Dawid Badanie kinetyki zasadowej hydrolizy estru


Overview

Dane
Wykres1
Wykres2
Wykres3
Wykres4


Sheet 1: Dane

Pomiar 1- 0,1 ml estru Pomiar 2 - 0,2 ml estru Pomiar 3 - 1 ml estru



λ0,01MKCl
[mS]
κ0,01M KCl
[mS∙cm-1]
k [cm-1]



lp. λ [mS] κ [mS·cm-1] lp. λ [mS] κ [mS∙cm-1] lp. λ [mS] κ [mS·cm-1] κ-κ∞ 0,1ml κ-κ∞ 0,2ml κ-κ∞ 1ml czas [s] 6.30 1.34 0.212698412698413



1 9.64 2.05 1 9.78 2.08 1 9.71 2.07 0.81 1.11 1.31 0 n 1/Y^(n-1)
2 9.61 2.04 2 9.75 2.07 2 9.64 2.05 0.80 1.10 1.29 15 11.8102 11.3408 6.7152 1.25705491986952 0.906268203834762 0.767439060182744 0.031319845148789
3 9.59 2.04 3 9.71 2.07 3 9.53 2.03 0.80 1.09 1.27 30 8.0652 8.0591 4.8231 1.26400176952303 0.91359060485449 0.782119100853413 0.016269526707533
4 9.53 2.03 4 9.64 2.05 4 9.34 1.99 0.78 1.08 1.23 45 6.8347 6.4691 3.8673 1.2853024014659 0.926688461978158 0.80881835401752 0.011566315595183
5 9.45 2.01 5 9.56 2.03 5 9.15 1.95 0.77 1.06 1.19 60 5.8620 5.4581 3.3045 1.31482493849283 0.942116574702676 0.837369755300212 0.009232791765167
6 9.34 1.99 6 9.46 2.01 6 8.97 1.91 0.74 1.04 1.15 75 5.3573 4.7475 2.8480 1.35766296903091 0.962126132948345 0.866306358555473 0.007823431049773
7 9.23 1.96 7 9.34 1.99 7 8.75 1.86 0.72 1.01 1.10 90 5.1735 4.2809 2.5313 1.40333283185027 0.987267876943575 0.90445559097232 0.006981680289243
8 9.15 1.95 8 9.23 1.96 8 8.52 1.81 0.70 0.99 1.05 105 4.5612 3.9158 2.2989 1.43848917948967 1.01147548343461 0.948033026035929 0.006416844816406
9 9.1 1.94 9 9.11 1.94 9 8.34 1.77 0.69 0.96 1.01 120 4.1988 3.6095 2.0921 1.46135420925001 1.03924941495721 0.985123538164073 0.005923416478358
10 9.01 1.92 10 8.97 1.91 10 8.08 1.72 0.67 0.93 0.96 135 4.0947 3.4599 1.9477 1.50436251431797 1.07360709040582 1.04402472026751 0.005680437991027
11 8.93 1.90 11 8.81 1.87 11 7.82 1.66 0.66 0.90 0.90 150 3.8361 3.2773 1.8226 1.54473433584634 1.11570988325118 1.11027051292152 0.005508248662446
12 8.86 1.88 12 8.68 1.85 12 7.56 1.61 0.64 0.87 0.85 165 3.5778 3.1617 1.7273 1.58184667499064 1.15238317028578 1.18531561389052 0.005390091220615
13 8.75 1.86 13 8.56 1.82 13 7.30 1.55 0.62 0.85 0.79 180 3.4404 3.0013 1.6462 1.64384069723316 1.18840138572281 1.27102446746012 0.005315266936931
14 8.71 1.85 14 8.45 1.80 14 7.03 1.50 0.61 0.82 0.74 195 3.3021 2.8865 1.5738 1.66758392318533 1.22341675460754 1.37392816511999 0.005291731760172
15 8.63 1.84 15 8.34 1.77 15 6.81 1.45 0.59 0.80 0.69 210 3.1447 2.7849 1.5074 1.71715053606325 1.26051894021531 1.47070141822641 0.00522658548809
16 8.56 1.82 16 8.22 1.75 16 6.55 1.39 0.58 0.77 0.63 225 3.0497 2.6685 1.4593 1.76295740932502 1.30359916526667 1.6038508971634 0.005249924363493
