Materials & Streams Report
for PDO flowsheet for case assignments
November 23, 2014
- Page 1 -
1. OVERALL PROCESS DATA
Annual Operating Time
7,920.00h
Unit Production Ref. Rate
90,409,667.41kg MP/yr
Operating Days per Year
330.00
MP = Total Flow of Stream 'Product'
- Page 2 -
2.1 STARTING MATERIAL REQUIREMENTS (per Section)
Section
Starting Material Active Product
Amount
Needed
(MT
Sin/kg
MP)
Molar
Yield
(%)
Mass
Yield
(%)
Gross
Mass
Yield
(%)
Fermentation Section
Glucose
1,3 PDO
0.00 Unknown Unknown Unknown
Clarification Section
1,3 PDO
1,3 PDO
0.00 Unknown Unknown Unknown
Purification Section
1,3 PDO
1,3 PDO
0.00
97.02
97.02
97.02
Sin = Section Starting Material, Aout = Section Active Product
2.2 BULK MATERIALS (Entire Process)
Material
MT/yr
MT/h
MT/kg MP
Air
246,059
31.068
0.003
Cane Juice
1,441,440
182.000
0.016
H2SO4 ( 4% w/w)
21,275
2.686
0.000
Inorganics
577
0.073
0.000
NaOH (4% w/w)
10,976
1.386
0.000
NH3 Sltn (28%)
3,870
0.489
0.000
Organics
2,595
0.328
0.000
Water
76,810
9.698
0.001
TOTAL
1,803,601
227.727
0.020
- Page 3 -
2.3 BULK MATERIALS (per Section)
SECTIONS IN: Main Branch
Fermentation Section
Material
MT/yr
MT/h
MT/kg MP
Air
246,059
31.068
0.003
Cane Juice
1,441,440
182.000
0.016
Inorganics
577
0.073
0.000
NH3 Sltn (28%)
3,870
0.489
0.000
Organics
2,595
0.328
0.000
Water
42,567
5.375
0.000
TOTAL
1,737,107
219.332
0.019
Clarification Section
Material
MT/yr
MT/h
MT/kg MP
Water
29,281
3.697
0.000
TOTAL
29,281
3.697
0.000
Purification Section
Material
MT/yr
MT/h
MT/kg MP
H2SO4 ( 4% w/w)
21,275
2.686
0.000
NaOH (4% w/w)
10,976
1.386
0.000
Water
4,963
0.627
0.000
TOTAL
37,213
4.699
0.000
Bulk Materials Per Section (%)
Process Sections
Fermentation Section
Clarification Section
Purification Section
0.00
10.00
20.00
30.00
40.00
50.00
60.00
70.00
80.00
90.00
100.00
- Page 4 -
2.4 BULK MATERIALS (per Material)
Air
Air
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-4
100.00
246,059
31.068
0.003
TOTAL
100.00
246,059
31.068
0.003
Cane Juice
Cane Juice
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-1
100.00
1,441,440
182.000
0.016
TOTAL
100.00
1,441,440
182.000
0.016
H2SO4 ( 4% w/w)
H2SO4 ( 4% w/w)
% Total
MT/yr
MT/h
MT/kg MP
Purification Section (Main Branch)
P-11
100.00
21,275
2.686
0.000
TOTAL
100.00
21,275
2.686
0.000
Inorganics
Inorganics
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-3
100.00
577
0.073
0.000
TOTAL
100.00
577
0.073
0.000
NaOH (4% w/w)
NaOH (4% w/w)
% Total
MT/yr
MT/h
MT/kg MP
Purification Section (Main Branch)
P-11
100.00
10,976
1.386
0.000
TOTAL
100.00
10,976
1.386
0.000
NH3 Sltn (28%)
NH3 Sltn (28%)
