338 J. EILMES, M. PTASZEK
Metal |
Kompleks |
Sposób syntezy |
Lit. |
Ru |
[Ru^tmtaaJRu^^tmtaa)]+ (1) |
[Ru2(OAc)4C12 4- H2tmtaa (w ob. BF4) |
[89] |
[Ru(tmtaaXCO)] |
(1) + co |
[89] | |
[Ru(tmtaa)]2 |
(1) + NaBH4 |
[89] | |
[Ru(tmtaa)]2+ |
(1) + CP2Fe + |
[89] | |
[Ru(tmtaa)(py)2] |
[Ru(tmtaa)]2 4- py |
[89] | |
[Ru(tmtaaXMeCN)2] + |
(1) 4- MeCN (w ob. CO, towarzyszy powstawaniu [Ru(tmtaaKCO)]) |
[89] | |
[Ru2(tmtaa)2Cl2(CO)2] |
(l) + CO + EtOH +cr |
[89] | |
[Ru2(tmtaa)2Cl2(CO)2] |
(1)4-CO 4- EtOH 4-Cr |
[89] | |
[Ru(tmtaaXPMePh2)2] |
Ru2(02CCH3)4 4- H2tmtaa + PMcPh2 |
[90] | |
[Ru2(HtmtaaXO 2CCH 3)3] |
Ru2(02CCH3)4 4- H2tmtaa -f- PhCCPh |
[91, 92] | |
[Ru(omtaaXPPh3)2] |
Li2tmtaa + [Ru(PPh3)2Cl2] (patrz też [94]) |
[93] | |
Rh |
[Rh2(H2tmtaaXCO)4]2 + |
Rh2Cl2(CO)4 4- H2tmtaa |
[95] |
[Rh2(tmtaaXCO)4] [Rh(tmtaa)]2 [Rh(tmtaa)H] |
[Rh2(H2tmtaaKCO)4]2+ 4- NEt, |
[95] [96] | |
4- [Rh(tmtaa)CHO] |
[Rh(tmtaa)]2 4- H2 4- CO (patrz też [106], [191) |
[96] | |
Pd |
[Pd(tmtaa)] |
Pd(PhCN)Cl2 4- H2tmtaa |
[97, 98] |
[Pd(tmtaa)] |
PdfCHjCSCH JOz + H2tmtaa |
[103] | |
[Pd(tptaa)] |
Pd(CH3CSCH3)Cl2 4- H dptaa |
[37] | |
W |
[W(H2tmtaaXCO)4] |
W(COjto 4- H2tmtaa |
[K2, 99] |
1 |
[W(Htmtaa)(CO)a(NO)] |
[W(H2tmtaaXCOU.| 4 NOPF„ (potem f-BuOK) |
[88] |
Pt |
Patrz schemat 4. |
[100] | |
[Pt(tmtaa)Cl2] |
Li2PtCl<, 4- MUtnuaa |
[101] | |
* |
[Pt(tmtaa)X2] (X = I”Br”, N3ł NCS“) (te same kompleksy dla taa) |
[Pt(lmtaa)Cl2) 4- NaX |
[101] [101] |
[Pt(taa)] |
K2PtCl4 4- <>-C\H5(NH2)2 + (HtO)2C=C(OHt)2 (patrz też [104]) |
[102] | |
Hf |
[Hf(tmtaa)(Cl)2]THF |
HfC l4(TIIF)2 + IJ2tmtaa (1:1) |
[<>6| |
[Hf(tmtaa)2] |
HfCl4(THF)2 4- U2tmtaa (1:2) |
[66] | |
[Hf(omtaa)R2] R = Mc, CH2SiMc3 |
[Hf(omtaa)02J 4 |
|77] | |
Rc |
[(Rc(CO)3)2(tmtaa)] |
Re2(CO)j0 4- M2tmtaa |
[ 105] [106] |
Cd |
[Cd(tmtaa)X2] |
CdX2 4 «-< „H4(NH2)2 4 |
[107] |
(X = NOJ, CT, NCS", cio4) |
CH;,COC’l I jCOCH., | ||
Ce |
[Li(THF)Ce(tmtaa)2]TH F |
CcBr3 4- Lijtnitaa |
[108] |