9.4 Pierwotny efekt solny reakcji jonowej : | ||||||||
Lp. | t [s] | E | X [Fe3+] | C [Fe2+] | 1/C | |||
1 | 470 | 0,025 | 6,458E-06 | 2,114E-02 | 4,729E+01 | |||
2 | 905 | 0,010 | 3,716E-06 | 2,115E-02 | 4,729E+01 | |||
3 | 1360 | 0,030 | 7,369E-06 | 2,114E-02 | 4,730E+01 | |||
I R-r | 4 | 1770 | 0,075 | 1,550E-05 | 2,114E-02 | 4,731E+01 | ||
5 | 2180 | 0,085 | 1,729E-05 | 2,113E-02 | 4,732E+01 | |||
6 | 2470 | 0,100 | 1,996E-05 | 2,113E-02 | 4,732E+01 | |||
Lp. | t [s] | E | X [Fe3+] | C [Fe2+] | 1/C | |||
1 | 530 | 0,030 | 7,369E-06 | 2,114E-02 | 4,730E+01 | |||
2 | 940 | 0,070 | 1,460E-05 | 2,114E-02 | 4,731E+01 | |||
3 | 1360 | 0,120 | 2,351E-05 | 2,113E-02 | 4,733E+01 | |||
II R-r | 4 | 1750 | 0,160 | 3,052E-05 | 2,112E-02 | 4,735E+01 | ||
5 | 2150 | 0,185 | 3,486E-05 | 2,112E-02 | 4,736E+01 | |||
6 | 2440 | 0,225 | 4,171E-05 | 2,111E-02 | 4,737E+01 | |||
Lp. | t [s] | E | X [Fe3+] | C [Fe2+] | 1/C | |||
1 | 555 | 0,035 | 8,278E-06 | 2,114E-02 | 4,730E+01 | |||
2 | 1000 | 0,120 | 2,351E-05 | 2,113E-02 | 4,733E+01 | |||
3 | 1300 | 0,160 | 3,052E-05 | 2,112E-02 | 4,735E+01 | |||
III R-r | 4 | 1730 | 0,250 | 4,595E-05 | 2,110E-02 | 4,738E+01 | ||
5 | 2130 | 0,330 | 5,925E-05 | 2,109E-02 | 4,741E+01 | |||
6 | 2415 | 0,385 | 6,817E-05 | 2,108E-02 | 4,743E+01 | |||
csoli | (csoli)1/2 | I | (I)1/2 | k | log k | |||
[M] | [dm3/mol*s] | |||||||
R-r | I | 0,8 | 0,8944 | 3,2 | 1,7889 | 1,817E-05 | -4,7407 | |
R-r | II | 0,5 | 0,7071 | 2 | 1,4142 | 3,955E-05 | -4,4029 | |
R-r | III | 0,25 | 0,5000 | 1 | 1,0000 | 7,228E-05 | -4,1410 | |
m nacz | 21,2773 | [g] | ||||||
mnacz+sól | 21,6920 | [g] | ||||||
m soli | 0,4147 | [g] | ||||||
M soli | 392,14 | [g/mol] | ||||||
Vc | 0,05 | [dm3] | ||||||
Co | 0,02115 | [mol/dm3] |