9.4 Pierwotny efekt solny reakcji jonowej : | |||||||||
Lp. | t [s] | E | X [Fe3+] | W kolbie reakcyjnej | C [Fe2+] | 1/C | |||
1 | 420 | 0,078 | 1,500E-05 | 7,502E-05 | 1,925E-03 | 5,195E+02 | |||
2 | 2580 | 0,483 | 8,512E-05 | 4,256E-04 | 1,574E-03 | 6,352E+02 | |||
3 | 3360 | 0,551 | 9,561E-05 | 4,780E-04 | 1,522E-03 | 6,570E+02 | |||
I R-r | 4 | 4140 | 0,668 | 1,128E-04 | 5,640E-04 | 1,436E-03 | 6,964E+02 | ||
Lp. | t [s] | E | X [Fe3+] | w kolbie reakcyjnej | C [Fe2+] | 1/C | |||
1 | 360 | 0,164 | 3,099E-05 | 1,550E-04 | 1,845E-03 | 5,420E+02 | |||
2 | 1980 | 0,628 | 1,070E-04 | 5,352E-04 | 1,465E-03 | 6,827E+02 | |||
3 | 2820 | 0,865 | 1,277E-04 | 6,385E-04 | 1,362E-03 | 7,345E+02 | |||
II R-r | 4 | 3480 | 1,019 | 1,578E-04 | 7,890E-04 | 1,211E-03 | 8,258E+02 | ||
Lp. | t [s] | E | X [Fe3+] | w kolbie reakcyjnej | C [Fe2+] | 1/C | |||
1 | 300 | 0,190 | 3,570E-05 | 1,785E-04 | 1,821E-03 | 5,490E+02 | |||
2 | 1440 | 0,576 | 9,937E-05 | 4,969E-04 | 1,503E-03 | 6,653E+02 | |||
3 | 2160 | 0,943 | 1,489E-04 | 7,445E-04 | 1,256E-03 | 7,965E+02 | |||
III R-r | 4 | 2820 | 1,182 | 1,754E-04 | 8,770E-04 | 1,123E-03 | 8,905E+02 | ||
csoli | (csoli)1/2 | I | (I)1/2 | k | log k | ||||
[M] | [dm3/mol*s] | ||||||||
R-r | I | 0,6 | 0,7746 | 2,4 | 1,5492 | 4,726E-02 | -1,3255 | ||
R-r | II | 0,3 | 0,5477 | 1,2 | 1,0954 | 8,739E-02 | -1,0585 | ||
R-r | III | 0,1 | 0,3162 | 0,4 | 0,6325 | 1,375E-01 | -0,8617 | ||
m nacz | 21,2773 | [g] | |||||||
mnacz+sól | 21,6920 | [g] | |||||||
m soli | 0,4147 | [g] | |||||||
M soli | 392,14 | [g/mol] | |||||||
Vc | 0,05 | [dm3] | |||||||
Co | 0,00200 | [mol/dm3] |