O
O
CH3
O
O
O
CH3
N
CH3
H C
N
9
4
H N
2
CH3
H N
2
N
CH3
* HCl
H
* HCl
Benzocainum FPVI
Procaini hydrochloridum FPVI Tetracaini hydrochloridum FPVI Benzokaina
Prokainy chlorowodorek Tetrakainy chlorowodorek C H NO
m.cz. 165.19
C H ClN O
m.cz. 272.77
C H ClN O
m.cz. 300.83
9
11
2
13
21
2
2
15
25
2
2
CH3
H
CH3
H
H
N
i enancjomer
N
CH
N
3
N
* HCl, * H O
2
O
* HCl, * H O
2
O
CH
CH
3
3
CH
CH
3
3
Lidocaini hydrochloridum FPVI Bupivacaini hydrochloridum FPVI Lidokainy chlorowodorek Bupiwakainy chlorowodorek C H ClN O *H O
m.cz. 288.82
C H ClN O *H O
m.cz. 342.89
14
23
2
2
18
29
2
2
O
H
O
H C
O
3
H C
3
O
H
O
O
H
H
N
CH
N
CH
N
CH
3
3
3
* HCl, * 3H O
* H PO , * 1/ H O
* HCl, * 2H O
2
3
4
2
2
2
O
H
O
H
O
H
Morphini hydrochloridum FPVI Codeini phosphas FPV
Ethylmorphini hydrochloridum FPVI Morfiny chlorowodorek Kodeiny fosforan
Etylomorfiny chlorowodorek C H ClNO *3H O
m.cz. 375.85
C H NO P *1/ H O
m.cz. 406,37
C H ClNO *2H O
m.cz. 385.89
17
20
3
2
18
24
7
2
2
19
24
3
2
O
N
O
H C
COOH
3
N
O
CH3
COOH
*
OH
N
* HCl
COOH
CH3
Fentanyli citras FPVI Pethidini hydrochloridum FPVI Fentanylu cytrynian
Petydyny chlorowodorek C H N O
m.cz. 528,60
C H ClNO
m.cz. 283,80
28
36
2
8
15
22
2
O
O
O
Ni
O
2+
2+
NH OH
2
Ni
Ni
NH
NH
OH
2
2
R
OR
-R OH
R
O
R
O
R
N
1
2
2
1
1
1
H
-
-
-
C H OH + 4I + 6OH CHI + HCOO + 5I + 5H O
2
5
2
3
2
CH3
CH
CH
3
N
C
3
H
N
N
O
N
CH3
CH
2
Co2+ / OH-
CH
3
3
O
Co
CH
CH
CH
3
3
3
CH
O
3
N
N
C
CH3
BENZOKAINA - oznaczenie bromianometryczne CH3
O
Br
Br
1) OH- / ∆
O
2) H+ / 3Br , -CO - 3HBr 2
2
H N
2
H N
2
CH3
Br
PROKAINA - oznaczenie bromianometryczne O
O
CH3
Br
CH3
H+ / 2Br
O
2
O
-2HBr
N
CH3
N
CH3
H N
H N
2
2
Br
CH COOH
2
H SO
2
4
CH COOH
CHCOOH
2
O
H
COOH
CHO
CH OH
CH COOH
2
O
H
OH
CHCOOH +
CH OH
-2H O
2
O
O
O
H
OH
O
H
OH
O
O
O
H
H
H
+ K Fe(CN)
N
N
3
6
O
H
O
H
CH
CH
3
3
N
CH3
+ O
+ K Fe(CN)
O
H
H
4
6
N
CH3
O
H
O