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Overview

Arkusz1
Dane z aparatu

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Sheet 1: Arkusz1

			STAŁE
1	Masa wody w kalorymetrzei bombie					mw [g]	2890
2	Masa tabletki					m [g]	1,094
3	Masa druckia
		przygotowanego do doświadczenia				md,0 [g]	0,0510
		pozostałosc po spaleniu				md,n [g]	0,0064
		masa spalonego drucika				md [g]	0,0446
4	pojemność cieplna kalorymetru					r = 1478 ± 33 J∙K-1
5	Przeliczenie oporu czujnika na 0C					T[0C] = 129,87 R[kΩ] - 105,92
				Przelicznik	T[0C] = 129,87 R[kΩ] - 105,92
	Czas [ s]	R [ kΩ ]			a	b	T[0C]
	131,443	1,059		T[0C]	129,87	105,92	31,6123	T1w
	150,766	1,0582					31,5084
	180,777	1,0582					31,5084
	210,808	1,0582					31,5084
	240,843	1,0582					31,5084
	270,866	1,0582					31,5084
	300,9	1,058					31,4825
	330,926	1,0577					31,4435
	360,956	1,0574					31,4045
	390,991	1,0573					31,3916
	421,015	1,0575					31,4175	T1g = Tnw
	481,075	1,0572					31,3786
	511,105	1,0577					31,4435
	541,139	1,0598					31,7162
	571,16	1,0629					32,1188
	601,209	1,0649					32,3786
	631,237	1,0661					32,5344
	661,242	1,0667					32,6123
	691,3	1,0673					32,6903
	721,327	1,0685					32,8461
	751,345	1,0689					32,8980
	781,378	1,0692					32,9370
	811,404	1,0697					33,0019
	841,602	1,0698					33,0149
	871,47	1,0699					33,0279
	901,492	1,0701					33,0539
	931,526	1,0701					33,0539
	961,553	1,0702					33,0669
	991,583	1,0702					33,0669
	1021,617	1,0702					33,0669
	1051,643	1,0702					33,0669
	1081,687	1,0703					33,0799
	1111,713	1,0702					33,0669
	1141,72	1,0701					33,0539	T1k
	1171,779	1,0702					33,0669
	1201,803	1,0701					33,0539
	1231,835	1,0701					33,0539
	1261,87	1,07					33,0409
	1291,894	1,07					33,0409
	1321,927	1,0699					33,0279
	1351,948	1,0699					33,0279
	1381,996	1,0699					33,0279
	1412,004	1,0698					33,0149
	1442,031	1,0698					33,0149
	1472,061	1,0697					33,0019
	1502,095	1,0697					33,0019
	1532,12	1,0696					32,9890
	1562,152	1,0695					32,9760
	1592,179	1,0695					32,9760
	1622,236	1,0694					32,9630
	1652,243	1,0693					32,9500
	1682,294	1,0693					32,9500
	1742,335	1,0691					32,9240
	1772,384	1,0691					32,9240
	1802,405	1,069					32,9110
	1832,44	1,0689					32,8980
	1862,475	1,0689					32,8980
	1892,482	1,0688					32,8851
	1922,507	1,0687					32,8721
	1952,552	1,0686					32,8591
	1982,587	1,0686					32,8591
	2012,611	1,0685					32,8461
	2042,63	1,0685					32,8461
	2072,67	1,0684					32,8331
	2102,701	1,0684					32,8331
	2132,735	1,0683					32,8201
	2162,747	1,0683					32,8201
	2192,805	1,0681					32,7941
	2222,813	1,068					32,7812
	2252,837	1,068					32,7812
	2282,883	1,0679					32,7682
	2312,908	1,0678					32,7552
	2342,953	1,0677					32,7422
	2372,961	1,0677					32,7422
	2402,987	1,0676					32,7292
