Obliczenia-ćwiczenie 1 |
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Wyniki pomiarów |
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temperatura |
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298,35 K |
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roztwór A |
mS |
cm^3 |
roztwór B |
mS |
cm^3 |
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nr pomiaru |
przewodnictwo |
V elektrolitu |
nr pomiaru |
przewodnictwo |
V elektrolitu |
przewodnictwa graniczne |
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roztwór 1A [KCl] |
mS |
cm^3 |
roztwór 1B [NaCl] |
mS |
cm^3 |
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KCl |
NaCl |
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1 |
3,46E-03 |
0,0 |
1 |
4,65E-03 |
0,0 |
KCl |
0,14985 |
cm^2/(ohm*mol) |
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nr pomiaru |
przewodnictwo |
V elektrolitu |
nr pomiaru |
przewodnictwo |
V elektrolitu |
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2 |
0,73 |
1,0 |
2 |
0,68 |
1,0 |
NaCl |
0,12645 |
cm^2/(ohm*mol) |
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1 |
0,713 |
1,0 |
1 |
0,723 |
1,0 |
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7,130E-04 |
7,230E-04 |
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3 |
1,35 |
2,0 |
3 |
1,22 |
2,0 |
Cl- |
0,07635 |
cm^2/(ohm*mol) |
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2 |
1,296 |
2,0 |
2 |
1,216 |
2,0 |
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1,296E-03 |
1,216E-03 |
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4 |
2,35 |
3,0 |
4 |
2,07 |
3,0 |
stała elektrody |
1,213 |
cm^-1 |
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3 |
2,600 |
3,0 |
3 |
2,330 |
3,0 |
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2,600E-03 |
2,330E-03 |
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5 |
3,03 |
4,0 |
5 |
2,65 |
4,0 |
stała elektrody |
1,213E-02 |
m^-1 |
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4 |
3,340 |
4,0 |
4 |
2,960 |
4,0 |
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3,340E-03 |
2,960E-03 |
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6 |
3,68 |
5,0 |
6 |
3,20 |
5,0 |
Stężenia roztworów[mol/dm^3] |
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5 |
4,030 |
5,0 |
5 |
3,530 |
5,0 |
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4,030E-03 |
3,530E-03 |
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7 |
4,30 |
6,0 |
7 |
3,70 |
6,0 |
A |
0,3500 |
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6 |
4,670 |
6,0 |
6 |
4,070 |
6,0 |
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4,670E-03 |
4,070E-03 |
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8 |
4,86 |
7,0 |
8 |
4,18 |
7,0 |
B |
0,3497 |
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7 |
5,260 |
7,0 |
7 |
4,570 |
7,0 |
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5,260E-03 |
4,570E-03 |
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9 |
5,41 |
8,0 |
9 |
4,65 |
8,0 |
Stężenia roztworów[mol/m^3] |
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8 |
5,830 |
8,0 |
8 |
5,040 |
8,0 |
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5,830E-03 |
5,040E-03 |
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10 |
5,95 |
9,0 |
10 |
5,09 |
9,0 |
A |
3,5000E+02 |
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9 |
6,350 |
9,0 |
9 |
5,470 |
9,0 |
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6,350E-03 |
5,470E-03 |
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11 |
6,42 |
10,0 |
11 |
5,52 |
10,0 |
B |
3,4970E+02 |
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10 |
6,850 |
10,0 |
10 |
5,880 |
10,0 |
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6,850E-03 |
5,880E-03 |
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12 |
6,89 |
11,0 |
12 |
5,89 |
11,0 |
objętość wody destylowanej |
