surface area m2/g | sample name | MAGNESIUM-based-HYDROTALCITES | Mg | Al | Cu | Fe | UV-vis-DRS | XRD | phenol oxidation | DeSOOT | VOC MeOH | AAS | |||
calcined | assumed (idealized) formula | fresh | calcined | fresh | calcined | fresh | calcined | calcined | calcined | fresh | |||||
146.7 | KG1 | Mg0,667 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.667 | 0.333 | 0 | 0 | + | + | + | + | + | + | + | + | |
124.7 | KG2 | Cu0,2 Mg0,467 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0.333 | 0.2 | 0 | + | + | + | + | + | + | + | + | |
37.4 | KG6 | Cu0,467 Mg0,2 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0.333 | 0.467 | 0 | + | + | + | + | + | + | + | + | |
27.6 | KG13 | Cu0,2 Mg0,467 Al0,166 Fe0,166 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0.166 | 0.2 | 0.166 | + | + | + | + | + | + | + | + | + |
52.6 | KG9 | Cu0,467 Mg0,2 Al0,166 Fe0,166 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0.166 | 0.467 | 0.166 | + | + | + | + | + | + | + | + | |
41.7 | KG11 | Cu0,2 Mg0,467 Fe0,333 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0 | 0.2 | 0.333 | + | + | + | + | + | + | + | + | + |
3.9 | KG12 | Cu0,467 Mg0,2 Fe0,333 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0 | 0.467 | 0.333 | + | + | + | + | + | + | + | + | |
surface area m2/g | sample name | ZINC-based-HYDROTALCITES | Zn | Al | Cu | Fe | UV-vis-DRS | XRD | phenol oxidation | DeSOOT | VOC MeOH | AAS | |||
calcined | assumed (idealized) formula | fresh | calcined | fresh | calcined | fresh | calcined | calcined | calcined | fresh | |||||
70.4 | KG4 | Zn0,667 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.667 | 0.333 | 0 | 0 | + | + | + | + | + | + | + | + | |
54.05 | KG3 | Cu0,2 Zn0,467 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0.333 | 0.2 | 0 | + | + | + | + | + | + | + | + | + |
73.6 | KG5 | Cu0,467 Zn0,2 Al0,333 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0.333 | 0.467 | 0 | + | + | + | + | + | + | + | + | + |
48.2 | KG14 | Cu0,2 Zn0,467 Al0,166 Fe0,166 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0.166 | 0.2 | 0.166 | + | + | + | + | + | + | + | + | |
26.5 | KG7 | Cu0,467 Zn0,2 Al0,166 Fe0,166 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0.166 | 0.467 | 0.166 | + | + | + | + | + | + | + | + | |
10.6 | KG10 | Cu0,2 Zn0,467 Fe0,333 (OH)2 (CO32-)0,165*nH20 | 0.467 | 0 | 0.2 | 0.333 | + | + | + | + | + | + | + | + | + |
23.5 | KG8 | Cu0,467 Zn0,2 Fe0,333 (OH)2 (CO32-)0,165*nH20 | 0.2 | 0 | 0.467 | 0.333 | + | + | + | + | + | + | + | + | + |
XRD | methods | |||||||
sample name | compound | note | calcined | UV-VIS | phenol oxidation [H2O2+MW] | deNOx | XRD | AAS |
TF1 | Mg-HT + Ti compl | pH=3,5 | - | + | - | - | + | + |
TF2 | Mg-HT + Ti compl | pH=10 | - | + | - | - | + | + |
TF3 | Mg2Al0.9Ti0.1 | po autoklawie | - | + | - | - | - | - |
TF4 | Mg2Al0.95Ti0.05 | po autoklawie | - | + | - | - | + | + |
TF5 | Zn2Al0.75Ti0.25 | po autoklawie | - | + | - | - | - | - |
TF6 | Zn2Al0.9Ti0.1 | po autoklawie | - | + | - | - | - | - |
TF7 | Zn2Al0.95Ti0.05 | po autoklawie | - | + | - | - | + | + |
TF8 | Mg-HT + Ti compl | Po US (najpierw doprowadzono pH do 7 następnie dodano hydrotalkit Magnezowo-glinowy) | - | + | - | - | + | + |
TF9 | Mg-HT + Ti compl | Po US (najpierw dodano hydrotalkit magnezowo-glinowy a następnie doprowadzono pH do 7) | - | + | - | - | + | + |
TF10 | Mg2Al0.75Ti0.25 | metoda współstrącania | + | + | + | - | - | + |
TF11 | Mg2Al0.9Ti0.1 | metoda współstrącania | + | + | + | - | - | + |
TF12 | Mg2Al0.95Ti0.05 | metoda współstrącania | - | + | - | - | + | - |
TF13 | Zn2Al0.75Ti0.25 | metoda współstrącania | + | + | + | - | - | + |
TF14 | Zn2Al0.9Ti0.1 | metoda współstrącania | + | + | - | - | - | + |
TF15 | Zn2Al0.95Ti0.05 | metoda współstrącania | + | + | - | - | + | + |
TF16 | Mg1.4Cu0.6Al0.9Ti.01 | po autoklawie | - | + | - | - | - | - |
TF17 | Zn1.4Cu0.6Al0.9Ti.01 | po autoklawie | - | + | - | - | - | - |
TF18 | Mg1.4Cu0.6Al0.9Ti.01 | metoda współstrącania | + | + | + | - | - | + |
TF19 | Zn1.4Cu0.6Al0.9Ti.01 | metoda współstrącania | + | + | - | - | - | + |
TF20 | MgAl+kwas glikolowy+TiCl4 | US pH=10 | + | - | - | - | - | + |
TF21 | MgAl+kwas glikolowy | US pH=10 | + | - | - | - | - | + |
TF22 | MgAl+kwas glikolowy | pH=10 | + | - | - | - | - | + |
TF23 | MgAl+kwas glikolowy | pH=7 | - | - | - | - | - | + |
TF24 | MgAl+kwas glikolowy | pH=4 | - | - | - | - | - | - |
*autoclave (3 days 120 C degr.) **Ultra Sound = US treatm. 60min | fresh + calcined | and CuZnFe (70-30-100) | * only calcined TF 18,19,10 |