1. Czerwień rozproszona - izomer trans

2-(ethyl{4-[(E)-(4-nitrophenyl)diazenyl]phenyl}amino)ethanol

Molecular Formula = C₁₆H₁₈N₄O₃

Formula Weight = 314.33912

Composition = C(61.13%) H(5.77%) N(17.82%) O(15.27%)

Molar Refractivity = 87.57 ± 0.5 cm³

Molar Volume = 255.1 ± 7.0 cm³

Parachor = 679.7 ± 8.0 cm³

Index of Refraction = 1.602 ± 0.05

Surface Tension = 50.3 ± 7.0 dyne/cm

Density = 1.23 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 34.71 ± 0.5 10^-24cm³

Monoisotopic Mass = 314.13789 Da

Nominal Mass = 314 Da

Average Mass = 314.3391 Da

M+ = 314.137342 Da

M- = 314.138439 Da

[M+H]+ = 315.145167 Da

[M+H]- = 315.146264 Da

[M-H]+ = 313.129517 Da

[M-H]- = 313.130614 Da

2. Czerwień rozproszona - izomer cis

Molecular Formula = C₁₆H₁₈N₄O₃

Formula Weight = 314.33912

Composition = C(61.13%) H(5.77%) N(17.82%) O(15.27%)

Molar Refractivity = 87.39 ± 0.5 cm³

Molar Volume = 254.2 ± 7.0 cm³

Parachor = 672.2 ± 8.0 cm³

Index of Refraction = 1.603 ± 0.05

Surface Tension = 48.8 ± 7.0 dyne/cm

Density = 1.23 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 34.64 ± 0.5 10^-24cm³

Monoisotopic Mass = 314.13789 Da

Nominal Mass = 314 Da

Average Mass = 314.3391 Da

M+ = 314.137342 Da

M- = 314.138439 Da

[M+H]+ = 315.145167 Da

[M+H]- = 315.146264 Da

[M-H]+ = 313.129517 Da

[M-H]- = 313.130614 Da

3. Szereg 1

4'-pentylbiphenyl-4-carbonitrile

Molecular Formula = C₁₈H₁₉N

Formula Weight = 249.35016

Composition = C(86.70%) H(7.68%) N(5.62%)

Molar Refractivity = 79.17 ± 0.4 cm³

Molar Volume = 241.4 ± 5.0 cm³

Parachor = 623.6 ± 6.0 cm³

Index of Refraction = 1.569 ± 0.03

Surface Tension = 44.4 ± 5.0 dyne/cm

Density = 1.03 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 31.38 ± 0.5 10^-24cm³

Monoisotopic Mass = 249.15175 Da

Nominal Mass = 249 Da

Average Mass = 249.3502 Da

M+ = 249.151201 Da

M- = 249.152298 Da

[M+H]+ = 250.159026 Da

[M+H]- = 250.160123 Da

[M-H]+ = 248.143376 Da

[M-H]- = 248.144473 Da

4. Szereg 2

4'-heptylbiphenyl-4-carbonitrile

Molecular Formula = C₂₀H₂₃N

Formula Weight = 277.40332

Composition = C(86.59%) H(8.36%) N(5.05%)

Molar Refractivity = 88.43 ± 0.4 cm³

Molar Volume = 274.0 ± 5.0 cm³

Parachor = 703.7 ± 6.0 cm³

Index of Refraction = 1.558 ± 0.03

Surface Tension = 43.5 ± 5.0 dyne/cm

Density = 1.01 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 35.05 ± 0.5 10^-24cm³

Monoisotopic Mass = 277.18305 Da

Nominal Mass = 277 Da

Average Mass = 277.4033 Da

M+ = 277.182501 Da

M- = 277.183598 Da

[M+H]+ = 278.190326 Da

[M+H]- = 278.191423 Da

[M-H]+ = 276.174676 Da

[M-H]- = 276.175773 Da

5. Szereg 3

4'-(octyloxy)biphenyl-4-carbonitrile

Molecular Formula = C₂₁H₂₅NO

Formula Weight = 307.4293

Composition = C(82.04%) H(8.20%) N(4.56%) O(5.20%)

