87318

E= -

zF

A

II, = /i,⁸ + RTIn

'a.

*	f	r o		f	( „
I	v,n* +viErin		-1	vtfif +vtRT ln	H
proddly		l^u< J,	SUbsfrdfy		^flł *

1	E w*	- E
zF
	prutiiAly	pimhi.lv
	E ™^e-	E^1'^

praluljy

sub&raly

O

I subaraiy

UltMUMy

o.

zF

[Modrhy

‘i    iiintKty

a.

E = E® - — zF

\^vi

X,

£l

E ">

ptoduhy

£ln

ujfnirary

« RT

£=£”- — zF

<		V,		¥, \
^in n fto&ity	(?)	->„n stituraiy	^a, kJ	i

^(,) Cd, Hg|CdCl₂|AgCl|Ag^(,)

Cd, Hg - 2e *=* Cd²*

2 AgCl + 2e «=* 2 Ag° + 2 CY

Cd, Hg + 2 AgCl *=* Cd²* + 2 Ag⁰ + 2 Cl'

~ RT , o~ Ag⁰ aCd²* a²Cl~

E =E--ln-r²-

2F a‘ AgCl aCd, Hg

ni,

m

cr

2 F

"•aa, = ^mcd^ł* -J^cr

(1)

rK

E = E⁰-—ln ^

z£

fk

su6wrorv

2