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-3
100.00
3,870
0.489
0.000
TOTAL
100.00
3,870
0.489
0.000
Organics
Organics
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-3
100.00
2,595
0.328
0.000
TOTAL
100.00
2,595
0.328
0.000
- Page 5 -
Water
Water
% Total
MT/yr
MT/h
MT/kg MP
Fermentation Section (Main Branch)
P-8
6.08
4,672
0.590
0.000
P-1
49.34
37,895
4.785
0.000
Clarification Section (Main Branch)
P-6
16.56
12,721
1.606
0.000
P-10
21.56
16,560
2.091
0.000
Purification Section (Main Branch)
P-11
6.46
4,963
0.627
0.000
TOTAL
100.00
76,810
9.698
0.001
2.5 BULK MATERIALS: SECTION TOTALS (MT/kg MP)
Raw Material
Fermentation
Section
Clarification
Section
Purification
Section
Air
0.003
0.000
0.000
Cane Juice
0.016
0.000
0.000
H2SO4 ( 4% w/w)
0.000
0.000
0.000
Inorganics
0.000
0.000
0.000
NaOH (4% w/w)
0.000
0.000
0.000
NH3 Sltn (28%)
0.000
0.000
0.000
Organics
0.000
0.000
0.000
Water
0.000
0.000
0.000
TOTAL
0.019
0.000
0.000
- Page 6 -
Bulk Materials (Entire Process)
Raw Materials
Air
Cane Juice
H2SO4 ( 4/w)
Inorganics
NaOH (4/w)
NH3 Sltn (28)
Organics
Water
0.00
0.00
0.00
0.00
0.00
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.02
Material Consumption (MT/kg MP)
2.6 BULK MATERIALS: SECTION TOTALS (MT/h)
Raw Material
Fermentation
Section
Clarification
Section
Purification
Section
Air
31.068
0.000
0.000
Cane Juice
182.000
0.000
0.000
H2SO4 ( 4% w/w)
0.000
0.000
2.686
Inorganics
0.073
0.000
0.000
NaOH (4% w/w)
0.000
0.000
1.386
NH3 Sltn (28%)
0.489
0.000
0.000
Organics
0.328
0.000
0.000
Water
5.375
3.697
0.627
TOTAL
219.332
3.697
4.699
- Page 7 -
Bulk Materials (Entire Process)
Raw Materials
Air
Cane Juice
H2SO4 ( 4/w)
Inorganics
NaOH (4/w)
NH3 Sltn (28)
Organics
Water
0.00
20.00
40.00
60.00
80.00
100.00
120.00
140.00
160.00
180.00
Material Consumption (MT/h)
2.7 BULK MATERIALS: SECTION TOTALS (MT/yr)
Raw Material
Fermentation
Section
Clarification
Section
Purification
Section
Air
246,059
0
0
Cane Juice
1,441,440
0
0
H2SO4 ( 4% w/w)
0
0
21,275
Inorganics
577
0
0
NaOH (4% w/w)
0
0
10,976
NH3 Sltn (28%)
3,870
0
0
Organics
2,595
0
0
Water
42,567
29,281
4,963
TOTAL
1,737,107
29,281
37,213
- Page 8 -
Bulk Materials (Entire Process)
Raw Materials
Air
Cane Juice
H2SO4 ( 4/w)
Inorganics
NaOH (4/w)
NH3 Sltn (28)
Organics
Water
0.00
100000.00
200000.00
300000.00
400000.00
500000.00
600000.00
700000.00
800000.00
900000.00
1000000.00
1100000.00
1200000.00
1300000.00
1400000.00
1500000.00
Material Consumption (MT/yr)
- Page 9 -
3. STREAM DETAILS
Stream Name
Cane Juice
S-101
Waste-101
S-107
Source
INPUT
P-1
P-1
P-16
Destination
P-1
P-16
OUTPUT
OUTPUT
