|
|
|
|
|
|
|
|
|
|
|
|
|
0,983964 |
|
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|
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|
|
|
|
twmp.termostatu: |
23oC |
|
|
|
23 |
208,05 |
|
150,12 |
|
|
0,043478260869565 |
1,005568 |
|
|
|
|
|
|
|
135,180279727839 |
|
|
|
|
|
|
|
|
|
|
pomiary: 0,1 M NaOH + ESTER |
|
|
|
|
35 |
251,37 |
|
176,808 |
|
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|
czas[min.] |
[mS] |
|
|
|
|
|
|
|
|
|
95,18208827 |
|
|
1,42022813519679 |
|
0,010785350752134 |
0,023520006479999 |
|
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|
|
ester-octan etylu 0,1M |
0 |
9,51 |
p= |
0,00091 |
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|
|
0,000566482099148 |
0,006702706588514 |
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|
|
C4H8O2 |
2 |
7,58 |
|
|
|
|
K=82m-1 |
czo= |
0,0047294592646 |
ceso= |
0,004468499842159 |
|
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|
M=88,11 g/mol |
4 |
6,67 |
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6 |
6,11 |
|
|
|
T[oC] |
t[min] |
Ω-1 |
[Ω-1∙m-1]
|
Cx[mol∙dm-3] |
k [dm3∙mol-1∙min-1] |
liczba |
log k |
log |
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8 |
5,57 |
|
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|
23 |
0 |
0,00951 |
0,77982 |
0,000278577138289 |
450,69423854225 |
1,0126866245936 |
2,65388200629529 |
0,005475073923755 |
|
a= |
0,012465351214991 |
|
|
k |
logk |
1/T |
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|
10 |
5,5 |
|
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|
23 |
2 |
0,00758 |
0,62156 |
0,001332800426326 |
78,5007376364876 |
1,09180570503389 |
1,89487373763635 |
0,038145359303394 |
|
|
0,010785350752134 |
0,023520006479999 |
|
95,18208827 |
1,97855522887405 |
0,003378378378378 |
|
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|
12 |
5,33 |
|
|
|
23 |
4 |
0,00667 |
0,54694 |
0,001829869437783 |
68,7116204089892 |
1,16621115947949 |
1,83703019052001 |
0,066777192870632 |
|
|
0,000566482099148 |
0,006702706588514 |
|
135,1802797 |
2,13091334070224 |
0,003246753246753 |
|
|
|
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|
|
14 |
5,18 |
|
|
|
23 |
6 |
0,00611 |
0,50102 |
0,002135758060219 |
64,4020989154618 |
1,24131926328332 |
1,80890002159194 |
0,093883494995892 |
|
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16 |
5,05 |
|
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|
23 |
8 |
0,00557 |
0,45674 |
0,002430722088995 |
68,5596130185965 |
1,35912352538406 |
1,83606835756796 |
0,13325892984121 |
|
|
k= |
110,00830542759 |
|
|
|
-303879,593024187 |
1121,80233497333 |
|
|
|
|
|
|
|
|
18 |
4,96 |
|
|
|
23 |
10 |
0,0055 |
0,451 |
0,0024689581668 |
57,5621927245746 |
1,37992071184446 |
1,76013732921948 |
0,139854133214508 |
|
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0 |
0 |
|
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|
20 |
4,88 |
|
|
|
23 |
12 |
0,00533 |
0,43706 |
0,002561817212896 |
54,1537564286928 |
1,43842599346913 |
1,73362858727103 |
0,15788752249692 |
|
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|
E |
|
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|
23 |
14 |
0,00518 |
0,42476 |
0,002643751665334 |
51,9516562902069 |
1,50214460703872 |
1,71559939801891 |
0,176711742931785 |
|
A= |
-31,1966477172109 |
3,12651779192031 |
|
|
|
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|
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|
|
|
temp.termostatu: |
35oC |
|
|
|
|
23 |
16 |
0,00505 |
0,4141 |
0,002714761524114 |
50,3851777219995 |
1,56988112063123 |
1,70230279477286 |
0,195866766671266 |
|
|
0 |
0 |
|
|
|
-25,388 |
|
486,107641096 |
|
|
|
|
|
|
0,1M NaOH+ESTER |
|
|
|
|
|
23 |
18 |
0,00496 |
0,40672 |
0,002763922195577 |
48,2613672957435 |
1,6257809351367 |
1,68359962177055 |
0,211062026454406 |
|
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|
|
czas[min.] |
[mS] |
|
|
|
23 |
20 |
0,00488 |
0,40016 |