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11 |
7,320 |
11,0 |
11 |
6,280 |
11,0 |
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7,320E-03 |
6,280E-03 |
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13 |
7,33 |
12,0 |
13 |
6,28 |
12,0 |
50 |
cm^3 |
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12 |
7,770 |
12,0 |
12 |
6,650 |
12,0 |
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7,770E-03 |
6,650E-03 |
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14 |
7,76 |
13,0 |
14 |
6,65 |
13,0 |
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13 |
8,200 |
13,0 |
13 |
6,990 |
13,0 |
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8,200E-03 |
6,990E-03 |
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15 |
8,19 |
14,0 |
15 |
6,97 |
14,0 |
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14 |
8,600 |
14,0 |
14 |
7,330 |
14,0 |
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8,600E-03 |
7,330E-03 |
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16 |
8,60 |
15,0 |
16 |
7,30 |
15,0 |
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15 |
8,990 |
15,0 |
15 |
7,650 |
15,0 |
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8,990E-03 |
7,650E-03 |
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Obliczanie stężeń roztworów |
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roztwór A |
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[cm^3] |
[mol*dm^-3] |
[mol*m^-3] |
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nr roztworu |
liczba moli soli |
objętość roztworu |
stężenie molowe |
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2 |
3,5000E-04 |
51,0 |
6,8627E-03 |
6,8627E+00 |
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roztwór 1A [KCl] |
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[cm^3] |
[mol*dm^-3] |
[mol*m^-3] |
pier Z C |
stężenie NaCl |
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0,4049 |
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3 |
7,0000E-04 |
52,0 |
1,3462E-02 |
1,3462E+01 |
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nr roztworu |
liczba moli KCl |
objętość roztworu |
stężenie molowe |
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stężenie KCL |
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0,3999 |
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4 |
1,0500E-03 |
53,0 |
1,9811E-02 |
1,9811E+01 |
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1 |
3,999E-04 |
51,0 |
7,841E-03 |
7,841 |
2,800 |
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5 |
1,4000E-03 |
54,0 |
2,5926E-02 |
2,5926E+01 |
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2 |
7,998E-04 |
52,0 |
1,538E-02 |
15,381 |
3,922 |
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6 |
1,7500E-03 |
55,0 |
3,1818E-02 |
3,1818E+01 |
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3 |
1,200E-03 |
53,0 |
2,264E-02 |
22,636 |
4,758 |
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7 |
2,1000E-03 |
56,0 |
3,7500E-02 |
3,7500E+01 |
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4 |
1,600E-03 |
54,0 |
2,962E-02 |
29,622 |
5,443 |
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8 |
2,4500E-03 |
57,0 |
4,2982E-02 |
4,2982E+01 |
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5 |
2,000E-03 |
55,0 |
3,635E-02 |
36,355 |
6,029 |
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9 |
2,8000E-03 |
58,0 |
4,8276E-02 |
4,8276E+01 |
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6 |
2,399E-03 |
56,0 |
4,285E-02 |
42,846 |
6,546 |
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10 |
3,1500E-03 |
59,0 |
5,3390E-02 |
5,3390E+01 |
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7 |
2,799E-03 |
57,0 |
4,911E-02 |
49,111 |
7,008 |
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11 |
3,5000E-03 |
60,0 |
5,8333E-02 |
5,8333E+01 |
