Wyniki pomiarów oraz tabela wyników: |
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ilość wody [m3] |
5,00E-05 |
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stała sondy [1/m] |
114,40 |
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NaCl |
KCl |
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B1 [m3/2/mol1/2] |
7,273E-03 |
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c [mol/m3] |
450,00 |
450,00 |
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B2 [m3/2/mol1/2] |
1,918E-04 |
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przew graniczne [ m2/W*mol] |
0,012645 |
0,014985 |
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Wielkości obliczone na podstawie wcześniej załączonego algorytmu: |
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zawartość dodawanego elektrolitu [m3] |
c [mol/m3] |
c1/2 [mol1/2/m3/2] |
L [S] |
L(dośw) |
L(teor) |
L' |
NaCl |
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1,0E-06 |
8,8235 |
2,9704 |
9,840E-05 |
1,276E-03 |
1,180E-02 |
1,8863E-03 |
2,0E-06 |
17,3077 |
4,1603 |
1,870E-04 |
1,236E-03 |
1,146E-02 |
2,0974E-03 |
3,0E-06 |
25,4717 |
5,0469 |
2,720E-04 |
1,222E-03 |
1,121E-02 |
2,2731E-03 |
4,0E-06 |
33,3333 |
5,7735 |
3,510E-04 |
1,205E-03 |
1,101E-02 |
2,4133E-03 |
5,0E-06 |
40,9091 |
6,3960 |
4,330E-04 |
1,211E-03 |
1,083E-02 |
2,5565E-03 |
7,0E-06 |
55,2632 |
7,4339 |
5,790E-04 |
1,199E-03 |
1,054E-02 |
2,7744E-03 |
9,0E-06 |
68,6441 |
8,2852 |
7,030E-04 |
1,172E-03 |
1,029E-02 |
2,9377E-03 |
1,1E-05 |
81,1475 |
9,0082 |
8,160E-04 |
1,150E-03 |
1,009E-02 |
3,0799E-03 |
1,3E-05 |
92,8571 |
9,6362 |
9,230E-04 |
1,137E-03 |
9,911E-03 |
3,2104E-03 |
1,5E-05 |
103,8462 |
10,1905 |
1,026E-03 |
1,130E-03 |
9,753E-03 |
3,3317E-03 |
KCl |
1,0E-06 |
8,8235 |
2,9704 |
9,060E-05 |
1,1747E-03 |
1,409E-02 |
1,7829E-03 |
2,0E-06 |
17,3077 |
4,1603 |
1,695E-04 |
1,1204E-03 |
1,373E-02 |
1,9781E-03 |
3,0E-06 |
25,4717 |
5,0469 |
2,310E-04 |
1,0375E-03 |
1,347E-02 |
2,0819E-03 |
4,0E-06 |
33,3333 |
5,7735 |
3,020E-04 |
1,0365E-03 |
1,325E-02 |
2,2378E-03 |
5,0E-06 |
40,9091 |
6,3960 |
3,630E-04 |
1,0151E-03 |
1,306E-02 |
2,3512E-03 |
7,0E-06 |
55,2632 |
7,4339 |
4,780E-04 |
9,8951E-04 |
1,275E-02 |
2,5534E-03 |
9,0E-06 |
68,6441 |
8,2852 |
5,850E-04 |
9,7494E-04 |
1,249E-02 |
2,7284E-03 |
1,1E-05 |
81,1475 |
9,0082 |
6,840E-04 |
9,6429E-04 |
1,228E-02 |
2,8808E-03 |
1,3E-05 |
92,8571 |
9,6362 |
7,650E-04 |
9,4248E-04 |
1,209E-02 |
3,0010E-03 |
1,5E-05 |
103,8462 |
10,1905 |
8,490E-04 |
9,3528E-04 |
1,192E-02 |
3,1211E-03 |
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Równanie Shedlovsky'ego przyjmuje postać: |
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L'=L(dośw)+bc , a więc dla elektrolitu: |
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a) |
NaCl |
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b= |
0,000011 |
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L(dośw)= |
0,002148 |
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b) |
KCl |
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b= |
1,16220110430868E-05 |
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L(dośw)= |
0,002082503449813 |
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