17 8.52 1.81 17 8.11 1.72 17 6.30 1.34 0.57 0.75 0.58 240 2.8453 2.6712 1.4203 1.79022687251084 1.34571029820249 1.7562671392662 0.005286894471277
18 8.42 1.79 18 8.01 1.70 18 6.07 1.29 0.55 0.73 0.53 255 2.8531 2.5201 1.3842 1.86216869362727 1.38638055463227 1.92394334557755 0.005321041374232
19 8.37 1.78 19 7.90 1.68 19 5.84 1.24 0.54 0.71 0.48 270 2.8025 2.4540 1.3533 1.90031175496532 1.43400029838685 2.12627133856752 0.00538287574374
20 8.33 1.77 20 7.82 1.66 20 5.62 1.20 0.53 0.69 0.44 285 2.6942 2.3708 1.3259 1.93194938203229 1.47070141822641 2.36313213616971 0.005457250839133
21 8.26 1.76 21 7.70 1.64 21 5.40 1.15 0.51 0.66 0.39 300 2.5406 2.3489 1.3077 1.98987839285642 1.52934789768356 2.65808957328368 0.0055628010515
22 8.19 1.74 22 7.62 1.62 22 5.21 1.11 0.50 0.65 0.35 315 2.5239 2.2753 1.2909 2.05132261228641 1.5710655929602 2.97779306073674 0.005645904890372
23 8.11 1.72 23 7.52 1.60 23 5.03 1.07 0.48 0.63 0.31 330 2.5409 2.2723 1.2730 2.12627133856752 1.62646482378078 3.35897839860188 0.005741575292676
24 8.08 1.72 24 7.44 1.58 24 4.85 1.03 0.48 0.61 0.27 345 2.3667 2.2058 1.2604 2.15578272390671 1.67362538781342 3.84956627756604 0.005873322331512
25 8.01 1.70 25 7.36 1.57 25 4.69 1.00 0.46 0.59 0.24 360 2.3609 2.1434 1.2513 2.22787464207825 1.7235506091132 4.42075133065337 0.005999521102767
26 7.96 1.69 26 7.26 1.54 26 4.55 0.97 0.45 0.57 0.21 375 2.3424 2.1115 1.2392 2.2823376293141 1.79022687251084 5.0766868053068 0.006115623972322
27 7.9 1.68 27 7.22 1.54 27 4.43 0.94 0.44 0.56 0.18 390 2.2878 2.0388 1.2231 2.35124777337788 1.81833781855859 5.81238960595384 0.006215331210353
28 7.85 1.67 28 7.11 1.51 28 4.32 0.92 0.43 0.54 0.16 405 2.2753 2.0804 1.2208 2.41187376595083 1.90031175496532 6.69786496381822 0.006323057666062
29 7.82 1.66 29 7.03 1.50 29 4.22 0.90 0.42 0.52 0.14 420 2.1551 1.9729 1.2178 2.44974609059845 1.96463901819961 7.76831054463235 0.006437950472371
30 7.78 1.65 30 6.96 1.48 30 4.13 0.88 0.41 0.51 0.12 435 2.0423 1.9635 1.2029 2.50209805625885 2.02453880546939 9.06540446342276 0.006558562707026
31 7.7 1.64 31 6.89 1.47 31 4.06 0.86 0.40 0.49 0.10 450 2.1553 1.9565 1.1926 2.61368332455774 2.08813636430041 10.4104971716258 0.006636680378179
32 7.66 1.63 32 6.82 1.45 32 4.00 0.85 0.39 0.48 0.09 465 2.0373 1.8967 1.1788 2.67322289977709 2.15578272390671 11.9191645799218 0.006703497532468
33 7.62 1.62 33 6.77 1.44 33 3.94 0.84 0.38 0.47 0.08 480 2.0387 1.8493 1.1776 2.73548777710905 2.20679816242087 13.9273137385062 0.006807101157598