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8 |
3,199E-03 |
58,0 |
5,516E-02 |
55,159 |
7,427 |
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12 |
3,8500E-03 |
61,0 |
6,3115E-02 |
6,3115E+01 |
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9 |
3,599E-03 |
59,0 |
6,100E-02 |
61,002 |
7,810 |
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13 |
4,2000E-03 |
62,0 |
6,7742E-02 |
6,7742E+01 |
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10 |
3,999E-03 |
60,0 |
6,665E-02 |
66,650 |
8,164 |
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14 |
4,5500E-03 |
63,0 |
7,2222E-02 |
7,2222E+01 |
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11 |
4,399E-03 |
61,0 |
7,211E-02 |
72,113 |
8,492 |
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15 |
4,9000E-03 |
64,0 |
7,6563E-02 |
7,6563E+01 |
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12 |
4,799E-03 |
62,0 |
7,740E-02 |
77,400 |
8,798 |
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16 |
5,2500E-03 |
65,0 |
8,0769E-02 |
8,0769E+01 |
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13 |
5,199E-03 |
63,0 |
8,252E-02 |
82,519 |
9,084 |
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roztwór B |
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[cm^3] |
[mol*dm^-3] |
[mol*m^-3] |
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14 |
5,599E-03 |
64,0 |
8,748E-02 |
87,478 |
9,353 |
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nr roztworu |
liczba moli soli |
objętość roztworu |
stężenie molowe |
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15 |
5,999E-03 |
65,0 |
9,228E-02 |
92,285 |
9,606 |
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2 |
3,4970E-04 |
51,0 |
6,8569E-03 |
6,8569E+00 |
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3 |
6,9940E-04 |
52,0 |
1,3450E-02 |
1,3450E+01 |
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roztwór 1B [NaCl] |
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[cm^3] |
[mol*dm^-3] |
[mol*m^-3] |
pier z C |
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4 |
1,0491E-03 |
53,0 |
1,9794E-02 |
1,9794E+01 |
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nr roztworu |
liczba moli soli |
objętość roztworu |
stężenie molowe |
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5 |
1,3988E-03 |
54,0 |
2,5904E-02 |
2,5904E+01 |
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1 |
4,049E-04 |
51,0 |
7,939E-03 |
7,939 |
2,818 |
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6 |
1,7485E-03 |
55,0 |
3,1791E-02 |
3,1791E+01 |
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2 |
8,098E-04 |
52,0 |
1,557E-02 |
15,573 |
3,946 |
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7 |
2,0982E-03 |
56,0 |
3,7468E-02 |
3,7468E+01 |
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3 |
1,215E-03 |
53,0 |
2,292E-02 |
22,919 |
4,787 |
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8 |
2,4479E-03 |
57,0 |
4,2946E-02 |
4,2946E+01 |
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4 |
1,620E-03 |
54,0 |
2,999E-02 |
29,993 |
5,477 |
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9 |
2,7976E-03 |
58,0 |
4,8234E-02 |
4,8234E+01 |
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5 |
2,025E-03 |
55,0 |
3,681E-02 |
36,809 |
6,067 |
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10 |
3,1473E-03 |
59,0 |
5,3344E-02 |
5,3344E+01 |
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6 |
2,429E-03 |
56,0 |
4,338E-02 |
43,382 |
6,587 |
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11 |
3,4970E-03 |
60,0 |
5,8283E-02 |
5,8283E+01 |
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7 |
2,834E-03 |
57,0 |
4,972E-02 |
49,725 |
7,052 |
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12 |
3,8467E-03 |
61,0 |
6,3061E-02 |
6,3061E+01 |
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8 |
