c |
-log c |
E |
|
|
|
|
|
|
1E-06 |
6 |
272 |
|
|
|
|
|
|
3E-06 |
5,52287874528034 |
278 |
|
|
|
|
|
|
1E-05 |
5 |
279 |
|
|
|
|
|
|
3E-05 |
4,52287874528034 |
269 |
|
|
|
|
|
|
0,0001 |
4 |
247 |
|
|
|
|
|
|
0,0003 |
3,52287874528034 |
224 |
|
|
|
|
|
|
0,001 |
3 |
200 |
|
|
|
|
|
|
0,003 |
2,52287874528034 |
176 |
|
|
|
|
|
|
0,01 |
2 |
145 |
|
|
|
|
|
|
0,1 |
1 |
90 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
C |
0,0003 |
|
cw |
0,01 |
S |
-51,0 |
|
metoda jednokrotnego dodatku wzorca |
|
|
|
|
|
|
|
|
a) |
|
|
|
bez rozc. |
z rozc. |
|
|
|
Vw [cm3] |
E1 [mV] |
E2 [mV] |
delta E |
cx |
cx |
|
|
|
0,5 |
224 |
219 |
-5 |
0,00039485997268 |
0,00037624129689 |
|
|
|
|
|
|
|
|
|
|
|
|
b) |
|
|
|
bez rozc. |
z rozc. |
|
|
|
Vw [cm3] |
E1 [mV] |
E2 [mV] |
delta E |
cx |
cx |
|
|
|
3,0 |
224 |
202 |
-22 |
0,000352929837903 |
0,000322224138314 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
metoda dwukrotnego dodatku wzorca |
|
|
|
|
|
|
|
|
a) |
|
|
|
|
|
|
|
|
Vw [cm3] |
E1 [mV] |
E2 [mV] |
E3 [mV] |
delta E2 |
delta E3 |
Z |
cx/delta cx |
cx |
0,5 |
224 |
219 |
214 |
-5 |
-10 |
2 |
|
|
|
|
|
|
|
|
|
|
|
b) |
|
|
|
|
|
|
|
|
Vw [cm3] |
E1 [mV] |
E2 [mV] |
E3 [mV] |
delta E2 |
delta E3 |
Z |
cx/delta cx |
cx |
2,0 |
224 |
208 |
198 |
-16 |
-26 |
1,625 |
1,245 |
0,0004570 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
metoda wielokrotnego dodatku wzorca |
|
|
|
|
|
|
|
|
Vw |
E |
10^E/S |
(Vp+Vw)10^E/S |
|
|
|
|
|
0 |
224 |
4,0536209634181E-05 |
0,002026810481709 |
|
|
|
|
|
0,5 |
219 |
5,08021804691302E-05 |
0,002565510113691 |
|
|
|
|
|
1 |
214 |
6,36680529262369E-05 |
0,003247070699238 |
|
|
|
|
|
1,5 |
211 |
7,29029492858894E-05 |
0,003754501888223 |
|
|
|
|
|
2 |
208 |
8,34773449211416E-05 |
0,004340821935899 |
|
|
|
|
|
2,5 |
205 |
9,55855309468529E-05 |
0,00501824037471 |
|
|
|
|
|
3 |
202 |
0,000109449979932 |
0,005800848936394 |
|
|
|
|
|
3,5 |
200 |
0,000119792981071 |
0,006408924487301 |
|
|
|
|
|
4 |
198 |
0,000131113393742 |
0,007080123262076 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
V [cm3] |
cx |
|
|
|
|
|
|
|
-1,51968503937008 |
0,000303937007874 |
|
|
|
|
|
|
|