34 7.56 1.61 34 6.70 1.43 34 3.89 0.83 0.37 0.45 0.07 495 2.0602 1.8629 1.1581 2.83441617949551 2.2823376293141 16.1880299567699 0.006894122354528
35 7.52 1.60 35 6.63 1.41 35 3.85 0.82 0.36 0.44 0.06 510 2.0055 1.8619 1.1497 2.90436696975072 2.36313213616971 18.5899526887207 0.006953180310032
36 7.49 1.59 36 6.56 1.40 36 3.81 0.81 0.35 0.42 0.05 525 1.8798 1.8067 1.1403 2.95909673784643 2.44974609059845 21.8092384684183 0.007048138357987
37 7.44 1.58 37 6.51 1.38 37 3.77 0.80 0.34 0.41 0.04 540 1.9321 1.7808 1.1523 3.05495835180058 2.51553129550526 26.3438103460943 0.007189989249514
38 7.41 1.58 38 6.47 1.38 38 3.75 0.80 0.33 0.40 0.04 555 1.8633 1.7607 1.1335 3.1154602324967 2.57071181507647 29.3823821578376 0.007185503982694
39 7.36 1.57 39 6.37 1.35 39 3.73 0.79 0.32 0.38 0.03 570 1.7879 1.8068 1.1396 3.22170236991058 2.71965594753377 33.1959497487577 0.007203048677283
40 7.3 1.55 40 6.33 1.35 40 3.70 0.79 0.31 0.37 0.03 585 1.8328 1.7485 1.1219 3.35897839860188 2.78408872580887 41.1637833739635 0.007373294206547
41 7.29 1.55 41 6.29 1.34 41 3.68 0.78 0.31 0.36 0.02 600 1.7574 1.6773 1.0931 3.38298254829461 2.85159156306609 48.9422087526342 0.007467385325822
42 7.23 1.54 42 6.22 1.32 42 3.66 0.78 0.30 0.35 0.02 615 1.7780 1.6987 1.0993 3.53439544912846 2.97779306073674 60.2529204736532 0.007611547790171
43 7.21 1.53 43 6.17 1.31 43 3.65 0.78 0.29 0.34 0.02 630 1.7750 1.6592
3.5878680862562 3.07486740240056
0.007617277661288
44 7.18 1.53 44 6.14 1.31 44 3.63 0.77 0.29 0.33 0.01 645 1.6683 1.6310
3.67112498910915 3.13615406540808
0.007886150386145
45 7.14 1.52 45 6.10 1.30 45 3.62 0.77 0.28 0.32 0.01 660 1.6994 1.5993
3.7882225018944 3.22170236991058
0.007983164478572
46 7.08 1.51 46 6.03 1.28 46 3.61 0.77 0.26 0.31 0.01 675 1.6975 1.6217
3.97830031648406 3.38298254829461
0.008136343862476
47 7.07 1.50 47 5.99 1.27 47 3.61 0.77 0.26 0.30 0.01 690 1.6297 1.6264
4.0118160853816 3.48246673400856
0.007959466821988
48 7.03 1.50 48 5.96 1.27 48 3.60 0.77 0.25 0.29 0.01 705 1.6159 1.5472
4.15161626400782 3.56093453127138
0.00819817614131
49 6.97 1.48 49 5.92 1.26 49 3.60 0.77 0.24 0.29 0.01 720 1.6646 1.5338
4.38022462382396 3.67112498910915
0.008027380805032
50 6.95 1.48 50 5.87 1.25 50 3.59 0.76 0.24 0.27 0.00 735 1.6133 1.5003
4.46202154164012 3.8186523340049
0.008415209915281
51 6.92 1.47 51 5.81 1.24 51 3.58 0.76 0.23 0.26 0.00 750 1.5831 1.5095
4.59050228156816 4.0118160853816
0.009171101957722
52 6.89 1.47 52 5.78 1.23 52 3.58 0.76 0.22 0.26 0.00 765 1.6023 1.5192
4.72646102279888 4.11577661910871
0.008991276429139
53 6.88 1.46 53 5.73 1.22 53 3.57 0.76 0.22 0.24 0.00 780 1.4783 1.5201
4.77355561545197 4.30132322513298

