3.4 Elektronowe Widma Absorpcyjne |
Suma pól trapezów (całki pod krzywymi) |
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całka EA |
całka EB |
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Grzegorz Cygan Ch.P. III r |
1,5671E+14 |
6,3803E+13 |
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Stężenie barwnika w kolbce po rozcieńczeniu |
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cA = |
0,001 |
cB = |
0,0001 |
mol/dm3 |
2. Zależność ekstynkcji barwników od stężenia |
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Stężenie A [mol/dm3] |
EA |
Stężenie A [mol/dm3] |
EB |
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1. Długość fali, absorpcja oraz pola trapezów |
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l [nm] |
n [s-1] |
EA |
EB |
EA+B |
P EA |
P EB |
c0 |
1,056 |
c0 |
0,599 |
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400 |
7,4950E+14 |
0,389 |
0,022 |
0,393 |
7,6047E+12 |
1,0054E+11 |
0,8c0 |
0,841 |
0,8c0 |
0,495 |
1,828049E+13 |
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410 |
7,3122E+14 |
0,443 |
0,021 |
0,433 |
8,3046E+12 |
5,2230E+10 |
0,5c0 |
0,532 |
0,5c0 |
0,27 |
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420 |
7,1381E+14 |
0,511 |
0,017 |
0,484 |
9,0720E+12 |
4,1501E+10 |
0,4c0 |
0,423 |
0,4c0 |
0,196 |
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430 |
6,9721E+14 |
0,582 |
0,020 |
0,545 |
9,8402E+12 |
1,0300E+11 |
0,2c0 |
0,216 |
0,2c0 |
0,075 |
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440 |
6,8136E+14 |
0,660 |
0,025 |
0,610 |
1,0660E+13 |
2,1955E+11 |
0,1c0 |
0,107 |
0,1c0 |
0,004 |
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450 |
6,6622E+14 |
0,748 |
0,036 |
0,689 |
1,1514E+13 |
4,1277E+11 |
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460 |
6,5174E+14 |
0,842 |
0,053 |
0,778 |
1,2390E+13 |
6,8641E+11 |
3. Parametry pasm barwników A i B |
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470 |
6,3787E+14 |
0,945 |
0,078 |
0,880 |
1,3110E+13 |
1,0365E+12 |
Parametr |
Barwnik A |
Barwnik B |
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480 |
6,2458E+14 |
1,028 |
0,110 |
0,974 |
1,3282E+13 |
1,4531E+12 |
Położenie pasma, lmax [nm] |
490 |
580 |
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490 |
6,1184E+14 |
1,056 |
0,150 |
1,034 |
1,2745E+13 |
1,9456E+12 |
lmax [cm-1] |
20408,1632653061 |
17241,3793103448 |
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500 |
5,9960E+14 |
1,027 |
0,200 |
1,060 |
1,1616E+13 |
2,4925E+12 |
nmax [s-1] |
611836734693878 |
516896551724138 |
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510 |
5,8784E+14 |
0,949 |
0,256 |
1,050 |
1,0067E+13 |
3,0523E+12 |
DE [J/cząsteczkę] |
4,05035918367347E-19 |
3,42185517241379E-19 |
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520 |
5,7654E+14 |
0,832 |
0,316 |
1,018 |
8,2565E+12 |
3,6224E+12 |
Absorbancja w maksimum |
1,056 |
0,599 |
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700 |
0,047 |
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530 |
5,6566E+14 |
0,686 |
0,382 |
0,964 |
6,3480E+12 |
4,1744E+12 |
Szerokość połówkowa Dn1/2 |
2,5406779661017E+015 |
2,56239316239316E+015 |
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690 |
0,058 |
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540 |
5,5519E+14 |
0,526 |
0,447 |
0,896 |
4,5475E+12 |
4,6434E+12 |
Stopień asymetrii, a |
1,74028436018958 |
1,53398058252428 |
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680 |
0,074 |
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550 |
5,4509E+14 |
0,375 |
0,505 |
0,831 |
3,0369E+12 |
5,0080E+12 |
Natężenie integralne |
1,5671E+14 |
6,3803E+13 |
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670 |
0,098 |
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710426540284360 |
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560 |
5,3536E+14 |
0,249 |
0,556 |
0,776 |
1,8550E+12 |
5,2080E+12 |
Molowe natężenie integralne |
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660 |
0,132 |
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555185185185185 |
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570 |
5,2596E+14 |
0,146 |
0,585 |
0,726 |
1,0429E+12 |
5,2234E+12 |
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650 |
0,183 |
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582135922330097 |
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0,527 |
580 |
5,1690E+14 |
0,084 |
0,599 |
0,685 |
5,6508E+11 |
5,0507E+12 |
4. Parametry pasm barwników A i B w mieszaninie |
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640 |
0,252 |
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474367088607595 |
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590 |
5,0814E+14 |
0,045 |
0,586 |
0,641 |
3,0065E+11 |
4,6876E+12 |
Parametr |
Barwnik A |
Barwnik B |
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630 |
0,355 |
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600 |
4,9967E+14 |
0,026 |
0,553 |
0,589 |
1,7202E+11 |
4,1489E+12 |
lmax [nm] |
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620 |
0,440 |
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0,2835 |
610 |
4,9148E+14 |
0,016 |
0,492 |
0,522 |
1,1098E+11 |
3,4403E+12 |
Absorbancja w maksimum |
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610 |
0,522 |
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117 |
620 |
4,8355E+14 |
0,012 |
0,408 |
0,440 |
8,8267E+10 |
2,6480E+12 |
Szerokość połówkowa Dn1/2 |
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600 |
0,589 |
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630 |
4,7587E+14 |
0,011 |
0,314 |
0,355 |
5,5766E+10 |
1,8291E+12 |
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590 |
0,522 |
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640 |
4,6844E+14 |
0,004 |
0,210 |
0,252 |
2,8827E+10 |
1,1423E+12 |
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580 |
0,440 |
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650 |
4,6123E+14 |
0,004 |
0,139 |
0,183 |
2,4459E+10 |
6,8835E+11 |
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570 |
0,355 |
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660 |
4,5424E+14 |
0,003 |
0,090 |
0,132 |
2,0339E+10 |
3,8983E+11 |
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560 |
0,252 |
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670 |
4,4746E+14 |
0,003 |
0,057 |
0,098 |
1,9741E+10 |
1,9741E+11 |
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550 |
0,183 |
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680 |
4,4088E+14 |
0,003 |
0,035 |
0,074 |
1,9169E+10 |
8,3065E+10 |
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540 |
0,132 |
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690 |
4,3449E+14 |
0,003 |
0,023 |
0,058 |
1,5518E+10 |
2,1725E+10 |
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530 |
0,098 |
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700 |
4,2829E+14 |
0,002 |
0,016 |
0,047 |
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520 |
0,074 |
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510 |
0,058 |
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500 |
0,047 |
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400 |
0,393 |
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410 |
0,433 |
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420 |
0,484 |
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430 |
0,545 |
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440 |
0,610 |
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450 |
0,689 |
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460 |
0,778 |
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470 |
0,880 |
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480 |
0,974 |
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490 |
1,034 |
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500 |
1,060 |
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600 |
510 |
1,034 |
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590 |
520 |
0,974 |
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580 |
530 |
0,880 |
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570 |
540 |
0,778 |
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560 |
550 |
0,689 |
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550 |
560 |
0,610 |
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540 |
570 |
0,545 |
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530 |
580 |
0,484 |
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520 |
590 |
0,433 |
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510 |
600 |
0,393 |
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