Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
Acenaphthene
C
12
H
10
–52 .1
Acetic acid
C
2
H
4
O
2
–52 .8
Acetone
C
3
H
6
O
–39 .7
Acetonitrile
C
2
H
3
N
–34 .9
Acetophenone
C
8
H
8
O
–53 .3
Ammonia
H
3
N
–35 .4
Aniline
C
6
H
7
N
–56 .5
Anisole
C
7
H
8
O
–41 .4
Argon
Ar
–12 .2
Benzaldehyde
C
7
H
6
O
–42 .1
Benzene
C
6
H
6
–28 .1
Benzonitrile
C
7
H
5
N
–48 .5
Benzyl alcohol
C
7
H
8
O
–66 .9
Biphenyl
C
12
H
10
–47 .2
Bromobenzene
C
6
H
5
Br
–33 .5
Bromodichloromethane
CHBrCl
2
–28 .9
Bromoethane
C
2
H
5
Br
–29 .5
Bromomethane
CH
3
Br
–23 .8
2-Bromo-2-methylpropane
C
4
H
9
Br
–25 .4
1,3-Butadiene
C
4
H
6
–31 .4
Butane
C
4
H
10
–24 .8
1,4-Butanediamine
C
4
H
12
N
2
–91 .6
1,4-Butanediol
C
4
H
10
O
2
–89 .6
Butanenitrile
C
4
H
7
N
–42 .1
1,2,3,4-Butanetetrol
C
4
H
10
O
4
–114
1-Butanethiol
C
4
H
10
S
–36 .3
Butanoic acid
C
4
H
8
O
2
–59 .5
1-Butanol
C
4
H
10
O
–61 .9
2-Butanol
C
4
H
10
O
–62 .7
2-Butanone
C
4
H
8
O
–41 .9
1-Butene
C
4
H
8
–24 .1
2-Butoxyethanol
C
6
H
14
O
2
–73 .6
Butyl acetate
C
6
H
12
O
2
–52 .7
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
sec-Butyl acetate
C
6
H
12
O
2
–51 .9
tert-Butyl acetate
C
6
H
12
O
2
–46 .2
Butylamine
C
4
H
11
N
–59 .2
sec-Butylamine
C
4
H
11
N
–57 .1
tert-Butylamine
C
4
H
11
N
–59 .0
Butylbenzene
C
10
H
14
–38 .5
Butyl butanoate
C
8
H
16
O
2
–63 .5
Butyl ethyl ether
C
6
H
14
O
–48 .4
tert-Butyl ethyl ether
C
6
H
14
O
–53 .4
4-tert-Butylphenol
C
10
H
14
O
–63 .8
Butyl propanoate
C
7
H
14
O
2
–57 .8
1-Butyne
C
4
H
6
–13 .5
Carbon dioxide
CO
2
–17 .9
Carbon monoxide
CO
–11 .1
Chlorine
Cl
2
–23 .4
Chlorine dioxide
ClO
2
–27 .8
Chlorobenzene
C
6
H
5
Cl
–30 .6
2-Chloro-1,1′-biphenyl
C
12
H
9
Cl
–42 .8
1-Chlorobutane
C
4
H
9
Cl
–28 .2
2-Chlorobutane
C
4
H
9
Cl
–34 .6
Chlorodibromomethane
CHBr
2
Cl
–33 .3
Chlorodifluoromethane
CHClF
2
–22 .8
Chloroethane
C
2
H
5
Cl
–22 .0
Chlorofluoromethane
CH
2
ClF
–21 .7
1-Chlorohexane
C
6
H
13
Cl
–34 .5
Chloromethane
CH
3
Cl
–20 .2
1-Chloropentane
C
5
H
11
Cl
–34 .1
3-Chlorophenol
C
6
H
5
ClO
–50 .3
1-Chloropropane
C
3
H
7
Cl
–27 .0
2-Chloropyridine
C
5
H
4
ClN
–42 .6
3-Chloropyridine
C
5
H
4
ClN
–46 .2
2-Chlorotoluene
C
7
H
7
Cl
–38 .3
3-Chlorotoluene
C
7
H
7
Cl
–37 .0
enthalPy of hydration of Gases
The molar enthalpy of hydration Δ
hyd
H
∞
is defined as the en-
thalpy change when one mole of an ideal gas is dissolved in an in-
finite amount of water . Another term for this quantity is enthalpy
(heat) of solvation in water at infinite dilution . The enthalpy of
hydration influences the distribution of a volatile compound be-
tween the aqueous solution phase and air and is thus important in
fields such as environmental science, geochemistry, and chemical
engineering . It is related to the enthalpy of solution of the liquid or
solid phase, Δ
sol
H
∞
, by
Δ
hyd
H
∞
= Δ
sol
H
∞
– Δ
vap
H
0
where Δ
vap
H
0
is the molar enthalpy of vaporization . This table
gives the molar enthalpy of hydration for a number of common
substances .