54 6.82 1.45 54 5.70 1.21 54 3.57 0.76 0.21 0.24 0.00 795 1.5363 1.4777
5.07668680530679 4.42075133065337

55 6.81 1.45 55 5.66 1.20 55 3.57 0.76 0.21 0.23 0.00 810 1.4592 1.4494
5.13092214209162 4.59050228156816

56 6.77 1.44 56 5.63 1.20 56 3.57 0.76 0.20 0.22 0.00 825 1.4470 1.4269
5.35974423897701 4.72646102279888

57 6.74 1.43 57 5.61 1.19 57 3.57 0.76 0.19 0.22 0.00 840 1.4607 1.3957
5.54495846675545 4.8215813252365

58 6.71 1.43 58 5.55 1.18 58 3.56 0.76 0.19 0.21 0.00 855 1.4162 1.4368
5.74318447795796 5.13092214209162

59 6.69 1.42 59 5.52 1.17 59 3.56 0.76 0.18 0.20 0.00 870 1.4357 1.3975
5.88325281511565 5.30067984131006

60 6.66 1.42 60 5.47 1.16 60 3.56 0.76 0.17 0.19 0.00 885 1.3588 1.3971
6.10640510737851 5.60952228466053

61 6.63 1.41 61 5.44 1.16 61 3.56 0.76 0.17 0.18 0.00 900 1.3862 1.4091
6.34682302915408 5.81238960595383

62 6.62 1.41 62 5.43 1.15 62 3.55 0.76 0.17 0.18 0.00 915 1.3744 1.3638
6.43114777015289 5.88325281511566

63 6.56 1.40 63 5.40 1.15 63 3.55 0.76 0.15 0.17 0.00 930 1.3885 1.3426
6.98722622897462 6.10640510737851

64 6.55 1.39 64 5.36 1.14 64 3.55 0.76 0.15 0.17 0.00 945 1.3394 1.3633
7.08921432910356 6.43114777015289

65 6.51 1.38 65 5.32 1.13 65 3.55 0.76 0.14 0.16 0.00 960 1.3648 1.3354
7.52818477512831 6.79166505922031

66 6.48 1.38 66 5.29 1.13 66 3.55 0.76 0.14 0.15 0.00 975 1.3819 1.3138
7.89410502981879 7.08921432910356

67 6.47 1.38 67 5.26 1.12 67 3.55 0.76 0.13 0.14 0.00 990 1.3284 1.3417
8.02396618791187 7.41351240553445

68 6.43 1.37 68 5.25 1.12 68 3.55 0.76 0.13 0.14 0.00 1005 1.3162 1.3308
8.58826602931588 7.52818477512831

69 6.43 1.37 69 5.21 1.11 69 3.55 0.76 0.13 0.13 0.00 1020 1.2940 1.3020
8.58826602931588 8.02396618791186

70 6.37 1.35 70 5.18 1.10 70 3.55 0.76 0.11 0.13 0.00 1035 1.2857 1.2383
9.59758768932276 8.44000870951606

71 6.37 1.35 71 5.17 1.10 71 3.55 0.76 0.11 0.13 0.00 1050 1.2818 1.2298
9.59758768932276 8.58826602931588

72 6.36 1.35 72 5.14 1.09 72 3.55 0.76 0.11 0.12 0.00 1065 1.2396 1.2228
9.78888183161371 9.06540446342275

73 6.33 1.35 73 5.11 1.09 73 3.55 0.76 0.10 0.11 0.00 1080 1.2182 1.2157
10.4104971716257 9.59758768932276

74 6.3 1.34 74 5.10 1.08 74 3.55 0.76 0.10 0.11 0.00 1095 1.2410 1.1959
11.1147496614432 9.78888183161373

75 6.29 1.34 75 5.06 1.08 75 3.55 0.76 0.10 0.10 0.00 1110 1.2311 1.1943
11.370757474067 10.6352916043412

