/ '■ . ................. I
1. Standardowe funkcje termodynamiczne pierwiastków i związków chemicznych. Pierwiastki i zw iązki nieorganiczne [ 1,2,18)
(1) |
Ml (■mol1 |
faza |
T= 298 K |
C./J-K |
'mol 1 |
lit | ||||
JH,°/ kJ mol 1 |
ÓG,°t kJ mol 1 |
S°/ JK*. mol1 |
a |
Cp = a + hT+ cl* fr-IO* c 10* |
77K | |||||
ak |
107.87 |
% |
0 |
0 |
42.55 |
25.36 |
298 |
2 | ||
AfiBr |
187.77 |
s |
-100.67 |
-97.23 |
107.11 |
52 3 |
298 |
2 | ||
A«a |
143.32 |
x |
• 127.0 |
• 108.8 |
96.25 |
50.79 |
298 |
1.2 | ||
Agi |
234.77 |
s |
-61.94 |
-66.36 |
115.48 |
56.99 |
298 |
2 | ||
AjjNO, |
169.87 |
s |
-124,52 |
•33.60 |
140.92 |
93.05 |
298 |
2 | ||
AgjCOjt |
275.75 |
s |
-506.11 |
-437.23 |
167.36 |
112.47 |
298 |
2 | ||
Ag.-« |
231.74 |
s |
•31.13 |
-11.254 |
121.34 |
65.86 |
298 |
2 | ||
AgjS |
247.80 |
s |
•32.79 |
-40.835 |
144.01 |
76.53 |
298 |
2 | ||
Ąfcso, |
311.80 |
s |
-717.22 |
-619.65 |
199.83 |
131.38 |
298 |
2 | ||
Ag,PO* |
418.58 |
t |
-990.35 |
•894.75 |
258.16 |
2 | ||||
Al |
26.98 |
s |
0 |
0 |
28.30 |
21.30 |
8.52 |
298 - 933 |
1 | |
AIBr, |
266.69 |
X |
-511.28 |
180.03 |
100.47 |
•137.69 |
463.43 |
298 - 371 |
1 | |
AICI, |
133.34 |
s |
-705.63 |
109.3 |
64.92 |
87.91 |
298-466 |
1 | ||
All, |
407.69 |
8 |
-302.92 |
195.95 |
44.50 |
238.48 |
189.58 |
298 - 464 |
1 | |
AIN |
40.99 |
s |
-317.98 |
20.14 |
7.76 |
90.00 |
-50.57 |
298 - 900 |
1 | |
AIjOj |
101.96 |
s(a) |
-1675.7 |
50.92 |
55.61 |
83.73 |
•20.59 |
298 - 2327 |
1 | |
ANS, |
150.16 |
8 |
-651.03 |
116.84 |
84.72 |
75.88 |
■25.‘»3 |
- 1500 |
1 | |
As |
74.92 |
s(sz) |
0 |
0 |
35.61 |
24.69 |
298 |
2 | ||
AsCI, |
181.29 |
c |
•315.47 |
-268.43 |
212.55 |
133.47 |
298 |
2 | ||
_£_ |
-269.47 |
-258.05 |
326.23 |
75.48 |
298 |
2 | ||||
AsH, |
77.94 |
_£_ |
73.91 |
66.40 |
222.97 |
38.58 |
298 |
2 | ||
As, |
149.84 |
_£_ |
222.2 |
171.9 |
239.4 |
35.0 |
298 |
IS | ||
As-O, |
229.84 |
s |
-924.9 |
-782.3 |
105.4 |
116.5 |
298 |
IS | ||
As.S, |
246.02 |
s |
•169.0 |
-168.6 |
163.6 |
116.3 |
298 |
IS | ||
Au |
196.97 |
s |
0 |
0 |
47.41 |
25.40 |
298 |
2 | ||
AuCI |
232.42 |
8 |
• 36.40 |
1.255 |
85.922 |
37.36 |
298 |
2 | ||
AuCI, |
303.34 |
8 |
-118.47 |
-5336 |
164.36 |
2 | ||||
B |
10.81 |
X |
0 |
5.90 |
2.60 |
31.73 |
•9.53 |
298- 1800 |
1 | |
BCI, |
117.18 |
c |
-427.2 |
-387.4 |
206.3 |
106.7 |
298 |
IS | ||
_£_ |
-403.8 |
-388.7 |
290.1 |
62.7 |
298 |
IS | ||||
BH, |
13.84 |
8 |
106.69 |
187.88 |
25.30 |
38.53 |
-6.01 |
298 - 1300 |
1 | |
BN |
24.82 |
8 |
-250.91 |
-226.75 |
14.77 |
19.71 |
298 |
1.2 | ||
B^llft |
27.67 |
Jb_ |
41.00 |
233.17 |
3.11 |
205.75 |
-71.56 |
181 - 1200 |
1 | |
B-O, |
69.62 |
8 |
-1271.9 |
-1193.8 |
53.97 |
62.76 |
298 |
1.2 | ||
B,N,H. |
80.50 |
-510.03 |
288.70 |
4.08 |
351.51 |
135.61 |
298- 1200 |
1 | ||
B*C |
55.26 |
_ 8 |
-62.68 |
26.77 |
27.9 |
298 - 2743 |
1 | |||
Ba |
137.33 |
8 |
0 |
62.48 |
36.99 |
-92.34 |
209.74 |
298 - 583 |
1 | |
BaBr. |
297.14 |
s |
-757.72 |
148.53 |
70.57 |
21.62 |
298-1130 |
1 | ||
BaCU |
208.23 |
8 |
-858,56 |
123.70 |
74.81 |
-5.21 |
21.75 |
298- 1198 |
1 | |
BaO |
153.33 |
8 |
-548.10 |
72.05 |
42.52 |
16.61 |
298 - 2286 |
1 | ||
Be |
9.012 |
X |
0 |
9.44 |
9.76 |
24.06 |
-6.26 |
298-1527 |
1 | |
BcCO, |
69.02 |
X |
-1025.0 |
52.0 |
65.0 |
298 |
IS | |||
BeCI> |
79.919 |
S(p> |
-496.22 |
449.51 |
75.81 |
37.68 |
101.78 |
-63.01 |
298-688 |
1.2 |
Bell.- |
11.028 |
_E_ |
12532 |
173.12 |
17.27 |
48.60 |
-15.34 |
298- 1200 |
1 | |
BeO |
25.012 |
8 |
-608.35 |
13.77 |
-4.70 |
123.61 |
-74.27 |
298 - 800 |
1 | |
Bi |
208.98 |
X |
0 |
0 |
56.90 |
26.02 |
298 |
2 | ||
Bi-O, |
465.96 |
8 |
-577.81 |
497.34 |
151.46 |
113.80 |
298 |
2 | ||
BrCI |
115.36 |
JŁ_ |
14.6 |
-1.0 |
240.1 |
35.0 |
298 |
IS | ||
BrF |
99.91 |
8 |
-93.8 |
-109.2 |
229.0 |
33.0 |
298 |
IS | ||
Br; |
159.81 |
c |
0 |
0 |
152.21 |
75.69 |
298 |
2 | ||
_ |
30.91 |
3.133 |
245.37 |
36.05 |
298 |
2 |