3,239E-03 |
58,0 |
5,585E-02 |
55,848 |
7,473 |
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13 |
4,1964E-03 |
62,0 |
6,7684E-02 |
6,7684E+01 |
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9 |
3,644E-03 |
59,0 |
6,176E-02 |
61,764 |
7,859 |
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14 |
4,5461E-03 |
63,0 |
7,2160E-02 |
7,2160E+01 |
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10 |
4,049E-03 |
60,0 |
6,748E-02 |
67,483 |
8,215 |
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15 |
4,8958E-03 |
64,0 |
7,6497E-02 |
7,6497E+01 |
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11 |
4,454E-03 |
61,0 |
7,301E-02 |
73,015 |
8,545 |
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16 |
5,2455E-03 |
65,0 |
8,0700E-02 |
8,0700E+01 |
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12 |
4,859E-03 |
62,0 |
7,837E-02 |
78,368 |
8,853 |
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Obliczanie doświadczalnych wartości przewodnictwa molowego dla badanych roztworów |
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13 |
5,264E-03 |
63,0 |
8,355E-02 |
83,551 |
9,141 |
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wzór: |
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K |
wartość pojemności oporowej sondy[m^-1] |
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14 |
5,669E-03 |
64,0 |
8,857E-02 |
88,572 |
9,411 |
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C |
stężenie roztworu[mol*m^-3] |
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15 |
6,074E-03 |
65,0 |
9,344E-02 |
93,438 |
9,666 |
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L |
zmierzone przewodnictwo[S] |
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roztwór A |
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roztwór B |
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nr pomiaru |
przew.molowe |
nr pomiaru |
przew.molowe |
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2 |
1,2956E-06 |
2 |
1,2082E-06 |
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roztwór 1A [KCl] |
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roztwór 1B [NaCl] |
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|
|
|
|
|
|
|
|
|
3 |
1,2174E-06 |
3 |
1,0994E-06 |
|
|
|
|
|
|
nr pomiaru |
przew.molowe |
nr pomiaru |
przew.molowe |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
4 |
1,4388E-06 |
4 |
1,2685E-06 |
|
|
|
|
|
|
1 |
1,169E-02 |
1 |
1,171E-02 |
|
stała elektrody |
128,6 |
|
|
|
|
|
|
|
|
|
|
|
|
5 |
1,4177E-06 |
5 |
1,2409E-06 |
|
|
|
|
|
|
2 |
1,084E-02 |
2 |
1,004E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
6 |
1,4029E-06 |
6 |
1,2210E-06 |
|
|
|
|
|
|
3 |
1,477E-02 |
3 |
1,307E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
7 |
1,3909E-06 |
7 |
1,1979E-06 |
|
|
|
|
|
|
4 |
1,450E-02 |
4 |
1,269E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
8 |
1,3715E-06 |
8 |
1,1806E-06 |
|
|
|
|
|
|
5 |
1,426E-02 |
5 |
1,233E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
9 |
1,3593E-06 |
9 |
1,1694E-06 |
|
|
|
|
|
|
6 |
1,402E-02 |
6 |
1,206E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
10 |
1,3518E-06 |
10 |
1,1574E-06 |
|
|
|
|
|
|
7 |
1,377E-02 |
7 |
1,182E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
11 |
1,3350E-06 |
11 |
1,1488E-06 |
|
|
|
|
|
|
8 |
1,359E-02 |
8 |
1,161E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
12 |
1,3242E-06 |
12 |
1,1330E-06 |
|
|
|
|
|
|
9 |
1,339E-02 |
9 |
1,139E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
13 |
1,3125E-06 |
13 |
1,1255E-06 |
|
|
|
|
|
|
10 |
1,322E-02 |
10 |
1,121E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
14 |
1,3033E-06 |
14 |
1,1179E-06 |
|
|
|
|
|
|
11 |
1,305E-02 |
11 |
1,106E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
15 |
1,2976E-06 |
15 |
1,1052E-06 |
|
|
|
|
|
|
12 |
1,291E-02 |
12 |
