8399010702

Organie chemistry

Course description_

Mechanism of polyreactions, kinetics of polymer synthesis, copolymerization, structure and reactivity of monomers, structure and properties of polymers

Lecture

Particular lectures contents	Number of hours
1. Introduction, structure of polymers	2
2. Comparison of polyaddition and polycondensation	2
3. Thermodynamics of polymerization, enthalpy, entropy and heat of polymerization	2
4. Intiation, propagation and termination reactions. Chain transfer	2
5. Kinetic equations, kinetic constants determination	2
6. Copolymerizations, reactivity coefficients	2
7. Composition of polymers as function of reactivitry coefficients. Q-e scheme	2
8. Cationic polymerization, catalysts, solvation	2
9. Anionie polymerizations, living polymerization	2
lO.Coordination polymerization, mechanisms, catalysts	2
11.Polycondensation	2
12.Kinetics of polycondensation. Carothers’ eąuation	2
13.Another polymerization mechanisms	2
14.Fotopolymerizations, plasma polymerization	2
15. Chemical reactions on polymers	2

Classes, seminars - the contents

Laboratory, project - the contents_

9.    Radical polymerization - bulk (6 hours)

10.    Suspension polymerization (6 hours)

11.    Emulsion polymerization (6 hours)

12.    Polymerization in solution (6 hours)

13.    Anionie and cationic polymerization (6 hours)

14.    Polycondensation (12 godzin)

15.    Introduction of functional groups to polymer structure and their analysis (6 hours)

16.    Analysis of polymers and plastics (6 hours)

Materiał for self preparation

Core literaturę_

Chemia polimerów pod red. Z. Florjańczyk i St. Penczek, Oficyna wyd. Politechniki Warszawskiej, 1995 Ch. Carraher Polymer chemistry, wyd 5, Plenum Press, NY 2000 Pielichowski J., Puszyński A.; Preparatyka związków wielkocząsteczkowych

Sorenson W.R., Campbel T.; Preparative methods of polymer chemistry_

Additional literaturę

Conditions for course credition_

Exam (lecture)

Positiye results of all laboratory reports (lab)

3