0,002807620570211 |
46,5477333429678 |
1,68339646676108 |
1,66789853772104 |
0,226186411310964 |
|
|
|
6,19385142876652 |
|
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|
|
1/T |
0,043478260869565 |
|
|
|
srednia |
58,903595378372 |
|
1,77014180421549 |
|
|
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|
|
0,028571428571429 |
|
|
|
|
|
|
2,235185 |
|
|
En akt. Estru = 46,9 kJ/mol |
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|
A= 1,4 * 10 ^10 albo do ^20 bo nie mogę się rozczytac ale raczej do 10 cm^3/mol*S |
|
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|
czo |
0,004000350081553 |
ceso |
0,0037837512887 |
|
|
|
|
stała czujnika k = 98,2 1/m |
|
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|
|
T[oC] |
t[min] |
Ω-1 |
[Ω-1∙m-1]
|
Cx[mol∙dm-3] |
k [dm3∙mol-1∙min-1] |
liczba |
log k |
log |
|
|
|
|
|
|
|
|
|
0 |
6,2 |
|
|
|
35 |
0 |
0,0062 |
0,5084 |
0,001873670874621 |
10113,0047243392 |
1,28024774053074 |
4,00488021012345 |
0,10729401803434 |
|
a= |
0,038079520494359 |
|
0,01271380173975 |
|
|
|
|
2 |
4,28 |
|
|
|
35 |
2 |
0,00428 |
0,35096 |
0,002764128319986 |
1765,82452359244 |
5,61540740972477 |
3,24694754396299 |
0,74938127072689 |
moduł liczb N |
a= |
0,01271380173975 |
0,355120062564519 |
|
|
|
|
|
4 |
3,92 |
|
|
|
35 |
4 |
0,00392 |
0,32144 |
0,002931089090991 |
-1,90300444493632 |
-0,996287782359089 |
0,2794398026901 |
-0,001615195473947 |
0,996287782359089 |
|
0,01040574031796 |
0,123122379846533 |
|
1,90300444493632 |
|
|
|
6 |
3,88 |
|
|
|
35 |
6 |
0,00388 |
0,31816 |
0,00294964028777 |
418,222744986824 |
-3,40766249238806 |
2,62140764816997 |
0,532456574078223 |
3,40766249238806 |
|
|
|
|
|
|
|
|
8 |
3,9 |
|
|
|
35 |
8 |
0,0039 |
0,3198 |
0,002940364689381 |
345,135212069551 |
-3,85366927771118 |
2,53798927000542 |
0,585874440722104 |
3,85366927771118 |
|
k= |
404,882846036145 |
|
|
|
|
|
10 |
3,9 |
|
|
|
35 |
10 |
0,0039 |
0,3198 |
0,002940364689381 |
276,108169655641 |
-3,85366927771118 |
2,44107925699737 |
0,585874440722104 |
3,85366927771118 |
|
|
|
|
|
|
|
|
12 |
3,9 |
|
|
|
35 |
12 |
0,0039 |
0,3198 |
0,002940364689381 |
230,090141379701 |
-3,85366927771118 |
2,36189801094974 |
0,585874440722104 |
3,85366927771118 |
|
|
|
|
|
|
|
|
14 |
3,9 |
|
|
|
35 |
14 |
0,0039 |
0,3198 |
0,002940364689381 |
197,220121182601 |
-3,85366927771118 |
2,29495122131913 |
0,585874440722104 |
3,85366927771118 |
|
|
|
|
|
|
|
|
16 |
3,89 |
|
|
|
35 |
16 |
0,00389 |
0,31898 |
0,002945002488575 |
164,550999883175 |
-3,61957615261366 |
2,21630052559986 |
0,558657718224304 |
3,61957615261366 |
|
|
|
|
|
|
|
|
18 |
3,88 |
|
|
|
35 |
18 |
0,00388 |
0,31816 |
0,00294964028777 |
139,407581662275 |
-3,40766249238806 |
2,14428639345031 |
0,532456574078223 |
3,40766249238806 |
|
|
|
|
|
|
|
|
20 |
3,86 |
|
|
|
35 |
20 |
0,00386 |
0,31652 |
0,002958915886159 |
113,744693970866 |
-3,03885625222591 |
2,0559311465782 |
0,482710157025782 |
3,03885625222591 |
|
|
|
|
|
|
|
|
|
|
|
|
1/T |
|
|
|
|
srednia |
364,840118393814 |
|
2,56210258798719 |
|
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|
o,1M NaOH+0,1M ester |
23oC |
3,80[mS] |
P= |
0,3116 |
|
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|
|
Po przegotowaniu |
35oC |
4,05[mS] |
P= |
0,3321 |
|
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|
(reakcja całkowicie zaszła) |
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|
208,05 |
|
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|
|
251,37 |
|
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|
|
|
|
|
0,05M NaOH |
23oC |
10,02[mS] |
Pm= |
208,05 |
P= |
10,4025 |
|
|
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|
|
35oC |
10,24[mS] |
Pm= |
251,37 |
|
12,5685 |
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h |
0,983964 |
|
cz |
0,0047294592646 |
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|
h |
1,005568 |
|
cz |
0,004000350081553 |
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