1,091E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
16 |
1,2916E-06 |
16 |
1,0973E-06 |
|
|
|
|
|
|
13 |
1,278E-02 |
13 |
1,076E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Obliczanie teoretycznych wartości przewodnictwa molowego na podstawie równania Onsagera |
|
|
|
|
|
|
|
|
|
14 |
1,264E-02 |
14 |
1,064E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
równanie Onsagera |
|
|
|
|
|
|
|
|
|
15 |
1,253E-02 |
15 |
1,053E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
roztwór 1A [KCl] |
|
roztwór 1B [NaCl] |
|
|
przew gran KCl |
0,014985 |
|
|
|
|
|
|
|
|
|
|
nr roztworu |
przew.teor. |
nr roztworu |
przew.teor. |
|
przew gran NaCl |
0,012645 |
|
|
|
|
|
|
|
|
|
|
1 |
1,414E-02 |
1 |
1,185E-02 |
|
|
|
roztwór A |
|
roztwór B |
|
|
|
|
|
|
|
2 |
1,381E-02 |
2 |
1,153E-02 |
|
B1 |
0,007273 |
nr roztworu |
przew.teor. |
nr roztworu |
przew.teor. |
|
|
|
|
|
|
3 |
1,355E-02 |
3 |
1,129E-02 |
|
B2 |
0,0001918 |
2 |
1,4649E-05 |
2 |
1,2354E-05 |
|
|
|
|
|
|
4 |
1,335E-02 |
4 |
1,109E-02 |
|
|
|
3 |
1,4515E-05 |
3 |
1,2237E-05 |
|
|
|
|
|
|
5 |
1,317E-02 |
5 |
1,092E-02 |
|
|
|
4 |
1,4415E-05 |
4 |
1,2150E-05 |
|
|
|
|
|
|
6 |
1,302E-02 |
6 |
1,078E-02 |
|
|
|
5 |
1,4332E-05 |
5 |
1,2079E-05 |
|
|
|
|
|
|
7 |
1,288E-02 |
7 |
1,064E-02 |
|
|
|
6 |
1,4262E-05 |
6 |
1,2018E-05 |
|
|
|
|
|
|
8 |
1,275E-02 |
8 |
1,052E-02 |
|
|
|
7 |
1,4200E-05 |
7 |
1,1965E-05 |
|
|
|
|
|
|
9 |
1,264E-02 |
9 |
1,041E-02 |
|
|
|
8 |
1,4145E-05 |
8 |
1,1917E-05 |
|
|
|
|
|
|
10 |
1,253E-02 |
10 |
1,031E-02 |
|
|
|
9 |
1,4094E-05 |
9 |
1,1873E-05 |
|
|
|
|
|
|
11 |
1,243E-02 |
11 |
1,022E-02 |
|
|
|
10 |
1,4049E-05 |
10 |
1,1833E-05 |
|
|
|
|
|
|
12 |
1,234E-02 |
12 |
1,013E-02 |
|
|
|
11 |
1,4006E-05 |
11 |
1,1796E-05 |
|
|
|
|
|
|
13 |
1,225E-02 |
13 |
1,005E-02 |
|
|
|
12 |
1,3967E-05 |
12 |
1,1762E-05 |
|
|
|
|
|
|
14 |
1,217E-02 |
14 |
9,974E-03 |
|
|
|
13 |
1,3930E-05 |
13 |
1,1731E-05 |
|
|
|
|
|
|
15 |
1,210E-02 |
15 |
9,902E-03 |
|
|
|
14 |
1,3896E-05 |
14 |
1,1701E-05 |
|
|
|
|
|
|
|
|
|
|
|
|
|
15 |
1,3864E-05 |
15 |
1,1673E-05 |
|
|
|
|
|
|
|
|
|
|
|
|
|
16 |
1,3833E-05 |
16 |
1,1647E-05 |
|
|
|
|
|
|
|
|
|
|
|
|
|
Obliczanie granicznego przewodnictwa molowego badanych elektrolitów |
|
|
|
|
|
|
|
|
|
roztwór 1A [KCl] |
|
roztwór 1B [NaCl] |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
roztwór A |
|
roztwór B |
|
|
|
|
|
|
|
nr roztworu |
A' |
nr roztworu |
A' |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
nr roztworu |
A' |
nr roztworu |
A' |
|
|
|
|
|
|
1 |
1,248E-02 |
1 |
1,251E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
2 |
5,1354E-04 |
2 |
5,1322E-04 |
|
|
|
|
|
|
2 |
1,193E-02 |
2 |
1,112E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
3 |
7,2426E-04 |
3 |
7,2382E-04 |
|
|
|
|
|
|
3 |
1,625E-02 |
3 |
1,450E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
4 |
8,8375E-04 |
4 |
8,8318E-04 |
|
|
|
|
|
|
4 |
1,618E-02 |
4 |
1,431E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
5 |
1,0156E-03 |
5 |
1,0150E-03 |
|
|
|
|
|
|
5 |
1,612E-02 |
5 |
1,412E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
6 |
1,1296E-03 |
6 |
1,1290E-03 |
|
|
|
|
|
|
6 |
1,604E-02 |
6 |
1,400E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
7 |
1,2307E-03 |
7 |
1,2300E-03 |
|
|
|
|
|
|
7 |
1,593E-02 |
7 |
1,388E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
8 |
1,3219E-03 |
8 |
1,3211E-03 |
|
|
|
|
|
|
8 |
1,587E-02 |
8 |
1,379E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
9 |
1,4050E-03 |
9 |
1,4042E-03 |
|
|
|
|
|
|
9 |
1,578E-02 |
9 |
1,368E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
10 |
1,4815E-03 |
10 |
1,4807E-03 |
|
|
|
|
|
|
10 |
1,572E-02 |
10 |
1,359E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
11 |
1,5525E-03 |
11 |
1,5516E-03 |
|
|
|
|
|
|
11 |
1,565E-02 |
11 |
1,354E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