references
1 . Plyasunov, A . V ., and Shock, E . L ., J. Chem. Eng. Data [Hydrocarbons,
alcohols, and ketones] 46, 1016, 2001 .
2 . Plyasunov, A . V ., Plyasunova, N . V ., and Shock, E . L ., J. Chem. Eng.
Data [Esters] 49, 1152, 2004 .
3 . Plyasunov, A . V ., Plyasunova, N . V ., and Shock, E . L ., J. Chem. Eng.
Data [Ethers, diethers, and polyethers] 51, 276, 2006 .
4 . Plyasunova, N . V ., Plyasunov, A . V ., and Shock, E . L ., J. Chem. Eng.
Data [Thiols, sulfides, and polysulfides] 50, 246 .
5 . Plyasunov, A . V ., Plyasunova, N . V ., and Shock, E . L ., J. Chem. Eng.
Data [Nitriles and dinitriles] 51, 1481, 2006 .
6 . Plyasunov, A . V ., and Shock, E . L ., Geochim. Cosmochim. Acta [Inorganics
and halogen compounds; temperature dependence] 67, 4981, 2003 .
7 . Kühne, R ., Ebert, R-U, and Schüürmann, G ., Environ. Sci. Technol .
[Compilation; temperature dependence] 39, 6705, 2005 .
8 . Mintz, C ., Clark, M ., Acree, W . E ., and Abraham, M . H ., J. Chem. Inf.
Model. [Compilation and modelling] 47, 115, 2007 .
5-88
6679X_S05.indb 88
4/11/08 11:29:50 AM
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
4-Chlorotoluene
C
7
H
7
Cl
–33 .3
o-Cresol
C
7
H
8
O
–64 .8
m-Cresol
C
7
H
8
O
–58 .7
p-Cresol
C
7
H
8
O
–61 .3
Cycloheptanol
C
7
H
14
O
–74 .6
Cyclohexane
C
6
H
12
–30 .0
cis-1,2-Cyclohexanediol
C
6
H
12
O
2
–82 .4
Cyclohexanol
C
6
H
12
O
–70 .7
Cyclohexanone
C
6
H
10
O
–49 .8
Cyclohexene
C
6
H
10
–27 .3
Cyclooctane
C
8
H
16
–39 .0
cis-Cyclooctene
C
8
H
14
–45 .5
Cyclopentane
C
5
H
10
–30 .3
Cyclopentanol
C
5
H
10
O
–58 .5
Cyclopentanone
C
5
H
8
O
–44 .3
Cyclopropane
C
3
H
6
–15 .4
Dibromomethane
CH
2
Br
2
–33 .0
Dibutylamine
C
8
H
19
N
–59 .3
Dibutyl ether
C
8
H
18
O
–55 .8
o-Dichlorobenzene
C
6
H
4
Cl
2
–37 .3
m-Dichlorobenzene
C
6
H
4
Cl
2
–35 .3
p-Dichlorobenzene
C
6
H
4
Cl
2
–28 .4
2,3-Dichloro-1,1′-biphenyl
C
12
H
8
Cl
2
–45 .6
2,4-Dichloro-1,1′-biphenyl
C
12
H
8
Cl
2
–43 .0
2,4′-Dichloro-1,1′-biphenyl
C
12
H
8
Cl
2
–44 .2
2,5-Dichlorobiphenyl
C
12
H
8
Cl
2
–45 .6
