117828195

117828195



Journal of Chromatugraphic Sci«?nce, Vol. 47, August 2009


Table II. Seven Volalile Compounds Most Frequent)y Appearing in the Salvia Species With Their Respective StructuraJ Formulas and Mass Spectra


Yolatile Compound    StructuraJ Formulas and Mass Spectra


100


93


a-Pinene


50


27



fam nti


105 '21

*1c

Itr innn


9|««t r


136

i


triloba contains no /3-pinene, and camphene, and S. officmalis is deprived of /^-chamigrene, thujol, and cadina-3,9-diene.

There are still other yolatile components, which remain unidentified in our experiment, yet they frequentJy appear in many investigated sagę species. For the sake of an example, compo-nent with the retention time equal to 26.01 min is present in fourteen Sałoia species, and its rela-tively highest levels are observed with S. azurea, S. pratensis, S. staminea, S. cadmica, and S. sclarea.


Camphene


20 30 40

77

53    67 ll

50 60 70 00

90 100 110 120 130


p-Pinene


27


77


jJii


107

nfrt-T-i


•21    136


p Chamigrene


10 20 30 40 50 40 70 00 90 100 110 120 IX


Conclusions

In our HS-CC-MS study, we obtained finger-print gas chromatograms of the yolatile fraction from 20 Safoia species most frequently grown in Poland. Seven yolatile compounds were identi-fied as characteristic of the prevailing mąjority of the investigated species. With four species, unique yolatile compounds were found, enabling them to act as their respective chemotaxonomic markers. With 13 species, certain yolatile compounds were identified, which (although not unique for these species) can be considered as their respective chemotaxonomic advice. With five species, an absence of the otherwise fre-quently occurring yolatile compounds was observed, which can be considered as a respec-tive chemotaxonomic advice, as well.


100


95


References


Camphor


55    69


108


152


77


ll.....lift


ThujoJ


|l Mai!\{ i| mI|I • H.|lll Ii «|Nlłl

2C 30 40 50 60

h.

70

l*»* | in^ii minji ii

80 90 100 MO 120 IX 140 150


Cadina 3,9-dicne


_

'T' T'-'

20    40    60    80    100    120    140    160    180 200


1.    M. Roberts. Margaret Roberts' Book ot Herbs: The Medicinal and Culinary Uses of Herbs in South Africa. Southern Book Publishers, National Book Printers, Goodwood, Cape, 1986.

2.    R.D. Cantino, R.M. Hariey, and S.J. Wagslaff. Genera of Labiatae: status and classification. In: Advances In Labiatae Science. Fds, R.M Hariey and I. Reynolds. Royal Botanical Gardens, Kew, UK, 1992, pp, 511-522.

3.    L.t.W. Codd. I.amiaceae. In: Flora of Southern Africa 28,4. Botanical Research Institute, Pretoria, 1985.

4.1.C Hedge. A global survey of the biogeog raphy of the Labiatae. In: Advances in Labiatae Science, tds, R.M Hariey and T. Reynolds. Royal Botanical Gardens, Kew, UK, 1992, pp. 7-17.

5.    B.M. Lawrence. Chemical components of Labiatae oils and their exploitation. In. Advances in Labiatae Science. Fds, R.M Hariey and I. Reynolds. Royal Botanical Gardens, Kew, UK, 1992, pp. 399-436.

6.    S.J. Wagstaff. A phylogenetic interpretation of




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