Overview
Wykres1Wykres2
Arkusz1
Arkusz1 (2)
Sheet 1: Wykres1
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Sheet 2: Wykres2
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Sheet 3: Arkusz1
| T [K] | U [V] | U[mV] | |||||||||||||
| 278,3 | 1,501 | 1501 | |||||||||||||
| 283,2 | 1,496 | 1496 | współczynik | jako średni z f. kwadratowej | |||||||||||
| 288,2 | 1,49 | 1490 | temperaturowy | błąd | |||||||||||
| 293,2 | 1,484 | 1484 | -0,00117 | 1,5E-05 | -0,0011992 | 0,001210418297449 | |||||||||
| 298,2 | 1,478 | 1478 | |||||||||||||
| 303,2 | 1,472 | 1472 | |||||||||||||
| standardowe | |||||||||||||||
| DH [J mol-1] | DG [J mol-1] | DS [J mol-1 K-1] | DCp [J mol-1 K-1] | ||||||||||||
| -332741,000 | -275943,000 | -190,700 | -207,500 | ||||||||||||
| T [K] | SEM [V] | DG [J mol-1] | DH [J mol-1] | DS [J mol-1 K-1] | błędy: | różnice | |||||||||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | G | H | S | G | H | S | ||||
| 278,1 | 1,501 | -289648,901 | -279566,282 | -352437,102 | -328611,750 | -225,7756254 | -176,359 | 192,97062 | 828,091349179808 | 2,8945593 | 10082,619 | 23825,352 | 49,417 | ||
| 283,0 | 1,496 | -288684,048 | -278693,217 | -352578,550 | -329628,500 | -225,7756254 | -179,983 | 192,97062 | 841,885368655329 | 2,8945593 | 9990,831 | 22950,050 | 45,792 | ||
| 288,0 | 1,490 | -287526,224 | -277784,188 | -352549,604 | -330666,000 | -225,7756254 | -183,617 | 192,97062 | 855,974015911752 | 2,8945593 | 9742,035 | 21883,604 | 42,158 | ||
| 293,0 | 1,484 | -286368,400 | -276857,147 | -352520,658 | -331703,500 | -225,7756254 | -187,189 | 192,97062 | 870,075273498406 | 2,8945593 | 9511,253 | 20817,158 | 38,587 | ||
| 298,0 | 1,478 | -285210,576 | -275912,400 | -352491,713 | -332741,000 | -225,7756254 | -190,700 | 192,97062 | 884,188538077497 | 2,8945593 | 9298,176 | 19750,713 | 35,076 | ||
| 303,0 | 1,472 | -284052,753 | -274950,244 | -352462,767 | -333778,500 | -225,7756254 | -194,153 | 192,97062 | 898,313243729033 | 2,8945593 | 9102,508 | 18684,267 | 31,623 | ||
| T [K] | SEM [V] | wspołczynnik temp. | DG [J mol-1] | DH [J mol-1] | DS [J mol-1 K-1] | błędy: | różnice | ||||||||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | G | H | S | wspołcz.temp | G | H | S | |||
| 278,1 | 1,501 | -0,00111984 | -289648,901 | -279566,282 | -349745,259 | -328611,750 | -216,0962191008 | -176,359 | 192,97062 | 44773,2517142819 | 160,995435635504 | 0,000834300245475 | 10082,619 | 21133,509 | 39,737 |
| 283,0 | 1,496 | -0,0011512 | -288684,048 | -278693,217 | -351551,869 | -329628,500 | -222,147777744 | -179,983 | 192,97062 | 46364,892024394 | 163,832102929326 | 0,000849000241225 | 9990,831 | 21923,369 | 42,164 |
| 288,0 | 1,49 | -0,0011832 | -287526,224 | -277784,188 | -353283,201 | -330666,000 | -228,322837584 | -183,617 | 192,97062 | 48017,6716687959 | 166,726661421178 | 0,000864000237037 | 9742,035 | 22617,201 | 44,705 |
| 293,0 | 1,484 | -0,0012152 | -286368,400 | -276857,147 | -355076,284 | -331703,500 | -234,497897424 | -187,189 | 192,97062 | 49699,397605128 | 169,621219940612 | 0,000879000232992 | 9511,253 | 23372,784 | 47,309 |
| 298,0 | 1,478 | -0,0012472 | -285210,576 | -275912,400 | -356931,118 | -332741,000 | -240,672957264 | -190,700 | 192,97062 | 51410,0697867873 | 172,515778486239 | 0,000894000229083 | 9298,176 | 24190,118 | 49,973 |
