6317101956

6317101956



4. Relations between symmetry and vibrational spectra of molecules

2

5. Structures and nomenclature of coordination compounds with metal ions, multinuclear complexes, organometallic compounds..

2

6. Coordination number, bonding and geometry of complexes. Hybridization of orbitals.

2

7. Reactions in coordination chemistry: inert and labile compounds, substitution and redox reactions, syntheses in non-aqueous Solutions, stereochemistry of reactions, reactions of coordinated ligands (template reactions).

2

8. Bonding in metal carbonyl complexes and in related complexes with 71-acceptor ligands. Synthesis and reactions of meta! carbonyls.

2

9. Organometallic Chemistry. Methods of syntheses. Non-transition metals.

1

10. Organometallic Chemistry. Bonding between transition metal atoms and carbon atom, organie K systems (linear and cyclic). Alkyl, carbene and carbyne (alkylidyne) complexes with metals. Fullerene complexes.

3

11. Selected organometallic reactions and examples of catalysis

2

12. Inorganic elements in the biological systems. The role of metal ions in stabilization of the nucleic acid structures. Metalloporphyrins.

2

13.Proteins containing iron-sulfur clusters. Structure and role of Vitamin Bi2. Selected metalloenzymes.

2

14. Inorganic compounds in medical diagnostic techniques.

2

15. Inorganic compounds in medical therapy: cisplatin and related complexes, gold and vanadium compounds

2

• Classes - the contents:

•    Seminars - the contents:

•    Laboratory - the contents:

•    Basic literaturę:

1)    A. Bielański, Podstawy chemii nieorganicznej, PWN, Warszawa, 2004 (2002, 1998, 1994).

2)    S.F.A. Kettle, Fizyczna Chemia Nieorganiczna, PWN, Warszawa, 1999.

3)    F. A. Cotton, G. Wilkinson, P.L. Gaus, Chemia Nieorganiczna, PWN, Warszawa, 1998.

4)    S. J. Lippard, J. M. Berg, Podstawy Chemii Bionieorganicznej, PWN, Warszawa, 1998.

•    Additional literaturę:

1)    G.L. Miessler, D.A. Tarr, Inorganic Chemistry, Pearson Prentice Hall, 2006.

2)    F. A. Cotton, G. Wilkinson, C. A. Murillo, M. Bochmann, Advanced Inorganic Chemistry, John Wiley & Sons, Inc. New York, 1999.

•    Conditions of the course acceptance/credition: passing the written exam * - depending on a system of studies

13



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