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
25.00
25.22
25.20
100.00
Pressure (bar)
1.01
1.01
1.01
1.01
Density (g/L)
1,021.16
1,018.69
1,066.20
0.59
Total Enthalpy (kW-h)
4,821.34
4,638.85
224.82
95,727.14
Specific Enthalpy (kcal/kg)
22.79
23.14
20.36
683.17
Heat Capacity (kcal/kg-°C)
0.91
0.92
0.81
0.45
Component Flowrates (MT/h)
Ash
0.546
0.087
0.459
0.000
Cellulose
1.820
0.291
1.529
0.000
Glucose
27.300
26.158
1.142
0.000
Water
152.334
145.962
6.372
120.565
TOTAL (MT/h)
182.000
172.498
9.502
120.565
TOTAL (m3/h)
178.229
169.333
8.912
204,919.467
- Page 10 -
Stream Name
S-106
S-102
Air-In
S-103
Source
P-16
P-2
INPUT
P-4
Destination
P-2
P-3
P-4
P-3
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
100.00
35.00
25.00
40.00
Pressure (bar)
1.01
1.01
1.01
4.01
Density (g/L)
1,040.05
1,074.20
1.18
4.45
Total Enthalpy (kW-h)
4,406.69
1,542.34
218.44
349.58
Specific Enthalpy (kcal/kg)
73.01
25.55
6.05
9.68
Heat Capacity (kcal/kg-°C)
0.73
0.73
0.24
0.24
Component Flowrates (MT/h)
Ash
0.087
0.087
0.000
0.000
Cellulose
0.291
0.291
0.000
0.000
Glucose
26.158
26.158
0.000
0.000
Nitrogen
0.000
0.000
23.829
23.829
Oxygen
0.000
0.000
7.239
7.239
Water
25.397
25.397
0.000
0.000
TOTAL (MT/h)
51.933
51.933
31.068
31.068
TOTAL (m3/h)
49.933
48.346
26,345.761
6,986.324
- Page 11 -
Stream Name
Organics &
Inorganics
Aq NH3 (28%)
Vent-1
S-104
Source
INPUT
INPUT
P-3
P-3
Destination
P-3
P-3
OUTPUT
P-5
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
25.00
25.00
35.00
35.00
Pressure (bar)
1.01
1.01
1.00
1.00
Density (g/L)
1,152.90
900.00
1.27
1,005.08
Total Enthalpy (kW-h)
4.69
14.67
1,310.54
1,539.34
Specific Enthalpy (kcal/kg)
10.08
25.83
27.88
30.48
Heat Capacity (kcal/kg-°C)
0.40
1.03
0.23
0.87
Component Flowrates (MT/h)
1,3 PDO
0.000
0.000
0.000
12.563
1-2-4 butanetri
0.059
0.000
0.000
0.059
Acetic-Acid
0.126
0.000
0.000
0.126
Ammonia
0.000
0.137
0.000
0.001
Ash
0.000
0.000
0.000
0.087
Biomass
0.000
0.000
0.000
0.813
Calcium Chlorid
0.001
0.000
0.000
0.001
Carb. Dioxide
0.000
0.000
14.768
0.000
Cell Debris
0.000
0.000
0.000
0.167
Cellulose
0.000
0.000
0.000
0.291
Citric Acid
0.015
0.000
0.000
0.015
Glucose
0.000
0.000
0.000
0.026
Glycerol
0.084
0.000
0.000
0.084
KH2PO4
0.020
0.000
0.000
0.020
MgSO4
0.009
0.000
0.000
0.009
NaCl
0.000
0.000
0.000
0.000
Nitrogen
0.000
0.000
23.829
0.000
Oxygen
0.000
0.000
1.848
0.000
Phosphoric Acid
0.019
0.000
0.000
0.019
Pyruvic Acid
0.059
0.000
0.000
0.059
Sulfuric Acid
0.008
0.000
0.000
0.008
Water
0.000
0.352
0.000
29.110
TOTAL (MT/h)
0.401
0.489
40.445
43.458
TOTAL (m3/h)
0.347
0.543
31,870.768
43.239
- Page 12 -