76 6.28 1.34 76 5.03 1.07 76 3.55 0.76 0.09 0.10 0.00 1125 1.1929 1.1865
11.6386167351355 11.370757474067

77 6.25 1.33 77 5.03 1.07 77 3.55 0.76 0.09 0.10 0.00 1140 1.1722 1.1622
12.522086852534 11.370757474067

78 6.22 1.32 78 5.02 1.07 78 3.55 0.76 0.08 0.09 0.00 1155 1.1634 1.1454
13.5477637519424 11.6386167351356

79 6.21 1.32 79 4.98 1.06 79 3.55 0.76 0.08 0.09 0.00 1170 1.1674 1.1511
13.9273137385062 12.846579003934

80 6.17 1.31 80 4.92 1.05 80 3.55 0.76 0.07 0.07 0.00 1185 1.1512 1.1581
15.6800653629222 15.2025036976778

81 6.17 1.31 81 4.91 1.04 81 3.55 0.76 0.07 0.07 0.00 1200 1.1164 1.1374
15.6800653629222 15.6800653629222

82 6.14 1.31 82 4.89 1.04 82 3.55 0.76 0.06 0.07 0.00 1215 1.1270 1.1227
17.3074861949463 16.7293767808538

83 6.11 1.30 83 4.87 1.04 83 3.55 0.76 0.06 0.06 0.00 1230 1.1281 1.1081
19.3037820607755 17.9262093058471

84 6.11 1.30 84 4.85 1.03 84 3.55 0.76 0.06 0.06 0.00 1245 1.0935 1.1035
19.3037820607755 19.3037820607756

85 6.1 1.30 85 4.83 1.03 85 3.55 0.76 0.06 0.05 0.00 1260 1.0954 1.0884
20.073550039539 20.9060547688338

86 6.07 1.29 86 4.81 1.02 86 3.55 0.76 0.05 0.05 0.00 1275 1.0636 1.0828
22.7924381296927 22.7924381296928

87 6.04 1.28 87 4.79 1.02 87 3.55 0.76 0.04 0.04 0.00 1290 1.0683 1.0767
26.3438103460943 25.0452162732358

88 6.02 1.28 88 4.77 1.01 88 3.55 0.76 0.04 0.04 0.00 1305 1.0607 1.0589
29.3823821578376 27.7816933819944

89 6.02 1.28 89 4.76 1.01 89 3.56 0.76 0.04 0.04 0.00 1320
1.0372

29.3823821578376

90 5.99 1.27 90 4.74 1.01 90 3.56 0.76 0.03 0.03 0.00 1335 Średnie n Średnie k
91 5.96 1.27 91 4.72 1.00 91 3.56 0.76 0.03 0.03 0.00 1350 2.2584 2.0969 1.7530 6.21211047561987 5.8952 9.9497
92 5.96 1.27 92 4.70 1.00 92 3.56 0.76 0.03 0.03 0.00 1365






93 5.95 1.27 93 4.68 1.00 93 3.56 0.76 0.02 0.02 0.00 1380
2.0361

7.3524

94 5.92 1.26 94 4.67 0.99 94 3.56 0.76 0.02 0.02 0.00 1395


0.0021 0.0012 0.002
95 5.92 1.26 95 4.65 0.99 95 3.56 0.76 0.02 0.01 0.00 1410






96 5.88 1.25 96 4.64 0.99 96 3.56 0.76 0.01 0.01 0.00 1425



0.0018

97 5.88 1.25 97 4.63 0.98 97 3.56 0.76 0.01 0.01 0.00 1440






98 5.87 1.25 98 4.61 0.98 98 3.56 0.76 0.01 0.01 0.00 1455






99 5.84 1.24 99 4.59 0.98 99 3.57 0.76 0.00 0.00 0.00 1470






100 5.84 1.24 100 4.58 0.97 100 3.57 0.76 0.00 0.00 0.00 1485



























Sheet 2: Wykres1



Sheet 3: Wykres2



Sheet 4: Wykres3



Sheet 5: Wykres4



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