12 |
1,6186E-03 |
12 |
1,6177E-03 |
|
|
|
|
|
|
12 |
1,560E-02 |
12 |
1,348E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
13 |
1,6805E-03 |
13 |
1,6796E-03 |
|
|
|
|
|
|
13 |
1,555E-02 |
13 |
1,340E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
14 |
1,7388E-03 |
14 |
1,7378E-03 |
|
|
|
|
|
|
14 |
1,549E-02 |
14 |
1,336E-02 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
15 |
1,7937E-03 |
15 |
1,7927E-03 |
|
|
|
|
|
|
15 |
1,545E-02 |
15 |
1,332E-02 |
|
|
|
|
|
16 |
1,8457E-03 |
16 |
1,8446E-03 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
zestawienie wartości potrzebnych do narysowania wykresów A'=f( C ) |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
wykres 1 |
|
wykres 2 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
nr roztworu |
A' |
stężenie |
A' |
stęzenie |
|
|
|
|
|
|
|
|
|
|
|
|
|
1 |
- |
0 |
- |
0 |
|
|
|
|
|
|
|
|
|
|
|
|
|
2 |
5,1354E-04 |
6,8627E+00 |
5,1322E-04 |
6,8569E+00 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
3 |
7,2426E-04 |
1,3462E+01 |
7,2382E-04 |
1,3450E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
4 |
8,8375E-04 |
1,9811E+01 |
8,8318E-04 |
1,9794E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
5 |
1,0156E-03 |
2,5926E+01 |
1,0150E-03 |
2,5904E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
6 |
1,1296E-03 |
3,1818E+01 |
1,1290E-03 |
3,1791E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
7 |
1,2307E-03 |
3,7500E+01 |
1,2300E-03 |
3,7468E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
8 |
1,3219E-03 |
4,2982E+01 |
1,3211E-03 |
4,2946E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
9 |
1,4050E-03 |
4,8276E+01 |
1,4042E-03 |
4,8234E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
10 |
1,4815E-03 |
5,3390E+01 |
1,4807E-03 |
5,3344E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
11 |
1,5525E-03 |
5,8333E+01 |
1,5516E-03 |
5,8283E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
12 |
1,6186E-03 |
6,3115E+01 |
1,6177E-03 |
6,3061E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
13 |
1,6805E-03 |
6,7742E+01 |
1,6796E-03 |
6,7684E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
14 |
1,7388E-03 |
7,2222E+01 |
1,7378E-03 |
7,2160E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
15 |
1,7937E-03 |
7,6563E+01 |
1,7927E-03 |
7,6497E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
16 |
1,8457E-03 |
8,0769E+01 |
1,8446E-03 |
8,0700E+01 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
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|
|
|
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|
|
|
|
|
|
|
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Parametry regresji |
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roztwór A |
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roztwór B |
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Wielokrotność R |
0,996759765676539 |
Wielokrotność R |
0,9907342180071 |
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R kwadrat |
0,993530030471548 |
R kwadrat |
0,98155429073014 |
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Błąd standardowy |
0,000405464828124 |
Błąd standardowy |
0,00075733147937 |
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Obserwacje |
13 |
Obserwacje |
13 |
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przew.gran. Dla C=0 |
0,148081711235352 |
przew.gran. Dla C=0 |
0,130623708263549 |
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Parametr b |
-243,553046773385 |
Parametr b |
-268,021048705315 |
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Obliczanie liczby przenoszenia kationu |
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roztwór A |
roztwór B |
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0,515593717570256 |
0,584503387746081 |
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Tabele |
