P21 052

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52. The change in entropy for the ideal gas is found from Eq. 21-2, Eq. 20-14, and the first law of thermo-

dynamics (using the fact that ∆E

int

= 0 for an ideal gas isothermal process).

S =

Q

T

=

W

T

=

nRT

T

ln



V

f

V

i



= nR ln 2 ,

which is independent of the temperature T of the reservoir. Thus the change in entropy of the reservoir,
S



=

S = −nR ln 2, is also independent of T . Here we noticed that the net change in entropy for

the entire system (the ideal gas plus the reservoir) is ∆S

total

= ∆S + ∆S



= 0 for a reversible process

so ∆S



=

S.


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