Dichlorodifluoromethane
CCl
2
F
2
–26 .0
2,2-Dichloro-1,1-difluoro-1-
methoxyethane
C
3
H
4
Cl
2
F
2
O
–30 .4
1,1-Dichloroethane
C
2
H
4
Cl
2
–30 .3
1,2-Dichloroethane
C
2
H
4
Cl
2
–27 .9
1,1-Dichloroethene
C
2
H
2
Cl
2
–28 .5
cis-1,2-Dichloroethene
C
2
H
2
Cl
2
–26 .9
trans-1,2-Dichloroethene
C
2
H
2
Cl
2
–29 .3
Dichloromethane
CH
2
Cl
2
–30 .3
1,2-Dichloropropane
C
3
H
6
Cl
2
–31 .1
1,3-Dichloropropane
C
3
H
6
Cl
2
–29 .7
1,2-Dichloro-1,1,2,2-
tetrafluoroethane
C
2
Cl
2
F
4
–20 .2
1,2-Diethoxyethane
C
6
H
14
O
2
–71 .9
Diethylamine
C
4
H
11
N
–64 .3
N,N-Diethylaniline
C
10
H
15
N
–45 .7
p-Diethylbenzene
C
10
H
14
–46 .4
Diethylene glycol dimethyl ether
C
6
H
14
O
3
–96 .2
Diethyl ether
C
4
H
10
O
–46 .4
Diethyl sulfide
C
4
H
10
S
–40 .2
1,1-Difluoroethane
C
2
H
4
F
2
–20 .7
Difluoromethane
CH
2
F
2
–17 .2
Diiodomethane
CH
2
I
2
–41 .6
Diisopropyl ether
C
6
H
14
O
–51 .7
1,2-Dimethoxyethane
C
4
H
10
O
2
–59 .3
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
Dimethylamine
C
2
H
7
N
–53 .1
2,4-Dimethylaniline
C
8
H
11
N
–58 .7
2,5-Dimethylaniline
C
8
H
11
N
–61 .5
2,6-Dimethylaniline
C
8
H
11
N
–60 .5
N,N-Dimethylaniline
C
8
H
11
N
–49 .6
2,3-Dimethylbutane
C
6
H
14
–32 .4
3,3-Dimethyl-2-butanone
C
6
H
12
O
–47 .5
cis-1,2-Dimethylcyclohexane
C
8
H
16
–38 .3
trans-1,2-Dimethylcyclohexane
C
8
H
16
–36 .1
Dimethyl ether
C
2
H
6
O
–34 .0
N,N-Dimethylformamide
C
3
H
7
NO
–62 .9
2,4-Dimethyl-3-pentanone
C
7
H
14
O
–54 .0
2,3-Dimethylpyridine
C
7
H
9
N
–57 .7
2,4-Dimethylpyridine
C
7
H
9
N
–60 .7
2,5-Dimethylpyridine
C
7
H
9
N
–54 .9
2,6-Dimethylpyridine
C
7
H
9
N
–52 .3
3,4-Dimethylpyridine
C
7
H
9
N
–50 .5
3,5-Dimethylpyridine
C
7
H
9
N
–51 .3
Dimethyl sulfide
C
2
H
6
S
–31 .5
Dimethyl sulfoxide
C
2
H
6
OS
–71 .9
2,5-Dimethyltetrahydrofuran
C
6
H
12
O
–56 .3
1,4-Dioxane
C
4
H
8
O
2
–48 .4
1,2-Dipropoxyethane
C
8
H
18
O
2
–76 .8
Dipropylamine
C
6
H
15
N
–65 .2
Dipropyl ether
C
6
H
14
O
–49 .9
Dipropyl sulfide
C
6
H
14
S
–47 .7
1-Dodecanol
C
12
H
26
O
–81 .9
Ethane
C
2
H
6
–17 .9
1,2-Ethanediamine