Stream Name
S-105
S-201
S-202
S-204
Source
P-5
P-6
P-6
P-8
Destination
P-6
P-9
P-7
P-9
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
35.00
35.29
35.30
69.33
Pressure (bar)
1.00
1.00
1.00
0.46
Density (g/L)
1,005.08
1,004.13
1,011.94
980.73
Total Enthalpy (kW-h)
1,539.34
1,386.75
165.51
1,090.87
Specific Enthalpy (kcal/kg)
30.48
30.66
31.37
67.24
Heat Capacity (kcal/kg-°C)
0.87
0.87
0.89
0.97
Component Flowrates (MT/h)
1,3 PDO
12.563
11.449
1.113
0.891
1-2-4 butanetri
0.059
0.053
0.005
0.004
Acetic-Acid
0.126
0.115
0.011
0.009
Ammonia
0.001
0.001
0.000
0.000
Ash
0.087
0.078
0.009
0.007
Biomass
0.813
0.065
0.749
0.024
Calcium Chlorid
0.001
0.001
0.000
0.000
Cell Debris
0.167
0.152
0.015
0.012
Cellulose
0.291
0.254
0.037
0.027
Citric Acid
0.015
0.014
0.001
0.001
Glucose
0.026
0.024
0.002
0.002
Glycerol
0.084
0.077
0.007
0.006
KH2PO4
0.020
0.019
0.002
0.001
MgSO4
0.009
0.008
0.001
0.001
NaCl
0.000
0.000
0.000
0.000
Phosphoric Acid
0.019
0.018
0.002
0.001
Pyruvic Acid
0.059
0.053
0.005
0.004
Sulfuric Acid
0.008
0.007
0.001
0.001
Water
29.110
26.530
2.580
12.968
TOTAL (MT/h)
43.458
38.918
4.540
13.960
TOTAL (m3/h)
43.239
38.758
4.487
14.234
- Page 13 -
Stream Name
S-205
S-206
Waste-202
NaOH (4%)
Source
P-9
P-10
P-10
INPUT
Destination
P-10
P-11
OUTPUT
P-11
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
45.00
45.37
45.40
25.00
Pressure (bar)
0.46
0.46
0.46
1.01
Density (g/L)
997.00
996.72
999.03
1,100.00
Total Enthalpy (kW-h)
2,477.62
2,370.99
125.33
38.27
Specific Enthalpy (kcal/kg)
40.32
40.62
40.70
23.76
Heat Capacity (kcal/kg-°C)
0.90
0.90
0.90
0.95
Component Flowrates (MT/h)
1,3 PDO
12.341
11.744
0.596
0.000
1-2-4 butanetri
0.058
0.055
0.003
0.000
Acetic-Acid
0.124
0.118
0.006
0.000
Ammonia
0.001
0.001
0.000
0.000
Ash
0.085
0.080
0.005
0.000
Biomass
0.089
0.000
0.089
0.000
Calcium Chlorid
0.001
0.001
0.000
0.000
Cell Debris
0.164
0.156
0.008
0.000
Cellulose
0.281
0.258
0.023
0.000
Citric Acid
0.015
0.014
0.001
0.000
Glucose
0.026
0.024
0.001
0.000
Glycerol
0.083
0.079
0.004
0.000
KH2PO4
0.020
0.019
0.001
0.000
MgSO4
0.009
0.008
0.000
0.000
NaCl
0.000
0.000
0.000
0.000
Phosphoric Acid
0.019
0.018
0.001
0.000
Pyruvic Acid
0.058
0.055
0.003
0.000
Sodium Hydroxid
0.000
0.000
0.000
0.139
Sulfuric Acid
0.008
0.007
0.000
0.000
Water
39.499
37.590
1.909
1.247
TOTAL (MT/h)
52.878
50.228
2.650
1.386
TOTAL (m3/h)
53.037
50.394
2.652
1.260
- Page 14 -
Stream Name
H2SO4 (4%)
Water
S-301
Waste-301
Source
INPUT
INPUT
P-11
P-11
Destination
P-11
P-11
P-12
OUTPUT
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
25.00
25.00
45.37
25.00
Pressure (bar)
1.01
