stężenie [mol/dm3] |
0,016 |
0,014 |
0,01 |
0,008 |
0,006 |
0,004 |
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objętość 0,2m (NH4)2S2O8[cm3] |
8 |
7 |
5 |
4 |
3 |
2 |
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stężenie (NH4)2S2O8 [mol/dm3] |
czas przebiegu reakcji |
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t1[s] |
t2[s] |
tśr.[s] |
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0,0160 |
510,0 |
495,6 |
502,8 |
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0,0140 |
274,8 |
301,8 |
288,3 |
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0,010 |
227,0 |
235,0 |
231,0 |
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0,0080 |
146,4 |
191,4 |
168,9 |
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0,0060 |
140,0 |
138,0 |
139,0 |
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0,0040 |
110,0 |
110,0 |
110,0 |
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x |
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x |
y |
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t [s] |
log(t) |
alfa |
log(alfa) |
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alfa |
t [s] |
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502,8 |
2,70 |
0,0625 |
-1,2041 |
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0,0625 |
502,8 |
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288,3 |
2,46 |
0,0714 |
-1,1461 |
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0,0714 |
288,3 |
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231,0 |
2,36 |
0,1000 |
-1,0000 |
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0,1000 |
231,0 |
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168,9 |
2,23 |
0,1250 |
-0,9031 |
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0,1250 |
168,9 |
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139,0 |
2,14 |
0,1667 |
-0,7782 |
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0,1667 |
139,0 |
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110,0 |
2,04 |
0,2500 |
-0,6021 |
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0,2500 |
110,0 |
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y |
x |
y |
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t [s] |
No-x |
c(t) |
log(t) |
log[c(t)] |
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No-x |
log[co-x] |
log(t) |
log[co-x] |
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502,8 |
3,7500E-04 |
6,2500E-03 |
2,70 |
-2,2041 |
4,17E-04 |
3,7500E-04 |
1,56E-02 |
2,70 |
-1,8068 |
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288,3 |
3,2500E-04 |
5,1467E-03 |
2,46 |
-2,2663 |
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3,2500E-04 |
1,36E-02 |
2,46 |
-1,8664 |
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231,0 |
2,2500E-04 |
3,7500E-03 |
2,36 |
-2,4260 |
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2,2500E-04 |
9,58E-03 |
2,36 |
-2,0186 |
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168,9 |
1,7500E-04 |
2,9167E-03 |
2,23 |
-2,5351 |
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1,7500E-04 |
7,58E-03 |
2,23 |
-2,1203 |
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139,0 |
1,2500E-04 |
2,0833E-03 |
2,14 |
-2,6812 |
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1,2500E-04 |
0,0056 |
2,14 |
-2,2518 |
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110,0 |
7,5000E-05 |
1,2500E-03 |
2,04 |
-2,9031 |
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7,5000E-05 |
3,58E-03 |
2,04 |
-2,4461 |
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1. Rząd reakcji względem jonów nadsiarczanowych |
-8,6127E-01 |
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2. Rząd reakcji względem jonów jodkowych |
1,0000E+00 |
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3. Całkowity rząd reakcji |
1,3873E-01 |
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4. Stała szybkości k' [1/s] |
1,3852E-08 |
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5. Stała szybkości k [dm3/mol*s] |
1,6623E-07 |
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x |
y |
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alfa |
c0 |
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0,016 |
0,0625 |
0,016 |
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0,014 |
0,0714 |
0,014 |
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0,01 |
0,1000 |
0,01 |
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0,008 |
0,1250 |
0,008 |
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0,006 |
0,1667 |
0,006 |
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0,004 |
0,2500 |
0,004 |
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