C
2
H
8
N
2
–76 .1
1,2-Ethanediol
C
2
H
6
O
2
–77 .3
Ethanethiol
C
2
H
6
S
–28 .9
Ethanol
C
2
H
6
O
–50 .6
2-Ethoxyethanol
C
4
H
10
O
2
–66 .4
1-Ethoxy-2-methoxyethane
C
5
H
12
O
2
–66 .1
Ethyl acetate
C
4
H
8
O
2
–45 .3
Ethylamine
C
2
H
7
N
–53 .7
2-Ethylaniline
C
8
H
11
N
–59 .7
4-Ethylaniline
C
8
H
11
N
–65 .0
Ethylbenzene
C
8
H
10
–39 .4
Ethyl butanoate
C
6
H
12
O
2
–52 .7
Ethylcyclohexane
C
8
H
16
–36 .8
Ethyl 2,2-dimethylpropanoate
C
7
H
14
O
2
–50 .3
Ethylene
C
2
H
4
–13 .7
Ethyl formate
C
3
H
6
O
2
–38 .1
Ethyl hexanoate
C
8
H
16
O
2
–60 .2
Ethyl 3-methylbutanoate
C
7
H
14
O
2
–56 .0
Ethyl 2-methylbutanoate
C
7
H
14
O
2
–55 .4
Ethyl 2-methylpropanoate
C
6
H
12
O
2
–51 .3
Ethyl pentanoate
C
7
H
14
O
2
–56 .5
Ethyl propanoate
C
5
H
10
O
2
–49 .5
2-Ethylpyridine
C
7
H
9
N
–55 .7
EnthalpyofHydrationofGases
5-89
6679X_S05.indb 89
4/11/08 11:29:51 AM
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
3-Ethylpyridine
C
7
H
9
N
–53 .5
4-Ethylpyridine
C
7
H
9
N
–52 .2
9H-Fluorene
C
13
H
10
–42 .7
Fluorobenzene
C
6
H
5
F
–29 .3
Fluoromethane
CH
3
F
–16 .1
Glycerol
C
3
H
8
O
3
–103 .5
Helium
He
–0 .67
1,1,1,2,3,3,3-Heptafluoropropane
C
3
HF
7
–24 .8
Heptanal
C
7
H
14
O
–56 .6
Heptane
C
7
H
16
–34 .0
1-Heptanol
C
7
H
16
O
–72 .1
2-Heptanol
C
7
H
16
O
–72 .6
4-Heptanol
C
7
H
16
O
–75 .3
2-Heptanone
C
7
H
14
O
–54 .9
4-Heptanone
C
7
H
14
O
–58 .1
1,1,1,3,3,3-Hexafluoro-2-propanol
C
3
H
2
F
6
O
–57 .1
Hexanal
C
6
H
12
O
–55 .2
Hexane
C
6
H
14
–31 .9
Hexanedinitrile
C
6
H
8
N
2
–66 .6
1-Hexanol
C
6
H
14
O
–67 .4
3-Hexanol
C
6
H
14
O
–69 .6
2-Hexanone
C
6
H
12
O
–48 .9
3-Hexanone
C
6
H
12
O
–46 .0
1-Hexene
C
6
H
12
–30 .4
Hexyl acetate
C
8
H
16
O
2
–60 .8
Hexylamine
C
6
H
15
N
–65 .9
Hexylbenzene
C
12
H
18
–52 .7
Hydrogen
H
2
–0 .402
Hydrogen selenide
H
2
Se
–15 .7
Hydrogen sulfide
H
2
S
–18 .0
3-Hydroxybenzaldehyde
C
7
H
6
O
2
–70 .7
3-Hydroxybenzonitrile
C
7
H
5
NO
–70 .7
4-Hydroxybenzonitrile
C
7
H
5
NO
–70 .3
Iodoethane
C
2
H
5
I
–31 .7
Iodomethane
CH
3
I
–28 .2
1-Iodopropane
C