1.01
0.46
0.46
Density (g/L)
1,066.10
994.70
996.58
1,037.91
Total Enthalpy (kW-h)
72.76
18.17
2,370.84
129.35
Specific Enthalpy (kcal/kg)
23.31
24.96
40.63
23.60
Heat Capacity (kcal/kg-°C)
0.93
1.00
0.90
0.94
Component Flowrates (MT/h)
1,3 PDO
0.000
0.000
11.744
0.000
1-2-4 butanetri
0.000
0.000
0.055
0.000
Acetic-Acid
0.000
0.000
0.118
0.000
Ammonia
0.000
0.000
0.000
0.001
Ash
0.000
0.000
0.064
0.016
Calcium Chlorid
0.000
0.000
0.001
0.000
Cell Debris
0.000
0.000
0.156
0.000
Cellulose
0.000
0.000
0.258
0.000
Citric Acid
0.000
0.000
0.014
0.000
Glucose
0.000
0.000
0.024
0.000
Glycerol
0.000
0.000
0.079
0.000
KH2PO4
0.000
0.000
0.019
0.000
MgSO4
0.000
0.000
0.008
0.000
NaCl
0.000
0.000
0.000
0.000
Phosphoric Acid
0.000
0.000
0.018
0.000
Pyruvic Acid
0.000
0.000
0.055
0.000
Sodium Hydroxid
0.000
0.000
0.000
0.139
Sulfuric Acid
0.269
0.000
0.007
0.269
Water
2.418
0.627
37.590
4.291
TOTAL (MT/h)
2.686
0.627
50.211
4.716
TOTAL (m3/h)
2.520
0.630
50.384
4.544
- Page 15 -
Stream Name
Water Vapor
S-302
S-304
S-303
Source
P-12
P-12
P-12
P-13
Destination
OUTPUT
P-13
P-14
P-7
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
60.00
79.13
60.00
79.13
Pressure (bar)
0.20
0.46
0.20
0.46
Density (g/L)
0.13
974.97
1,006.09
974.97
Total Enthalpy (kW-h)
6,149.10
2,338.94
808.33
1,250.42
Specific Enthalpy (kcal/kg)
665.08
78.99
41.45
78.99
Heat Capacity (kcal/kg-°C)
0.45
1.00
0.69
1.00
Component Flowrates (MT/h)
1,3 PDO
0.000
0.000
11.744
0.000
1-2-4 butanetri
0.000
0.000
0.055
0.000
Acetic-Acid
0.000
0.000
0.118
0.000
Ammonia
0.000
0.000
0.000
0.000
Ash
0.000
0.000
0.064
0.000
Calcium Chlorid
0.000
0.000
0.001
0.000
Cell Debris
0.000
0.000
0.156
0.000
Cellulose
0.000
0.000
0.258
0.000
Citric Acid
0.000
0.000
0.014
0.000
Glucose
0.000
0.000
0.024
0.000
Glycerol
0.000
0.000
0.079
0.000
KH2PO4
0.000
0.000
0.019
0.000
MgSO4
0.000
0.000
0.008
0.000
NaCl
0.000
0.000
0.000
0.000
Phosphoric Acid
0.000
0.000
0.018
0.000
Pyruvic Acid
0.000
0.000
0.055
0.000
Sulfuric Acid
0.000
0.000
0.007
0.000
Water
7.955
25.478
4.156
13.621
TOTAL (MT/h)
7.955
25.478
16.778
13.621
TOTAL (m3/h)
61,435.742
26.132
16.676
13.971
- Page 16 -
Stream Name
Condensate
S-203
Waste-201
S-305
Source
P-13
P-7
P-8
P-14
Destination
OUTPUT
P-8
OUTPUT
P-15
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
0.00
Temperature (°C)
79.13
69.10
69.30
145.28
Pressure (bar)
0.46
0.46
0.46
1.01
Density (g/L)
974.97
983.42
992.09
943.89
Total Enthalpy (kW-h)
1,088.52
1,415.93
329.86
1,861.67
Specific Enthalpy (kcal/kg)
78.99
67.08
67.55
102.38
Heat Capacity (kcal/kg-°C)
1.00
0.97
0.97
0.70
Component Flowrates (MT/h)
