |
9,51 |
0,951 |
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2 |
7,58 |
0,758 |
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4 |
6,67 |
0,667 |
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208,05 |
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6 |
6,11 |
0,611 |
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128,703703703704 |
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8 |
5,57 |
0,557 |
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10 |
5,5 |
0,55 |
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12 |
5,33 |
0,533 |
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14 |
5,18 |
0,518 |
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16 |
5,05 |
0,505 |
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H |
10402,5 |
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18 |
4,96 |
0,496 |
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20 |
4,88 |
0,488 |
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0,882528 |
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80,8177907913669 |
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80,8192903597123 |
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czysty 0,05M NaOH |
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80,819997410072 |
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T = 23 stopnie Celcjusza |
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80,8204325179856 |
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S= 9,24 [mS] |
9,24 |
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80,8208520863309 |
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69,1282104108861 |
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8,11() |
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9,24 |
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80,8209064748202 |
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69,129493079901 |
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czysty 0,05M NaOH |
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80,8210385611511 |
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69,1300978616645 |
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T =35 stopni Celcjusza |
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80,8211551079137 |
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69,1304700350574 |
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S= 1,663 [mS] |
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80,8212561151079 |
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69,1308289165434 |
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1,663 |
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80,8213260431655 |
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69,1308754382176 |
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69,1309884194261 |
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k |
0,000000000000000000000000 |
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En akt. Estru = 46,9 kJ/mol |
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69,1310881087278 |
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A= 1,4 * 10 ^10 albo do ^20 bo nie mogę się rozczytac ale raczej do 10 cm^3/mol*S |
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69,1311745061226 |
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stała czujnika k = 98,2 1/m |
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69,1312343197036 |
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98,2 |
k |
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69,1312874873312 |
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mieszanina 0,1 mola NaOH i 0,1 M estru |
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T= 35 stopni celcjusza |
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t [s] |
S [ mS] |
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dla t=23oC wyniosła: |
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0 |
6,2 |
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=92,8[m-1]∙ 9,24 0,001[Ω-1]= 0,857472 [m-1 Ω-1] |
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0,907368 |
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2 |
4,28 |
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Otrzymujemy Czo= 0,857472 [/[190*(1+0,019*(23-18))]= 0,00000317 |
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0,00436129776496 |
0,004361298 |
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4 |
3,92 |
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dla t=35oC wyniosła: |
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6 |
3,88 |
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=92,8 [m-1]∙ 1,663 0,001[Ω-1]= 0,1543264 [m-1 Ω-1] |
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0,1633066 |
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8 |
3,9 |
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Otrzymujemy Czo= 0,1543264/[190*(1+0,019*(35-18))]= 0,00000057 |
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0,000649666229065 |
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10 |
3,9 |
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12 |
3,9 |
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Po przegotowaniu (reakcja całkowicie zaszła)przewodnictwo |
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14 |
3,9 |
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dla 0,1M NaOH+0,1M ester w temperaturze t=23oC wyniosła:
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0,42226 |
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16 |
3,89 |
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=92,8 [m-1]∙0,00924[Ω-1]= 0,395328 [m-1 Ω-1]
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18 |
3,88 |
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Po przegotowaniu (reakcja całkowicie zaszła)przewodnictwo |
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20 |
3,86 |
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dla 0,1M NaOH+0,1M ester w temperaturze t=35oC wyniosła:
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=92,8 [m-1]∙0,001663[Ω-1]= 0,39904 [m-1 Ω-1]
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0,418332 |
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0,39904 |
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mieszanina 0,1 M NaOH i 0,1 M estru po gotowaniu |
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T= 35 stopnia Celcjusza |
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S= 4,3 [mS] |
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4,3 |
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mieszanina 0,1 M NaOH i 0,1 M estru po gotowaniu |
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T= 23 stopnia Celcjusza |
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S= 4,26 [mS] |
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4,26 |
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