	2433,031	1,0675					32,7162
	2463,057	1,0675					32,7162
	2493,089	1,0674					32,7032
	2523,238	1,0674					32,7032
	2583,192	1,0673					32,6903	Tnk
	Obliczenie korygowanej różnicy temperatur - Metoda graficzna
		Okres wstępny
	Czas [ s]	R [ kΩ ]	T[0C]	czas [ min ]
	131,443	1,059	31,6123	2,1907
	150,766	1,0582	31,5084	2,5128
	180,777	1,0582	31,5084	3,0130
	210,808	1,0582	31,5084	3,5135
	240,843	1,0582	31,5084	4,0141
	270,866	1,0582	31,5084	4,5144
	300,9	1,058	31,4825	5,0150
	330,926	1,0577	31,4435	5,5154
	360,956	1,0574	31,4045	6,0159
	390,991	1,0573	31,3916	6,5165
	421,015	1,0575	31,4175	7,0169
	aw	bw
	-0,0006	31,64
		Okres końcowy
	Czas [ s]	R [ kΩ ]	T[0C]	czas [ min ]
	1171,779	1,0702	33,0669	19,5297
	1201,803	1,0701	33,0539	20,0301
	1231,835	1,0701	33,0539	20,5306
	1261,87	1,07	33,0409	21,0312
	1291,894	1,07	33,0409	21,5316
	1321,927	1,0699	33,0279	22,0321
	1351,948	1,0699	33,0279	22,5325
	1381,996	1,0699	33,0279	23,0333
	1412,004	1,0698	33,0149	23,5334
	1442,031	1,0698	33,0149	24,0339
	1472,061	1,0697	33,0019	24,5344
	1502,095	1,0697	33,0019	25,0349
	1532,12	1,0696	32,9890	25,5353
	1562,152	1,0695	32,9760	26,0359
	1592,179	1,0695	32,9760	26,5363
	1622,236	1,0694	32,9630	27,0373
	1652,243	1,0693	32,9500	27,5374
	1682,294	1,0693	32,9500	28,0382
	1742,335	1,0691	32,9240	29,0389
	1772,384	1,0691	32,9240	29,5397
	1802,405	1,069	32,9110	30,0401
	1832,44	1,0689	32,8980	30,5407
	1862,475	1,0689	32,8980	31,0413
	1892,482	1,0688	32,8851	31,5414
	1922,507	1,0687	32,8721	32,0418
	1952,552	1,0686	32,8591	32,5425
	1982,587	1,0686	32,8591	33,0431
	2012,611	1,0685	32,8461	33,5435
	2042,63	1,0685	32,8461	34,0438
	2072,67	1,0684	32,8331	34,5445		ak	bk
	2102,701	1,0684	32,8331	35,0450		-0,0003	33,408
	2132,735	1,0683	32,8201	35,5456
	2162,747	1,0683	32,8201	36,0458
	2192,805	1,0681	32,7941	36,5468
	2222,813	1,068	32,7812	37,0469
	2252,837	1,068	32,7812	37,5473
	2282,883	1,0679	32,7682	38,0481
	2312,908	1,0678	32,7552	38,5485
	2342,953	1,0677	32,7422	39,0492
	2372,961	1,0677	32,7422	39,5494
	2402,987	1,0676	32,7292	40,0498
	2433,031	1,0675	32,7162	40,5505
	2463,057	1,0675	32,7162	41,0510
	2493,089	1,0674	32,7032	41,5515
	2523,238	1,0674	32,7032	42,0540
	2583,192	1,0673	32,6903	43,0532
		Okres główny
	Czas [ s]	R [ kΩ ]	T[0C]	czas [ min ]
	481,075	1,0572	31,3786	8,0179
	511,105	1,0577	31,4435	8,5184
	541,139	1,0598	31,7162	9,0190
	571,16	1,0629	32,1188	9,5193
	601,209	1,0649	32,3786	10,0202
	631,237	1,0661	32,5344	10,5206
	661,242	1,0667	32,6123	11,0207
	691,3	1,0673	32,6903	11,5217
	721,327	1,0685	32,8461	12,0221
	751,345	1,0689	32,8980	12,5224
	781,378	1,0692	32,9370	13,0230
	811,404	1,0697	33,0019	13,5234
	841,602	1,0698	33,0149	14,0267
	871,47	1,0699	33,0279	14,5245
	901,492	1,0701	33,0539	15,0249