3
H
7
I
–35 .3
2-Iodopropane
C
3
H
7
I
–36 .6
Isobutanal
C
4
H
8
O
–40 .0
Isobutane
C
4
H
10
–21 .7
Isobutene
C
4
H
8
–22 .7
Isobutyl acetate
C
6
H
12
O
2
–51 .8
Isobutyl formate
C
5
H
10
O
2
–43 .0
Isobutyl isobutanoate
C
8
H
16
O
2
–55 .3
Isobutyl propanoate
C
7
H
14
O
2
–54 .7
Isoflurane
C
3
H
2
ClF
5
O
–35 .3
Isopentyl acetate
C
7
H
14
O
2
–53 .8
Isopentyl formate
C
6
H
12
O
2
–47 .7
Isophorone
C
9
H
14
O
–59 .1
Isopropyl acetate
C
5
H
10
O
2
–46 .8
Isopropylamine
C
3
H
9
N
–55 .0
Isopropylbenzene
C
9
H
12
–33 .7
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
Isopropyl formate
C
4
H
8
O
2
–43 .0
1-Isopropyl-4-methylbenzene
C
10
H
14
–34 .6
Krypton
Kr
–15 .6
Methane
CH
4
–12 .0
Methanethiol
CH
4
S
–24 .4
Methanol
CH
4
O
–52 .0
2-Methoxyethanol
C
3
H
8
O
2
–60 .4
2-Methoxy-2-methylbutane
C
6
H
14
O
–52 .5
2-Methoxyphenol
C
7
H
8
O
2
–62 .6
Methyl acetate
C
3
H
6
O
2
–40 .1
Methylamine
CH
5
N
–45 .3
Methyl benzoate
C
8
H
8
O
2
–50 .3
Methyl butanoate
C
5
H
10
O
2
–47 .5
3-Methyl-1-butanol
C
5
H
12
O
–66 .0
2-Methyl-2-butanol
C
5
H
12
O
–68 .4
3-Methyl-2-butanone
C
5
H
10
O
–57 .6
2-Methyl-2-butene
C
5
H
10
–26 .6
Methyl tert-butyl ether
C
5
H
12
O
–48 .7
Methyl 2,2-dimethylpropanoate
C
6
H
12
O
2
–46 .2
Methyl formate
C
2
H
4
O
2
–32 .0
Methyl hexanoate
C
7
H
14
O
2
–54 .7
Methyl isobutanoate
C
5
H
10
O
2
–46 .0
4-Methylmorpholine
C
5
H
11
NO
–68 .7
1-Methylnaphthalene
C
11
H
10
–45 .0
2-Methylnaphthalene
C
11
H
10
–44 .9
2-Methylpentane
C
6
H
14
–30 .5
3-Methylpentane
C
6
H
14
–36 .8
Methyl pentanoate
C
6
H
12
O
2
–50 .4
4-Methyl-2-pentanol
C
6
H
14
O
–69 .9
4-Methyl-2-pentanone
C
6
H
12
O
–44 .6
1-Methylpiperidine
C
6
H
13
N
–65 .8
2-Methylpropanenitrile
C
4
H
7
N
–40 .0
Methyl propanoate
C
4
H
8
O
2
–44 .5
2-Methyl-1-propanol
C
4
H
10
O
–60 .2
2-Methyl-2-propanol
C
4
H
10
O
–62 .9
Methyl propyl ether
C
4
H
10
O
–38 .0
2-Methylpyridine
C
6
H
7
N
–50 .3
3-Methylpyridine
C
6
H
7
N
–50 .3
4-Methylpyridine
C
6
H
7
N
–51 .8
N-Methylpyrrolidine
C
5
H
11
N
–63 .4
2-Methyltetrahydrofuran
