5314027782
POSTER SESSION. H41
SIMULTANEOUS ROVIBRATIONAL ANALYSIS OF THE //2, tv3, i/5ł AND z/6 BANDS OF H3I3CF
D. PAPOUSEK. Zlićinskd 18, 169 00 Prague 6, Czech Republic;
M. WINNEWISSER, S. KLEE, Phystkalisch-Chemisches Institut, Justus-Liebig Universitdt Giessen, Heinrich-Buff Ring 58, D-35892 Giessen, Germany; J. DEMAISON, Laboratoirc de Spectroscopie Hertzienne, U RA CNRS 2Ą9 Bat. P5, Unwersite de 1Alle /. 59655 VU-leneuue D'Ascq Cedei, France; P. PRACNA, J. Heyrousky Institute of Physical Chemistry, Czech Academy of Sciences, Dolejśkow 3. 182 23 Prague 8, Czech Republic.
A total of 6071 transition wavenumbers of the ^5* and vg fundanicntal bands of
H3l3CF and 1689 frequencics of the rotational transitions in the and vibrational States have been fitted sinmltaneously by taking into account various Coriolis interactions, 1-type interactions. and a-resonance terms betwcen and within the vibrational States. The standard deviation of the fit using 75 parameters was 7.63 x 10-4 cm”1 for the infrared data and 0.150 MHz for the rotational data. The possibility of obtaining a quantitative fit of the very precise data of high-resolution Fourier transform and subinillimeter-wave spec-troscopy for a semirigid symmetric top molecule is discussed.
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