	931,526	1,0701	33,0539	15,5254
	961,553	1,0702	33,0669	16,0259
	991,583	1,0702	33,0669	16,5264
	1021,617	1,0702	33,0669	17,0270
	1051,643	1,0702	33,0669	17,5274
	1081,687	1,0703	33,0799	18,0281
	1111,713	1,0702	33,0669	18,5286
	1141,72	1,0701	33,0539	19,0287
												31,289
				32,2162
							aw	bw
							-0,0006	31,64
				585	[s]
				9,75	[min]
													1,9435
												33,2325
							ak	bk
							-0,0003	33,408
			Obliczenie korygowanej różnicy temperatur- Metoda REGNAULTA - PFAUNDLERA
		Okres wstępny
					31,4175	31,6123	421,015	-0,0005
					31,4175	31,6123	31,5149
					31,64
		Okres końcowy
							32,6903	33,0539	2583,192	1141,72	-0,000252
							32,6903	33,0539	2583,192	1141,72	33,3419
							32,6903	33,0539	32,8721
		Wyrażenie na poprawkę
								23	32,872069	31,5149275	-0,0003	-0,0005	33,0539	31,4175	0,00814
	Czas [ s]	R [ kΩ ]	T[0C]	czas [ min ]
	481,075	1,0572	31,3786	8,0179		31,4110315
	511,105	1,0577	31,4435	8,5184		31,5798625
	541,139	1,0598	31,7162	9,0190		31,9175245
	571,16	1,0629	32,1188	9,5193		32,248693
	601,209	1,0649	32,3786	10,0202		32,456485
	631,237	1,0661	32,5344	10,5206		32,573368
	661,242	1,0667	32,6123	11,0207		32,65129
	691,3	1,0673	32,6903	11,5217		32,768173
	721,327	1,0685	32,8461	12,0221		32,872069
	751,345	1,0689	32,8980	12,5224		32,9175235
	781,378	1,0692	32,9370	13,0230		32,9694715
	811,404	1,0697	33,0019	13,5234		33,0084325
	841,602	1,0698	33,0149	14,0267		33,0214195
	871,47	1,0699	33,0279	14,5245		33,0409
	901,492	1,0701	33,0539	15,0249		33,053887
	931,526	1,0701	33,0539	15,5254		33,0603805
	961,553	1,0702	33,0669	16,0259		33,066874
	991,583	1,0702	33,0669	16,5264		33,066874
	1021,617	1,0702	33,0669	17,0270		33,066874
	1051,643	1,0702	33,0669	17,5274		33,0733675
	1081,687	1,0703	33,0799	18,0281		33,0733675
	1111,713	1,0702	33,0669	18,5286		33,0603805
	1141,72	1,0701	33,0539	19,0287
					Suma	688,547217
				1,6835
	Obliczenie ciepła spalania
	R-P		-6688000	5,1E-06	10	0,154	2,88	4175	1478	1,6835		-22697,4823955005
														-24453,0252977502	±	1755,54290224975
			-6688000	5,1E-06	10	0,154	2,88	4175	1478	1,9435		-26208,5682
Obliczenie molowego ciepła spalania w stalej objętości
				R-P	-22697,4823955005		1,094		-2867472,1228388				poprawka
											-3089257,52815082	±	221,785405312027
					-26208,5682	138,2098	1,094		-3311042,93346285
Obliczenie standardowej entalpii spalania
						R-P	-2867472,1228388	8,314	298		-2878621,1968388				poprawka
													-3100406,60215082	±	221,785405312027
							-3311042,93346285	8,314	298		-3322192,00746285
Obliczenie ciepła tworzenia związku
	-2878621,1968388		-393510		-173000		-811300		-285900			-1574998,8031612	R-P			poprawka
														-1353213,39784918	±	-221,785405312027
	-3322192,00746285		-393510		-173000		-811300		-285900			-1131427,99253715