| 303,0 | 1,472 | -0,0012792 | -284052,753 | -274950,244 | -358847,702 | -333778,500 | -246,848017104 | -194,153 | 192,97062 | 53149,688170988 | 175,410337056764 | 0,000909000225303 | 9102,508 | 25069,202 | 52,695 |
| T [K] | DCp [J mol-1 K-1] | ||||||||||||||
| błąd | różnica | ||||||||||||||
| 278,1 | -343,4568283008 | 160,995435635504 | 135,9568283008 | ||||||||||||
| 283,0 | -349,508386944 | 163,832102929326 | 142,008386944 | ||||||||||||
| 288,0 | -355,683446784 | 166,726661421178 | 148,183446784 | ||||||||||||
| 293,0 | -361,858506624 | 169,621219940612 | 154,358506624 | ||||||||||||
| 298,0 | -368,033566464 | 172,515778486239 | 160,533566464 | ||||||||||||
| 303,0 | -374,208626304 | 175,410337056764 | 166,708626304 | ||||||||||||
| średnio | -358,7915602368 | 68,6901469364794 | 151,2915602368 | ||||||||||||
| T [K] | SEM [V] | DG [J mol-1] | DH [J mol-1] | DS [J mol-1 K-1] | błędy: | różnice | |||||||||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | G | H | S | G | H | S | ||||
| 278,1 | 1,501 | -289648,901 | -279566,282 | -352437,102 | -328611,750 | -225,7756254 | -176,359 | 192,97062 | 828,091349179808 | 2,8945593 | 10082,619 | 23825,352 | 49,417 | ||
| 283,0 | 1,496 | -288684,048 | -278693,217 | -352578,550 | -329628,500 | -225,7756254 | -179,983 | 192,97062 | 841,885368655329 | 2,8945593 | 9990,831 | 22950,050 | 45,792 | ||
| 288,0 | 1,490 | -287526,224 | -277784,188 | -352549,604 | -330666,000 | -225,7756254 | -183,617 | 192,97062 | 855,974015911752 | 2,8945593 | 9742,035 | 21883,604 | 42,158 | ||
| 293,0 | 1,484 | -286368,400 | -276857,147 | -352520,658 | -331703,500 | -225,7756254 | -187,189 | 192,97062 | 870,075273498406 | 2,8945593 | 9511,253 | 20817,158 | 38,587 | ||
| 298,0 | 1,478 | -285210,576 | -275912,400 | -352491,713 | -332741,000 | -225,7756254 | -190,700 | 192,97062 | 884,188538077497 | 2,8945593 | 9298,176 | 19750,713 | 35,076 | ||
| 303,0 | 1,472 | -284052,753 | -274950,244 | -352462,767 | -333778,500 | -225,7756254 | -194,153 | 192,97062 | 898,313243729033 | 2,8945593 | 9102,508 | 18684,267 | 31,623 | ||
| T [K] | SEM [V] | wspołczynnik temp. | DG [J mol-1] | DH [J mol-1] | DS [J mol-1 K-1] | błędy: | różnice | ||||||||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | G | H | S | wspołcz.temp | G | H | S | |||
| 278,1 | 1,501 | -0,00111984 | -289648,901 | -279566,282 | -349745,259 | -328611,750 | -216,0962191008 | -176,359 | 192,97062 | 44773,2517142819 | 160,995435635504 | 0,000834300245475 | 10082,619 | 21133,509 | 39,737 |
| 283,0 | 1,496 | -0,0011512 | -288684,048 | -278693,217 | -351551,869 | -329628,500 | -222,147777744 | -179,983 | 192,97062 | 46364,892024394 | 163,832102929326 | 0,000849000241225 | 9990,831 | 21923,369 | 42,164 |
| 288,0 | 1,49 | -0,0011832 | -287526,224 | -277784,188 | -353283,201 | -330666,000 | -228,322837584 | -183,617 | 192,97062 | 48017,6716687959 | 166,726661421178 | 0,000864000237037 | 9742,035 | 22617,201 | 44,705 |
| 293,0 | 1,484 | -0,0012152 | -286368,400 | -276857,147 | -355076,284 | -331703,500 | -234,497897424 | -187,189 | 192,97062 | 49699,397605128 | 169,621219940612 | 0,000879000232992 | 9511,253 | 23372,784 | 47,309 |