1,3 PDO
0.000
1.113
0.222
11.509
1-2-4 butanetri
0.000
0.005
0.001
0.000
Acetic-Acid
0.000
0.011
0.002
0.000
Ammonia
0.000
0.000
0.000
0.000
Ash
0.000
0.009
0.002
0.000
Biomass
0.000
0.749
0.724
0.000
Calcium Chlorid
0.000
0.000
0.000
0.000
Cell Debris
0.000
0.015
0.003
0.000
Cellulose
0.000
0.037
0.010
0.000
Citric Acid
0.000
0.001
0.000
0.000
Glucose
0.000
0.002
0.000
0.000
Glycerol
0.000
0.007
0.001
0.000
KH2PO4
0.000
0.002
0.000
0.000
MgSO4
0.000
0.001
0.000
0.000
NaCl
0.000
0.000
0.000
0.000
Phosphoric Acid
0.000
0.002
0.000
0.000
Pyruvic Acid
0.000
0.005
0.001
0.000
Sulfuric Acid
0.000
0.001
0.000
0.000
Water
11.857
16.201
3.232
4.136
TOTAL (MT/h)
11.857
18.161
4.201
15.645
TOTAL (m3/h)
12.162
18.468
4.235
16.575
- Page 17 -
Stream Name
Waste-302
Waste-303
Product
Source
P-14
P-15
P-15
Destination
OUTPUT
OUTPUT
OUTPUT
Stream Properties
Activity (U/ml)
0.00
0.00
0.00
Temperature (°C)
200.53
100.75
213.13
Pressure (bar)
1.01
1.01
1.01
Density (g/L)
1,008.32
967.31
890.03
Total Enthalpy (kW-h)
131.92
489.04
1,696.61
Specific Enthalpy (kcal/kg)
100.25
99.48
127.88
Heat Capacity (kcal/kg-°C)
0.50
0.99
0.60
Component Flowrates (MT/h)
1,3 PDO
0.235
0.115
11.394
1-2-4 butanetri
0.055
0.000
0.000
Acetic-Acid
0.118
0.000
0.000
Ammonia
0.000
0.000
0.000
Ash
0.064
0.000
0.000
Calcium Chlorid
0.001
0.000
0.000
Cell Debris
0.156
0.000
0.000
Cellulose
0.258
0.000
0.000
Citric Acid
0.014
0.000
0.000
Glucose
0.024
0.000
0.000
Glycerol
0.078
0.000
0.000
KH2PO4
0.019
0.000
0.000
MgSO4
0.008
0.000
0.000
NaCl
0.000
0.000
0.000
Phosphoric Acid
0.018
0.000
0.000
Pyruvic Acid
0.055
0.000
0.000
Sulfuric Acid
0.007
0.000
0.000
Water
0.021
4.115
0.021
TOTAL (MT/h)
1.132
4.230
11.415
TOTAL (m3/h)
1.123
4.373
12.826
- Page 18 -
4. OVERALL COMPONENT BALANCE (MT/yr)
COMPONENT
IN
OUT
IN-OUT
1,3 PDO
0
99,503
- 99,503
1-2-4 butanetri
464
464
- 0
Acetic-Acid
1,000
1,000
- 0
Ammonia
1,084
18
1,066
Ash
4,324
4,425
- 100
Biomass
0
6,442
- 6,442
Calcium Chlorid
12
12
- 0
Carb. Dioxide
0
116,960
- 116,960
Cell Debris
0
1,320
- 1,320
Cellulose
14,414
14,415
- 0
Citric Acid
117
117
- 0
Glucose
216,216
9,251
206,965
Glycerol
668
668
- 0
KH2PO4
161
161
- 0
MgSO4
69
69
- 0
NaCl
1
1
- 0
Nitrogen
188,724
188,724
0
Oxygen
57,334
14,637
42,698
Phosphoric Acid
154
154
- 0
Pyruvic Acid
464
464
- 0
Sodium Hydroxid
1,098
1,964
- 867
Sulfuric Acid
2,191
1,743
447
Water
1,315,107
1,341,216
- 26,109
TOTAL
1,803,601
1,803,728
126
Overall Error:
0.007%
- Page 19 -
5. EQUIPMENT CONTENTS
This section will be skipped (overall process is continuous)
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