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Sheet 2: Dane z aparatu

Dane z aparatu			Poprawione dane
Czas [ s]	Rezystancja		Czas [ s]	Rezystancja
131,443	1,059		131,443	1,059
150,766	1,0582		150,766	1,0582
180,777	1,0582		180,777	1,0582
210,808	1,0582		210,808	1,0582
240,843	1,0582		240,843	1,0582
270,866	1,0582		270,866	1,0582
300,9	1,058		300,9	1,058
330,926	1,0577		330,926	1,0577
360,956	1,0574		360,956	1,0574
390,991	1,0573		390,991	1,0573
421,015	1,0575		421,015	1,0575
451,049	1,0346		481,075	1,0572
481,075	1,0572		511,105	1,0577
511,105	1,0577		541,139	1,0598
541,139	1,0598		571,16	1,0629
571,16	1,0629		601,209	1,0649
601,209	1,0649		631,237	1,0661
631,237	1,0661		661,242	1,0667
661,242	1,0667		691,3	1,0673
691,3	1,0673		721,327	1,0685
721,327	1,0685		751,345	1,0689
751,345	1,0689		781,378	1,0692
781,378	1,0692		811,404	1,0697
811,404	1,0697		841,602	1,0698
841,602	1,0698		871,47	1,0699
871,47	1,0699		901,492	1,0701
901,492	1,0701		931,526	1,0701
931,526	1,0701		961,553	1,0702
961,553	1,0702		991,583	1,0702
991,583	1,0702		1021,617	1,0702
1021,617	1,0702		1051,643	1,0702
1051,643	1,0702		1081,687	1,0703
1081,687	1,0703		1111,713	1,0702
1111,713	1,0702		1141,72	1,0701
1141,72	1,0701		1171,779	1,0702
1171,779	1,0702		1201,803	1,0701
1201,803	1,0701		1231,835	1,0701
1231,835	1,0701		1261,87	1,07
1261,87	1,07		1291,894	1,07
1291,894	1,07		1321,927	1,0699
1321,927	1,0699		1351,948	1,0699
1351,948	1,0699		1381,996	1,0699
1381,996	1,0699		1412,004	1,0698
1412,004	1,0698		1442,031	1,0698
1442,031	1,0698		1472,061	1,0697
1472,061	1,0697		1502,095	1,0697
1502,095	1,0697		1532,12	1,0696
1532,12	1,0696		1562,152	1,0695
1562,152	1,0695		1592,179	1,0695
1592,179	1,0695		1622,236	1,0694
1622,236	1,0694		1652,243	1,0693
1652,243	1,0693		1682,294	1,0693
1682,294	1,0693		1742,335	1,0691
1712,258	0,0691		1772,384	1,0691
1742,335	1,0691		1802,405	1,069
1772,384	1,0691		1832,44	1,0689
1802,405	1,069		1862,475	1,0689
1832,44	1,0689		1892,482	1,0688
1862,475	1,0689		1922,507	1,0687
1892,482	1,0688		1952,552	1,0686
1922,507	1,0687		1982,587	1,0686
1952,552	1,0686		2012,611	1,0685
1982,587	1,0686		2042,63	1,0685
2012,611	1,0685		2072,67	1,0684
2042,63	1,0685		2102,701	1,0684
2072,67	1,0684		2132,735	1,0683
2102,701	1,0684		2162,747	1,0683
2132,735	1,0683		2192,805	1,0681
2162,747	1,0683		2222,813	1,068
2192,805	1,0681		2252,837	1,068
2222,813	1,068		2282,883	1,0679
2252,837	1,068		2312,908	1,0678
2282,883	1,0679		2342,953	1,0677
2312,908	1,0678		2372,961	1,0677
2342,953	1,0677		2402,987	1,0676
2372,961	1,0677		2433,031	1,0675
2402,987	1,0676		2463,057	1,0675
2433,031	1,0675		2493,089	1,0674
2463,057	1,0675		2523,238	1,0674
2493,089	1,0674		2583,192	1,0673
2523,238	1,0674
2553,144	0,0673
2583,192	1,0673