zad 9 23 str 2

INFRARED SPECTRUM

CHAPTER NINĘ 357

Compound 9.23

1685.6    1359.5    959.0

1597.5    1266.3    839.2

1506.4    1157.0    565.7

Wavelength, (^m)

WAVENUMBERS (cm^-1)

NICOLET 20SX FT4R

MASS SPECTRAL DATA (Relative Intensities)

100-1

U!traviolet Data

90-

80-

70-

60-

50-

40-

M (138) = 20.0 (100% ofM)

M + 1 (139) =    2.04

M + 2(140)=    0.114(0.57%)

Compound 9.23 gives a positive halogen test.

Pasma izotopowe M/z %M

\ isooctanc ^Amax	\ isooctanc ^Amax
(nm)	^max (nm)	^max
240	16,900 278	258
268	762 292 (s)	86
275	466 312	71

(s) = shoulder

30-

20-

10-

138    (M)    100

139    (M+l)    10,2

140    (M+2)    0,57

⁰ )ii]Miuf|iiłi|iiii|łiir|i!ii|im|M

30    40    50    60

łW

70

TnTpTnri n 111 m 11 m j m i ii i n | n ii i m i j 11

80    90    100    110    120

|!1II|I!I!|I1

130

m/z

t|TTITpi 11 [ 11 fi] IIT11111111111111II1111111II111II111111111111 140    150    160    170    180    190    200

¹H NMR SPECTRUM (Solvent CCU, 60 MHz)