Molar Refractivity = 94.80 ± 0.4 cm³

Molar Volume = 296.3 ± 5.0 cm³

Parachor = 764.2 ± 6.0 cm³

Index of Refraction = 1.552 ± 0.03

Surface Tension = 44.2 ± 5.0 dyne/cm

Density = 1.03 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 37.58 ± 0.5 10^-24cm³

Monoisotopic Mass = 307.193614 Da

Nominal Mass = 307 Da

Average Mass = 307.4293 Da

M+ = 307.193066 Da

M- = 307.194163 Da

[M+H]+ = 308.200891 Da

[M+H]- = 308.201988 Da

[M-H]+ = 306.185241 Da

[M-H]- = 306.186338 Da

6. Szereg 4

4''-pentyl-1,1':4',1''-terphenyl-4-carbonitrile

Molecular Formula = C₂₄H₂₃N

Formula Weight = 325.44612

Composition = C(88.57%) H(7.12%) N(4.30%)

Molar Refractivity = 103.87 ± 0.4 cm³

Molar Volume = 300.2 ± 5.0 cm³

Parachor = 795.6 ± 6.0 cm³

Index of Refraction = 1.608 ± 0.03

Surface Tension = 49.3 ± 5.0 dyne/cm

Density = 1.08 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 41.18 ± 0.5 10^-24cm³

Monoisotopic Mass = 325.18305 Da

Nominal Mass = 325 Da

Average Mass = 325.4461 Da

M+ = 325.182501 Da

M- = 325.183598 Da

[M+H]+ = 326.190326 Da

[M+H]- = 326.191423 Da

[M-H]+ = 324.174676 Da

[M-H]- = 324.175773 Da

7. Szereg 5

4''-propyl-1,1':4',1''-terphenyl-4-carbonitrile

Molecular Formula = C₂₂H₁₉N

Formula Weight = 297.39296

Composition = C(88.85%) H(6.44%) N(4.71%)

Molar Refractivity = 94.61 ± 0.4 cm³

Molar Volume = 267.8 ± 5.0 cm³

Parachor = 715.5 ± 6.0 cm³

Index of Refraction = 1.624 ± 0.03

Surface Tension = 50.9 ± 5.0 dyne/cm

Density = 1.11 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 37.50 ± 0.5 10^-24cm³

Monoisotopic Mass = 297.15175 Da

Nominal Mass = 297 Da

Average Mass = 297.393 Da

M+ = 297.151201 Da

M- = 297.152298 Da

[M+H]+ = 298.159026 Da

[M+H]- = 298.160123 Da

[M-H]+ = 296.143376 Da

[M-H]- = 296.144473 Da

8. Szereg 6

4'-propylbiphenyl-4-carbonitrile

Molecular Formula = C₁₆H₁₅N

Formula Weight = 221.297

Composition = C(86.84%) H(6.83%) N(6.33%)

Molar Refractivity = 69.91 ± 0.4 cm³

Molar Volume = 208.9 ± 5.0 cm³

Parachor = 543.4 ± 6.0 cm³

Index of Refraction = 1.583 ± 0.03

Surface Tension = 45.8 ± 5.0 dyne/cm

Density = 1.05 ± 0.1 g/cm³

Dielectric Constant = Not available

Polarizability = 27.71 ± 0.5 10^-24cm³

Monoisotopic Mass = 221.120449 Da

Nominal Mass = 221 Da

Average Mass = 221.297 Da

M+ = 221.119901 Da

M- = 221.120998 Da

[M+H]+ = 222.127726 Da

[M+H]- = 222.128823 Da

[M-H]+ = 220.112076 Da

[M-H]- = 220.113173 Da

9. Szereg cząsteczek

1. POLARYZOWALNOŚĆ ORIENTACYJNA

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2. REFRAKCJA MOLOWA dla szeregu 6

Wg tabeli:

CN 4,820

C6H5 (fenyl) 25,359

-CH2- 4,647

CH3 5,653

R= 4,820 + 2 * 25,359+ 2* 4,647 + 5,653 = 70,485*10^-6 [m3 * mol -1] =

70,485 [cm3 *mol-1]

Wg wzoru:

R = 70,437

Wg programu:

R = 69.91 ± 0.4 cm3

???

3. FUNKCJE α, R , n w zależności od długośći łańcucha cząsteczki

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