C
5
H
10
O
–51 .4
Morpholine
C
4
H
9
NO
–69 .5
Naphthalene
C
10
H
8
–42 .8
Neon
Ne
–3 .90
Neopentane
C
5
H
12
–23 .4
Nitric oxide
NO
–11 .9
Nitrobenzene
C
6
H
5
NO
2
–43 .8
Nitroethane
C
2
H
5
NO
2
–32 .5
Nitrogen
N
2
–1 .04
Nitromethane
CH
3
NO
2
–35 .7
2-Nitrophenol
C
6
H
5
NO
3
–49 .8
5-90
EnthalpyofHydrationofGases
6679X_S05.indb 90
4/11/08 11:29:52 AM
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
3-Nitrophenol
C
6
H
5
NO
3
–67 .7
4-Nitrophenol
C
6
H
5
NO
3
–68 .6
1-Nitropropane
C
3
H
7
NO
2
–34 .4
2-Nitropropane
C
3
H
7
NO
2
–34 .1
2-Nitrotoluene
C
7
H
7
NO
2
–46 .4
3-Nitrotoluene
C
7
H
7
NO
2
–38 .5
Nitrous oxide
N
2
O
–19 .8
5-Nonanone
C
9
H
18
O
–62 .8
2-Nonanone
C
9
H
18
O
–65 .3
Octanal
C
8
H
16
O
–48 .8
Octane
C
8
H
18
–36 .0
1-Octanol
C
8
H
18
O
–74 .1
2-Octanone
C
8
H
16
O
–58 .3
1-Octene
C
8
H
16
–39 .2
Octylamine
C
8
H
19
N
–52 .3
Oxygen
O
2
–1 .20
Pentachlorobenzene
C
6
HCl
5
–39 .9
Pentafluoroethane
C
2
HF
5
–21 .5
2,2,3,3,3-Pentafluoro-1-propanol
C
3
H
3
F
5
O
–51 .9
Pentanal
C
5
H
10
O
–42 .9
Pentane
C
5
H
12
–28 .3
1,5-Pentanediamine
C
5
H
14
N
2
–95 .1
Pentanedinitrile
C
5
H
6
N
2
–63 .5
Pentanenitrile
C
5
H
9
N
–45 .6
1-Pentanol
C
5
H
12
O
–61 .9
2-Pentanol
C
5
H
12
O
–63 .3
3-Pentanol
C
5
H
12
O
–59 .6
2-Pentanone
C
5
H
10
O
–45 .3
3-Pentanone
C
5
H
10
O
–49 .6
Pentyl acetate
C
7
H
14
O
2
–55 .3
Pentylamine
C
5
H
13
N
–62 .1
Pentylbenzene
C
11
H
16
–49 .5
Pentyl formate
C
6
H
12
O
2
–48 .1
Perfluoropropene
C
3
F
6
–17 .4
Phenol
C
6
H
6
O
–57 .7
1-Phenyl-1-propanone
C
9
H
10
O
–61 .9
Piperidine
C
5
H
11
N
–65 .4
Propanal
C
3
H
6
O
–39 .4
Propanamide
C
3
H
7
NO
–73 .4
Propane
C
3
H
8
–20 .4
1,3-Propanediamine
C
3
H
10
N
2
–85 .6
1,3-Propanediol
C
3
H
8
O
2
–81 .1
Propanenitrile
C
3
H
5
N
–39 .5
1-Propanethiol
C
3
H
8
S
–30 .2
Propanoic acid
C
3
H
6
O
2
–56 .5
1-Propanol
C
3
H
8
O
–59 .9
2-Propanol
C
3
H
8
O
–58 .2
Propene
C
3
H
6
–21 .6
2-Propoxyethanol
C
5
H
12
O
2
–69 .6
Propyl acetate
C
5
H
10
O
2
–48 .7
Propylamine
C
3
H
9
N
–56 .0
Name
Mol. Form.