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roztwór A |
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nr pomiaru |
c[mol/m^-3] |
c^0,5 |
L[S] |
przew.dośw. |
przew.teor. |
A' |
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1 |
0,0000E+00 |
0,0000E+00 |
3,46E-06 |
- |
- |
- |
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2 |
6,8627E+00 |
2,6197E+00 |
7,33E-04 |
1,2956E-06 |
1,4649E-05 |
5,1354E-04 |
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3 |
1,3462E+01 |
3,6690E+00 |
1,35E-03 |
1,2174E-06 |
1,4515E-05 |
7,2426E-04 |
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4 |
1,9811E+01 |
4,4510E+00 |
2,35E-03 |
1,4388E-06 |
1,4415E-05 |
8,8375E-04 |
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5 |
2,5926E+01 |
5,0918E+00 |
3,03E-03 |
1,4177E-06 |
1,4332E-05 |
1,0156E-03 |
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6 |
3,1818E+01 |
5,6408E+00 |
3,68E-03 |
1,4029E-06 |
1,4262E-05 |
1,1296E-03 |
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7 |
3,7500E+01 |
6,1237E+00 |
4,30E-03 |
1,3909E-06 |
1,4200E-05 |
1,2307E-03 |
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8 |
4,2982E+01 |
6,5561E+00 |
4,86E-03 |
1,3715E-06 |
1,4145E-05 |
1,3219E-03 |
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9 |
4,8276E+01 |
6,9481E+00 |
5,41E-03 |
1,3593E-06 |
1,4094E-05 |
1,4050E-03 |
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10 |
5,3390E+01 |
7,3068E+00 |
5,95E-03 |
1,3518E-06 |
1,4049E-05 |
1,4815E-03 |
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11 |
5,8333E+01 |
7,6376E+00 |
6,42E-03 |
1,3350E-06 |
1,4006E-05 |
1,5525E-03 |
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12 |
6,3115E+01 |
7,9445E+00 |
6,89E-03 |
1,3242E-06 |
1,3967E-05 |
1,6186E-03 |
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13 |
6,7742E+01 |
8,2305E+00 |
7,33E-03 |
1,3125E-06 |
1,3930E-05 |
1,6805E-03 |
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14 |
7,2222E+01 |
8,4984E+00 |
7,76E-03 |
1,3033E-06 |
1,3896E-05 |
1,7388E-03 |
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15 |
7,6563E+01 |
8,7500E+00 |
8,19E-03 |
1,2976E-06 |
1,3864E-05 |
1,7937E-03 |
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16 |
8,0769E+01 |
8,9872E+00 |
8,60E-03 |
1,2916E-06 |
1,3833E-05 |
1,8457E-03 |
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Graniczne przewodnictwo molowe elektrolitu |
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0,1481 |
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Liczba przenoszenia kationu |
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0,516 |
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roztwór B |
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nr pomiaru |
c[mol/m^-3] |
c^0,5 |
L[S] |
przew.dośw. |
przew.teor. |
A' |
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1 |
0 |
0 |
4,65E-06 |
- |
- |
- |
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2 |
6,8569E+00 |
2,6186E+00 |
6,83E-04 |
1,2082E-06 |
1,2354E-05 |
5,1322E-04 |
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3 |
1,3450E+01 |
3,6674E+00 |
1,22E-03 |
1,0994E-06 |
1,2237E-05 |
7,2382E-04 |
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4 |
1,9794E+01 |
4,4491E+00 |
2,07E-03 |
1,2685E-06 |
1,2150E-05 |
8,8318E-04 |
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5 |
2,5904E+01 |
5,0896E+00 |
2,65E-03 |
1,2409E-06 |
1,2079E-05 |
1,0150E-03 |
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6 |
3,1791E+01 |
5,6383E+00 |
3,20E-03 |
1,2210E-06 |
1,2018E-05 |
1,1290E-03 |
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7 |
3,7468E+01 |
6,1211E+00 |
3,70E-03 |
1,1979E-06 |
1,1965E-05 |
1,2300E-03 |
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8 |
4,2946E+01 |
6,5533E+00 |
4,18E-03 |
1,1806E-06 |
1,1917E-05 |
1,3211E-03 |
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9 |
