Oblicz pH roztworu zawierającego w 1 dm3 0.020 M Na2SO4 i 0.020 M HCl.
cNa+ = 2 *cNa2SO4 = 2*0.020 M = 0.040 M
cSO42- = 0.020 M
cCl- = 0.020 M
I = ½ (0.040*12 + 0.020*22 + 0.020*12 +0.020*12) =0.080
Dla jonu H+: a*B = 3.0, A = 0.51
ogniwa: K(+)-red | A(-)-utl elektro: K(-)-red | A(+)-utl |
→(+)e.joniz.,powin.e-(-)char.metal. ↓(+)char.metal.(-)e.joniz.,powin.e-,elektrouj. |
[H3O+]=10-pH |
[HCOOH] |
[H3O+] |
[HCOO−] |
pocz. |
0.10 |
0 |
0 |
zmiana |
−4.2 × 10-3 |
+4.2 × 10-3 |
+4.2 × 10−3 |
równow. |
0.10 − 4.2 × 10−3 = 0.0958 = 0.10 |
4.2 × 10−3 |
4.2 × 10−3 |