Δ
hyd
H
∞
/kJmol
–1
at298.15K
Propylbenzene
C
9
H
12
–36 .4
Propyl butanoate
C
7
H
14
O
2
–54 .9
Propyl formate
C
4
H
8
O
2
–40 .5
Propyl propanoate
C
6
H
12
O
2
–51 .2
Propyne
C
3
H
4
–15 .6
Pyridine
C
5
H
5
N
–42 .1
Quinoline
C
9
H
7
N
–58 .2
Radon
Rn
–24 .0
Styrene
C
8
H
8
–28 .4
Succinonitrile
C
4
H
4
N
2
–58 .2
Sulfur hexafluoride
F
6
S
–20 .7
1,2,3,4-Tetrachlorobenzene
C
6
H
2
Cl
4
–35 .0
1,1,2,2-Tetrachloroethane
C
2
H
2
Cl
4
–34 .8
1,1,1,2-Tetrachloroethane
C
2
H
2
Cl
4
–36 .2
Tetrachloroethene
C
2
Cl
4
–41 .5
Tetrachloromethane
CCl
4
–30 .5
Tetraethylene glycol dimethyl ether C
10
H
22
O
5
–126
1,1,1,2-Tetrafluoroethane
C
2
H
2
F
4
–22 .2
Tetrafluoroethene
C
2
F
4
–15 .1
Tetrafluoromethane
CF
4
–13 .5
2,2,3,3-Tetrafluoro-1-propanol
C
3
H
4
F
4
O
–57 .9
Tetrahydrofuran
C
4
H
8
O
–47 .3
Tetrahydropyran
C
5
H
10
O
–48 .9
Thiophene
C
4
H
4
S
–29 .9
Toluene
C
7
H
8
–32 .4
Tribromomethane
CHBr
3
–35 .8
1,2,3-Trichlorobenzene
C
6
H
3
Cl
3
–32 .6
1,3,5-Trichlorobenzene
C
6
H
3
Cl
3
–34 .2
1,1,1-Trichloroethane
C
2
H
3
Cl
3
–28 .7
1,1,2-Trichloroethane
C
2
H
3
Cl
3
–32 .5
Trichloroethene
C
2
HCl
3
–32 .2
Trichlorofluoromethane
CCl
3
F
–19 .8
Trichloromethane
CHCl
3
–33 .5
1,1,2-Trichloro-1,2,2-
trifluoroethane
C
2
Cl
3
F
3
–28 .8
Triethylamine
C
6
H
15
N
–69 .7
Triethylene glycol dimethyl ether
C
8
H
18
O
4
–102 .4
2,2,2-Trifluoroethanol
C
2
H
3
F
3
O
–50 .2
Trifluoromethane
CHF
3
–22 .6
1,1,1-Trifluoro-2-propanol
C
3
H
5
F
3
O
–53 .5
Trimethylamine
C
3
H
9
N
–52 .7
1,2,3-Trimethylbenzene
C
9
H
12
–37 .4
1,2,4-Trimethylbenzene
C
9
H
12
–36 .6
1,3,5-Trimethylbenzene
C
9
H
12
–39 .1
2,2,4-Trimethylpentane
C
8
H
18
–31 .0
2,3,4-Trimethylpentane
C
8
H
18
–38 .5
Xenon
Xe
–19 .4
o-Xylene
C
8
H
10
–37 .7
m-Xylene
C
8
H
10
–38 .6
p-Xylene
C
8
H
10
–34 .8
EnthalpyofHydrationofGases
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