4,8234E+01 |
6,9451E+00 |
4,65E-03 |
1,1694E-06 |
1,1873E-05 |
1,4042E-03 |
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10 |
5,3344E+01 |
7,3037E+00 |
5,09E-03 |
1,1574E-06 |
1,1833E-05 |
1,4807E-03 |
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11 |
5,8283E+01 |
7,6344E+00 |
5,52E-03 |
1,1488E-06 |
1,1796E-05 |
1,5516E-03 |
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12 |
6,3061E+01 |
7,9411E+00 |
5,89E-03 |
1,1330E-06 |
1,1762E-05 |
1,6177E-03 |
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13 |
6,7684E+01 |
8,2270E+00 |
6,28E-03 |
1,1255E-06 |
1,1731E-05 |
1,6796E-03 |
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14 |
7,2160E+01 |
8,4947E+00 |
6,65E-03 |
1,1179E-06 |
1,1701E-05 |
1,7378E-03 |
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15 |
7,6497E+01 |
8,7462E+00 |
6,97E-03 |
1,1052E-06 |
1,1673E-05 |
1,7927E-03 |
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16 |
8,0700E+01 |
8,9833E+00 |
7,30E-03 |
1,0973E-06 |
1,1647E-05 |
1,8446E-03 |
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Graniczne przewodnictwo molowe elektrolitu |
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0,1306 |
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Liczba przenoszenia kationu |
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0,585 |
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Zestawienie danych potrzebnych do narysowania wykresów z punktu 4.8 |
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roztwór A |
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roztwór B |
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C^0,5 |
przew.dośw. |
przew.teor. |
C^0,5 |
przew.dośw. |
przew.teor. |
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0,0000E+00 |
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0,0000E+00 |
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2,6197E+00 |
1,2956E-06 |
1,4649E-05 |
2,6186E+00 |
1,2082E-06 |
1,2354E-05 |
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3,6690E+00 |
1,2174E-06 |
1,4515E-05 |
3,6674E+00 |
1,0994E-06 |
1,2237E-05 |
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4,4510E+00 |
1,4388E-06 |
1,4415E-05 |
4,4491E+00 |
1,2685E-06 |
1,2150E-05 |
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5,0918E+00 |
1,4177E-06 |
1,4332E-05 |
5,0896E+00 |
1,2409E-06 |
1,2079E-05 |
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5,6408E+00 |
1,4029E-06 |
1,4262E-05 |
5,6383E+00 |
1,2210E-06 |
1,2018E-05 |
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6,1237E+00 |
1,3909E-06 |
1,4200E-05 |
6,1211E+00 |
1,1979E-06 |
1,1965E-05 |
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6,5561E+00 |
1,3715E-06 |
1,4145E-05 |
6,5533E+00 |
1,1806E-06 |
1,1917E-05 |
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|
6,9481E+00 |
1,3593E-06 |
1,4094E-05 |
6,9451E+00 |
1,1694E-06 |
1,1873E-05 |
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|
7,3068E+00 |
1,3518E-06 |
1,4049E-05 |
7,3037E+00 |
1,1574E-06 |
1,1833E-05 |
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|
7,6376E+00 |
1,3350E-06 |
1,4006E-05 |
7,6344E+00 |
1,1488E-06 |
1,1796E-05 |
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|
7,9445E+00 |
1,3242E-06 |
1,3967E-05 |
7,9411E+00 |
1,1330E-06 |
1,1762E-05 |
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|
8,2305E+00 |
1,3125E-06 |
1,3930E-05 |
8,2270E+00 |
1,1255E-06 |
1,1731E-05 |
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|
8,4984E+00 |
1,3033E-06 |
1,3896E-05 |
8,4947E+00 |
1,1179E-06 |
1,1701E-05 |
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|
8,7500E+00 |
1,2976E-06 |
1,3864E-05 |
8,7462E+00 |
1,1052E-06 |
1,1673E-05 |
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|
8,9872E+00 |
1,2916E-06 |
1,3833E-05 |
8,9833E+00 |
1,0973E-06 |
1,1647E-05 |
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