| 298,0 | 1,478 | -0,0012472 | -285210,576 | -275912,400 | -356931,118 | -332741,000 | -240,672957264 | -190,700 | 192,97062 | 51410,0697867873 | 172,515778486239 | 0,000894000229083 | 9298,176 | 24190,118 | 49,973 |
| 303,0 | 1,472 | -0,0012792 | -284052,753 | -274950,244 | -358847,702 | -333778,500 | -246,848017104 | -194,153 | 192,97062 | 53149,688170988 | 175,410337056764 | 0,000909000225303 | 9102,508 | 25069,202 | 52,695 |
Sheet 4: Arkusz1 (2)
| DH0298 [kJ mol-1] | DG0298 [kJ mol-1] | DS0298 [J mol-1 K-1] | DCp [J mol-1 K-1] | średni współczynnik temperaturowy ( dla zależności liniowej E (T) ) [V K-1] | błąd śr. współcz. temp. [V K-1] | ||||||||||
| -332,74 | -275,94 | -190,7 | -207,5 | -0,00117 | 0,000015 | ||||||||||
| T [K] | SEM [V] | DG [kJ mol-1] | |DGdośw - DGoblicz| [kJ mol-1] | błąd DG [kJ mol-1] | DH [kJ mol-1] | |DHdośw - DHoblicz| [kJ mol-1] | błąd DH [kJ mol-1] | DS [J mol-1] | |DSdośw - DSoblicz| [J mol-1] | błąd DS [J mol-1] | |||||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | ||||||||||
| 278,1 | 1,501 | -289,65 | -279,57 | 10,08 | 0,20 | -352,44 | -328,61 | 23,83 | 0,83 | -225,8 | -176,4 | 49,4 | 2,9 | ||
| 283,0 | 1,496 | -288,68 | -278,69 | 9,99 | 0,20 | -352,58 | -329,63 | 22,95 | 0,85 | -225,8 | -180,0 | 45,8 | 2,9 | ||
| 288,0 | 1,490 | -287,53 | -277,78 | 9,74 | 0,20 | -352,55 | -330,67 | 21,88 | 0,86 | -225,8 | -183,6 | 42,2 | 2,9 | ||
| 293,0 | 1,484 | -286,37 | -276,86 | 9,51 | 0,20 | -352,52 | -331,70 | 20,82 | 0,88 | -225,8 | -187,2 | 38,6 | 2,9 | ||
| 298,0 | 1,478 | -285,21 | -275,91 | 9,30 | 0,20 | -352,49 | -332,74 | 19,75 | 0,89 | -225,8 | -190,7 | 35,1 | 2,9 | ||
| 303,0 | 1,472 | -284,05 | -274,95 | 9,10 | 0,20 | -352,46 | -333,78 | 18,68 | 0,90 | -225,8 | -194,2 | 31,6 | 2,9 | ||
| T [K] | SEM [V] | współcz. temp. [V K-1] | błąd wsp. temp. [V K-1] | DG [kJ mol-1] | |DGdośw - DGoblicz| [kJ mol-1] | błąd DG [kJ mol-1] | DH [kJ mol-1] | |DHdośw - DHoblicz| [kJ mol-1] | błąd DH [kJ mol-1] | DS [J mol-1] | |DSdośw - DSoblicz| [J mol-1] | błąd DS [J mol-1] | |||
| dośw. | oblicz. | dośw. | oblicz. | dośw. | oblicz. | ||||||||||
| 278,1 | 1,501 | -0,00112 | 0,00084 | -289,65 | -279,57 | 10,08 | 0,20 | -350 | -328,61 | 21 | 46 | -216 | -176,4 | 40 | 170 |
| 283,0 | 1,496 | -0,00115 | 0,00085 | -288,68 | -278,69 | 9,99 | 0,20 | -352 | -329,63 | 22 | 47 | -222 | -180,0 | 42 | 170 |
| 288,0 | 1,490 | -0,00118 | 0,00087 | -287,53 | -277,78 | 9,74 | 0,20 | -353 | -330,67 | 23 | 49 | -228 | -183,6 | 45 | 170 |
| 293,0 | 1,484 | -0,00122 | 0,00088 | -286,37 | -276,86 | 9,51 | 0,20 | -355 | -331,70 | 23 | 50 | -234 | -187,2 | 47 | 170 |
| 298,0 | 1,478 | -0,00125 | 0,00090 | -285,21 | -275,91 | 9,30 | 0,20 | -357 | -332,74 | 24 | 52 | -241 | -190,7 | 50 | 180 |
| 303,0 | 1,472 | -0,00128 | 0,00091 | -284,05 | -274,95 | 9,10 | 0,20 | -359 | -333,78 | 25 | 54 | -247 | -194,2 | 53 | 180 |
| T [K] | DCp [J mol-1 K-1] | |DCp dośw - DCp oblicz| [J mol-1 K-1] | błąd DCp [J mol-1 K-1] | ||||||||||||
| 278,1 | -343 | 136 | 170 | ||||||||||||
| 283,0 | -350 | 142 | 170 | ||||||||||||
| 288,0 | -356 | 148 | 170 | ||||||||||||
| 293,0 | -362 | 154 | 170 | ||||||||||||
| 298,0 | -368 | 161 | 180 | ||||||||||||
| 303,0 | -374 | 167 | 180 | ||||||||||||
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